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US6015457A Expired / Lapsed US ⏱️ 0.0 years remaining

Stable inorganic polymers

Assignee: Honeywell International Inc
•
Filing: 1998-03-12
•
Granted: 2000-01-18
•
Expires: 2018-03-12
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Abstract

Abstract Processes for producing poly (hydrido siloxane) copolymers and processes for producing solutions of such copolymers for coating semiconductor substrates are provided. The copolymers have the general formula: (HSiO1.5)a(HSiO(OR))b(SiO2)c, wherein R is a mixture of H and an alkyl group having between 1 and 4 carbon atoms; a+b+c=1; 0.5<a<0.99; 0.01<b<0.5; and 0<c<0.5. Processes for producing the copolymers use alkoxysilanes as starting materials. Processes for producing coating solutions include removal of water and alcohol. Films of such coating solutions are useful as planarizing dielectric layers.

Inventors

  • 👤 Roger Y. Leung
  • 👤 Tadashi Nakano

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 22:42
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/69; H10P14/692; H10P14/6921; H10P14/6922; C; C08; C08G; C08G77/00; C08G77/04; C08G77/12; H10P14/63; H10P14/6326; H10P14/6342; H10P14/66; H10P14/668; H10P14/6681; H10P14/6684; H10P14/6686

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 94 words
A solution for coating a semiconductor device comprising: a poly (hydrido siloxane) copolymer having a general formula: (HSiO.sub.1.5).sub.a (HSiO(OR)).sub.b (SiO.sub.2).sub.c, wherein R is a mixture of H and an alkyl group having between 1 and 4 carbon atoms; a+b+c=1; 0.5<a<0.99; 0.01<b<0.5; and 0<c<0.5; and a solvent selected from the group consisting of dialkylketals, alkylacetates, dialkylacetals, ethers, dialkyl glycol ethers, ketones, and esters, or mixtures thereof, wherein said solution for coating a semiconductor has a water content of less than about 0.5% by weight and an alcohol content of less than about 1% by weight.
Claim 2
Dependent Claim 94 words
A solution for coating a semiconductor device comprising: a poly (hydrido siloxane) copolymer having a general formula: (HSiO.sub.1.5).sub.a (HSiO(OR)).sub.b (SiO.sub.2).sub.c, wherein R is a mixture of H and an alkyl group having between 1 and 4 carbon atoms; a+b+c=1; 0.5<a<0.99; 0.01<b<0.5; and 0<c<0.5; and a solvent selected from the group consisting of dialkylketals, alkylacetates, dialkylacetals, ethers, dialkyl glycol ethers, ketones, and esters, or mixtures thereof, wherein said solution for coating a semiconductor has a water content of less than about 0.5% by weight and an alcohol content of less than about 1% by weight.
Claim 3
Dependent Claim 101 words
A solution for coating a semiconductor device comprising: a poly (hydrido siloxane) copolymer having a general formula: (HSiO.sub.1.5).sub.a (HSiO(OR)).sub.b (SiO.sub.2).sub.c, wherein R is a mixture of H and an alkyl group having between 1 and 4 carbon atoms; a+b+c=1; 0.5<a<0.99; 0.01<b<0.5; and 0<c<0.5, and wherein the poly (hydrido siloxane) copolymer is produced by a process comprising: charging a reaction vessel with at least one alkoxysilane and an aprotic solvent, wherein a first reaction mixture is provided; adding an acid mixture to said first reaction mixture, wherein a second reaction mixture is provided; and polymerizing said second reaction mixture; and a 2,2-dialkoxypropane.
Claim 4
Dependent Claim 101 words
A solution for coating a semiconductor device comprising: a poly (hydrido siloxane) copolymer having a general formula: (HSiO.sub.1.5).sub.a (HSiO(OR)).sub.b (SiO.sub.2).sub.c, wherein R is a mixture of H and an alkyl group having between 1 and 4 carbon atoms; a+b+c=1; 0.5<a<0.99; 0.01<b<0.5; and 0<c<0.5, and wherein the poly (hydrido siloxane) copolymer is produced by a process comprising: charging a reaction vessel with at least one alkoxysilane and an aprotic solvent, wherein a first reaction mixture is provided; adding an acid mixture to said first reaction mixture, wherein a second reaction mixture is provided; and polymerizing said second reaction mixture; and a 2,2-dialkoxypropane.
Claim 5
Dependent Claim 24 words
The solution for coating a semiconductor device of claim 2 wherein said 2,2-dialkoxypropane is selected from the group consisting of 2,2-dimethoxypropane, 2,2-diethoxypropane, and 2-ethoxy,2-propoxypropane.
Claim 6
Dependent Claim 15 words
The solution for coating a semiconductor device of claim 2 wherein said 2,2-dialkoxypropane is 2,2-dimethoxypropane.
Claim 7
Dependent Claim 16 words
The solution for coating a semiconductor device of claim 1 wherein said solvent is a 2,2-dialkoxypropane.
Claim 8
Dependent Claim 24 words
The solution for coating a semiconductor device of claim 1 wherein said solvent is selected from the group consisting of 2,2-dimethoxypropane, 2,2-diethoxypropane, and 2-ethoxy,2-propoxypropane.
Claim 9
Dependent Claim 15 words
The solution for coating a semiconductor device of claim 1 wherein said solvent is 2,2-dimethoxypropane.
Claim 10
Dependent Claim 25 words
The solution for coating a semiconductor device of claim 1 wherein the solution is stable for at least 9 months when stored at -15° C.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2003-01-17 2003-07-19 2004-01-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2007-01-17 2007-07-19 2008-01-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2011-01-17 2011-07-19 2012-01-18 $7700.00 Window Closed / Lapsed

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