US6001727A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of making a semiconductor device
Assignee: Canon Inc
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Filing: 1997-03-28
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Granted: 1999-12-14
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Expires: 2017-03-28
Abstract
Abstract In a semiconductor device in which a wiring layer is formed on the surface of a layer having a stepped portion, the wiring layer formed contains hydrogen at least at its surface portion. In a process for fabricating the semiconductor device, hydrogen is incorporated in the wiring layer in the course of, or after, the formation of the wiring layer. In particular, the wiring is heated at a temperature of from 150° C. to 450° C. in an atmosphere containing hydrogen gas, radical hydrogen or plasma hydrogen, without the step of exposure to the atmosphere, in the course of, or after, the formation of the wiring layer. The wiring layer is formed in an Ar and/or Xe plasma containing from 0.1% to 10% of at least one of hydrogen, radical hydrogen and plasma hydrogen.
Inventors
- 👤 Tadahiro Ohmi
- 👤 Mamoru Miyawaki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 21:18
CPC Classifications
H; H10; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/056; H10W20/059; H10P; H10P95/00; H10P95/04
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
95 words
A process for forming on a surface having a stepped portion of a substrate a metal film to form a wiring, comprising: a deposition step of depositing a metal film on the substrate having the stepped portion by sputtering; and a heat treatment step of heat treating the substrate having the metal film deposited at a temperature of from 150° C. to 450° C. in an atmosphere containing at least one selected from the group consisting of hydrogen gas, radical hydrogen and plasma hydrogen, without exposure to the atmosphere, for reflowing the deposited metal film.
Claim 2
Dependent Claim
95 words
A process for forming on a surface having a stepped portion of a substrate a metal film to form a wiring, comprising: a deposition step of depositing a metal film on the substrate having the stepped portion by sputtering; and a heat treatment step of heat treating the substrate having the metal film deposited at a temperature of from 150° C. to 450° C. in an atmosphere containing at least one selected from the group consisting of hydrogen gas, radical hydrogen and plasma hydrogen, without exposure to the atmosphere, for reflowing the deposited metal film.
Claim 3
Dependent Claim
18 words
The process according to claim 1, wherein the stepped portion includes a hole provided in an insulating film.
Claim 4
Dependent Claim
20 words
The process according to claim 1, wherein the metal film contains Ge and at least one of Al and Cu.
Claim 5
Dependent Claim
17 words
The process according to claim 3, wherein the content of Ge is 0.2% to 5% by weight.
Claim 6
Dependent Claim
30 words
The process according to claim 1, further comprising, before the deposition step, the step of forming a film containing titanium on the surface of the substrate having the stepped portion.
Claim 7
Dependent Claim
32 words
The process according to claim 1, further comprising, before the deposition step, the step of forming a film containing titanium and nitrogen on the surface of the substrate having the stepped portion.
Claim 8
Dependent Claim
20 words
The process according to claim 1, wherein the pressure during the heat treatment step is 10 -7 Torr or less.
Claim 9
Dependent Claim
39 words
The process according to claim 1, further comprising, after the heat treatment step, a polishing step of polishing the surface of the metal film until a surface of an insulating film lying beneath the metal film is partly exposed.
Claim 10
Dependent Claim
71 words
The process according to claim 1, comprising using an apparatus having a barrier metal forming chamber, a deposition chamber for depositing the metal film and a heat treatment chamber for carrying out the heat treatment connected to one another via a load lock chamber, wherein, after a barrier metal is formed on the surface having the stepped portion of the substrate, the deposition and the heat treatment steps are carried out.
Claim 11
Dependent Claim
46 words
The process according to claim 1, wherein the stepped portion forms a contact hole, and further comprising the steps of: forming an insulating film on the metal film; forming a through-hole in the insulating film on the contact hole; and depositing a metal in the through-hole.
Claim 12
Dependent Claim
60 words
A process for forming a metal film on a substrate surface to form a wiring, comprising: forming a stepped portion on the surface of the substrate; and depositing a metal film on the stepped portion of the substrate by sputtering in an atmosphere containing at least one selected from the group consisting of hydrogen gas, radical hydrogen and plasma hydrogen.
Claim 13
Dependent Claim
60 words
A process for forming a metal film on a substrate surface to form a wiring, comprising: forming a stepped portion on the surface of the substrate; and depositing a metal film on the stepped portion of the substrate by sputtering in an atmosphere containing at least one selected from the group consisting of hydrogen gas, radical hydrogen and plasma hydrogen.
Claim 14
Dependent Claim
33 words
The process according to claim 11, wherein the atmosphere is established by supplying a reaction chamber with hydrogen gas at a flow rate ratio of from 0.1% to 10% based on another gas.
Claim 15
Dependent Claim
20 words
The process according to claim 11, wherein the stepped portion is formed by removing a portion of an insulating film.
Claim 16
Dependent Claim
20 words
The process according to claim 11, wherein the metal film contains Ge and at least one of Al and Cu.
Claim 17
Dependent Claim
18 words
The process according to claim 14, wherein the content of Ge is approximately 0.2% to 5% by weight.
Claim 18
Dependent Claim
25 words
The process according to claim 11, further comprising: forming a film containing titanium on the stepped portion of the substrate prior to the deposition step.
Claim 19
Dependent Claim
27 words
The process according to claim 11, further comprising: forming a film containing titanium and nitrogen on the stepped portion of the substrate prior to the deposition step.
Claim 20
Dependent Claim
20 words
The process according to claim 11, wherein the pressure during the heat treatment step is 10 -7 Torr or less.
Claim 21
Dependent Claim
34 words
The process according to claim 11, further comprising: a polishing step for polishing the surface of the metal film until a surface of an insulating film lying beneath the metal film is partially exposed.
Claim 22
Dependent Claim
54 words
The process according to claim 11, wherein the metal film is deposited using an apparatus having a barrier metal forming chamber and a deposition chamber connected to one another via a load lock chamber, wherein, after a barrier metal is formed on the stepped surface of the substrate, the deposition step is carried out.
Claim 23
Dependent Claim
43 words
The process according to claim 11, wherein the stepped portion forms a contact hole, and further comprising: forming an insulating film on the metal film; forming a through-hole in the insulating film on the contact hole; and depositing a metal in the through-hole.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2002-12-13 | 2003-06-14 | 2003-12-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2006-12-13 | 2007-06-14 | 2007-12-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2010-12-13 | 2011-06-14 | 2011-12-14 | $7700.00 | Window Closed / Lapsed |