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US6066358A Expired / Lapsed US ⏱️ 0.0 years remaining

Blanket-selective chemical vapor deposition using an ultra-thin nucleation layer

Assignee: Applied Materials Inc
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Filing: 1996-03-05
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Granted: 2000-05-23
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Expires: 2016-03-05
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Abstract

Abstract The present invention relates generally to an improved apparatus and process for providing uniform step coverage on a substrate and planarization of conducting layers to form continuous, void-free interconnects in sub-half micron, high aspect ratio aperture width applications and highly oriented conducting layers. In one aspect of the invention, a dielectric layer is formed over a conducting or semiconducting layer and etched to form an aperture exposing the underlying conducting or semiconducting layer on the aperture floor. An ultra-thin nucleation layer is then deposited by physical vapor deposition onto the field of the dielectric layer. A CVD metal layer is then deposited onto the structure to achieve selective deposition on the floor of the aperture, while preferably also forming a highly oriented blanket layer on the field. The present apparatus and process reduce the number of steps necessary to fabricate CVD metal interconnects and layers that are substantially void-free and planarized. The metallization process is preferably carried out in an integrated processing system that includes both a PVD and CVD processing chamber so that once the substrate is introduced into a vacuum environment, the metallization of the apertures to form vias and contacts occurs without the formation of oxides between the layers.

Inventors

  • 👤 Ted Guo
  • 👤 Liang Chen
  • 👤 Fusen Chen
  • 👤 Roderick C. Mosely

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 01:38
CPC Classifications
H; H10; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/032; H10W20/042; H10W20/045; C; C23; C23C; C23C14/00; C23C14/22; C23C14/56; C23C14/568; C23C16/00; C23C16/44; C23C16/54; H10P; H10P14/00; H10P14/40; H10P14/412; H10W20/033; H10W20/056; H10W20/057

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 75 words
A method of selectively filling an aperture formed in a dielectric layer and exposing an underlying conducting layer, comprising the steps of: a) physical vapor depositing a nucleation layer having a thickness of about 50 Å or less over a field of the dielectric layer; and b) chemical vapor depositing a metal selectively on a floor of the aperture at a first rate and on the field of the dielectric layer at a second rate.
Claim 2
Independent Claim 75 words
A method of selectively filling an aperture formed in a dielectric layer and exposing an underlying conducting layer, comprising the steps of: a) physical vapor depositing a nucleation layer having a thickness of about 50 Å or less over a field of the dielectric layer; and b) chemical vapor depositing a metal selectively on a floor of the aperture at a first rate and on the field of the dielectric layer at a second rate.
Claim 3
Dependent Claim 18 words
The method of claim 1 wherein the aperture has a depth:width aspect ratio of at least about 3:1.
Claim 4
Dependent Claim 20 words
The method of claim 1 wherein substantially no nucleation material is deposited on one or more walls of the aperture.
Claim 5
Dependent Claim 49 words
The method of claim 1 further comprising the step of: c) physical vapor depositing a second metal over the chemical vapor deposited metal at a temperature below about 660° C. to cause the CVD metal and the PVD second metal to flow into the aperture without voids forming therein.
Claim 6
Dependent Claim 28 words
The method of claim 4, wherein the PVD second metal comprises aluminum, and wherein the physical vapor deposition of aluminum occurs at a temperature below about 400° C.
Claim 7
Dependent Claim 32 words
The method of claim 5, wherein the PVD aluminum comprises a dopant, the method further comprising the step of annealing at a temperature of between about 250° C. and about 350° C.
Claim 8
Dependent Claim 13 words
The method of claim 1, wherein the nucleation layer is a discontinuous layer.
Claim 9
Dependent Claim 30 words
The method of claim 7, wherein the nucleation layer is selected from the group consisting of titanium, titanium nitride, aluminum, niobium, aluminum silicates, silica, high alumina, silicon, copper and tantalum.
Claim 10
Dependent Claim 21 words
The method of claim 1, wherein the nucleation layer comprises discrete nucleation sites deposited on the field of the dielectric layer.
Claim 11
Dependent Claim 19 words
The method of claim 1, wherein the metal is selected from the group comprising aluminum, copper or combinations thereof.
Claim 12
Dependent Claim 16 words
The method of claim 1, wherein the method is carried out in an integrated processing system.
Claim 13
Dependent Claim 58 words
In a selective chemical vapor deposition process for filling high aspect ratio interconnects formed through a dielectric layer, the improvement comprising the step of: a) physical vapor depositing a discontinuous nucleation layer having a thickness of about 50 Å or less over a field of the dielectric layer prior to chemical vapor depositing a metal in the interconnects.
Claim 14
Dependent Claim 58 words
In a selective chemical vapor deposition process for filling high aspect ratio interconnects formed through a dielectric layer, the improvement comprising the step of: a) physical vapor depositing a discontinuous nucleation layer having a thickness of about 50 Å or less over a field of the dielectric layer prior to chemical vapor depositing a metal in the interconnects.
Claim 15
Independent Claim 67 words
A method of preventing nodule formation on a dielectric surface during selective chemical vapor deposition of a metal on an underlying metal surface of an aperture, the method comprising the step of: a) physical vapor depositing a nucleation layer having a thickness of about 50 Å or less on the dielectric surface to nucleate substantially uniform growth of a chemical vapor deposited film on the dielectric surface.
Claim 16
Independent Claim 67 words
A method of preventing nodule formation on a dielectric surface during selective chemical vapor deposition of a metal on an underlying metal surface of an aperture, the method comprising the step of: a) physical vapor depositing a nucleation layer having a thickness of about 50 Å or less on the dielectric surface to nucleate substantially uniform growth of a chemical vapor deposited film on the dielectric surface.
Claim 17
Dependent Claim 32 words
The method of claim 13 wherein the nucleation layer provides controlled growth of a film on the dielectric layer at a rate slower than the selective deposition on the underlying metal surface.
Claim 18
Dependent Claim 11 words
The method of claim 13 wherein the nucleation layer is discontinuous.
Claim 19
Independent Claim 72 words
A method of providing a reflective film layer adjacent to an aperture in an underlying film layer on a substrate, comprising the steps of: a) providing a conformal film layer over the underlaying layer and the aperture; then b) depositing a flux of sputtered refractory material having a thickness of about 50 Å or less on the substrate; and then c) depositing a conductor over the flux and the underlying film layer.
Claim 20
Independent Claim 72 words
A method of providing a reflective film layer adjacent to an aperture in an underlying film layer on a substrate, comprising the steps of: a) providing a conformal film layer over the underlaying layer and the aperture; then b) depositing a flux of sputtered refractory material having a thickness of about 50 Å or less on the substrate; and then c) depositing a conductor over the flux and the underlying film layer.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2003-05-23 2003-11-22 2004-05-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2007-05-23 2007-11-22 2008-05-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2011-05-23 2011-11-22 2012-05-23 $7700.00 Window Closed / Lapsed

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