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US6458516B1 Expired / Lapsed US ⏱️ 0.0 years remaining

Method of etching dielectric layers using a removable hardmask

Assignee: Applied Materials Inc
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Filing: 2000-04-18
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Granted: 2002-10-01
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Expires: 2020-04-18
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Abstract

Abstract A method of patterning a layer of dielectric material having a thickness greater than 1,000 Å, and typically a thickness greater than 5,000 Å. The method is particularly useful for forming a high aspect ratio via or a high aspect ratio contact including self-aligned contact structures, where the aspect ratio is typically greater than 3 and the feature size of the contact is about 0.25 μm or less. In particular, an organic, polymeric-based masking material is used in a plasma etch process for transferring a desired pattern through an underlying layer of dielectric material. The combination of masking material and plasma source gas must provide the necessary high selectivity toward etching of the underlying layer of dielectric material. The selectivity is preferably greater than 3:1, where the etch rate of the dielectric material is at least 3 times greater than the etch rate of the organic, polymeric-based masking material. The dielectric material may be inorganic, for example, silicon oxide; doped silicon oxide; carbon-containing silicon oxide; SOG; BPSG; and similar materials. The dielectric material may be also be organic, where a high temperature organic-based masking material is used for transferring a desired pattern, and the underlying dielectric material is of a chemical and structural composition which is sufficiently different from the masking material that the required selectivity is provided. In any case, the organic, polymeric-based masking material is easily removed from the substrate etch process after completion of etch without damage to underlying device structures.

Inventors

  • 👤 Yan Ye
  • 👤 Pavel Ionov
  • 👤 Allen Zhao
  • 👤 Peter Hsieh
  • 👤 Diana Ma
  • 👤 Chun Yan
  • 👤 Jie Yuan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 19:12
CPC Classifications
H; H10; H10P; H10P50/00; H10P50/20; H10P50/28; H10P50/286; H10P50/287; H10P50/71; H10P50/73; H10P76/00; H10P76/20; H10P76/204; H10P76/2041; H10P14/00; H10P14/60; H10P14/63; H10P14/6326; H10P14/6328; H10P14/6334; H10P14/6336; H10P14/68; H10P14/683; H10P14/687; H10P14/69; H10P14/6902; H10P50/26; H10P50/264; H10P50/266; H10P50/267; H10P50/282; H10P50/283

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 82 words
A method of patterning semiconductor device features comprising the steps of: (a) patterning a high-temperature inorganic masking material; (b) transferring said pattern from an inorganic mask created in step (a) through an underlying layer of an organic, polymeric-based masking material; (c) transferring said pattern from an organic, polymeric-based mask created in step (b) through at least one feature layer underlying said organic, polymeric-based mask, wherein said at least one feature layer comprises a dielectric material having a thickness greater than 1,000 Å.
Claim 2
Independent Claim 82 words
A method of patterning semiconductor device features comprising the steps of: (a) patterning a high-temperature inorganic masking material; (b) transferring said pattern from an inorganic mask created in step (a) through an underlying layer of an organic, polymeric-based masking material; (c) transferring said pattern from an organic, polymeric-based mask created in step (b) through at least one feature layer underlying said organic, polymeric-based mask, wherein said at least one feature layer comprises a dielectric material having a thickness greater than 1,000 Å.
Claim 3
Dependent Claim 15 words
The method of claim 1 , wherein said dielectric material is an inorganic dielectric material.
Claim 4
Dependent Claim 30 words
The method of claim 2 , wherein said inorganic dielectric material is selected from the group consisting of silicon-comprising materials which also contain atoms of O, C, H, or N.
Claim 5
Dependent Claim 38 words
The method of claim 3 , wherein said inorganic dielectric material is selected from the group consisting of silicon oxide, doped silicon oxide, silicon oxynitride, carbon-containing silicon oxide, BPSG, FSG, SOG, silicon nitride, silicon carbide, and combinations thereof.
Claim 6
Dependent Claim 15 words
The method of claim 1 , wherein said dielectric material is an organic dielectric material.
Claim 7
Dependent Claim 40 words
The method of claim 5 , wherein said organic dielectric material is selected from the group consisting of Poly(arylene)ethers, Poly(arylene)ether oxazoles, Parylene-N, Polyimides, Polynaphthalene-N, Polyphenyl-Quinoxalines, Polybenzoxazoles, Polyindane, Polynorborene, Polystyrene, Polyphenyleneoxide, Polyethylene, Polypropylene, divinylsiloxane bis-benzocyclobutene (BCB) αC, αFC, and combinations thereof.
Claim 8
Dependent Claim 39 words
The method of claim 6 , wherein said organic dielectric material is a low k dielectric material selected from the group consisting of Poly(arylene)ethers, Poly(arylene)ether oxazoles, Parylene-N, Polyimides, Polynaphthalene-N, Polyphenyl-Quinoxalines, Polybenzoxazoles, Polyindane, Polynorborene, Polyphenyleneoxide, αC, αFC, and combinations thereof.
Claim 9
Dependent Claim 30 words
The method of claim 1 , including an additional step subsequent to step (c): (d) removing residual organic, polymeric-based masking layer material from a surface of said underlying feature layer.
Claim 10
Dependent Claim 31 words
The method of claim 1 , including an additional step following step (b), said step comprising: (b-2) removing any portion of said high-temperature inorganic masking material which remains after step (b).
Claim 11
Dependent Claim 24 words
The method of claim 1 , wherein said step (b) transfer through said organic polymeric-based masking material is achieved using an anisotropic plasma etch.
Claim 12
Dependent Claim 19 words
The method of claim 1 , wherein said step (c) pattern transfer is achieved using an anisotropic plasma etch.
Claim 13
Dependent Claim 31 words
The method of claim 1 , wherein the ratio of the etch rate of said dielectric material to the etch rate of said organic, polymeric-based masking layer is at least 3:1.
Claim 14
Independent Claim 92 words
A method of patterning semiconductor device features comprising the steps of: (a) patterning a layer of high-temperature imagable organo-silicon-based material; (b) transferring a pattern from said patterned high-temperature organo-silicon-based layer created in step (a) through a layer of a high temperature organic-based masking material; (c) transferring a pattern from said patterned high temperature organic-based masking material layer created in step (b) through at least one feature layer underlying said patterned high temperature organic-based material, wherein said at least one feature layer comprises a dielectric material having a thickness greater than 1,000 Å.
Claim 15
Independent Claim 92 words
A method of patterning semiconductor device features comprising the steps of: (a) patterning a layer of high-temperature imagable organo-silicon-based material; (b) transferring a pattern from said patterned high-temperature organo-silicon-based layer created in step (a) through a layer of a high temperature organic-based masking material; (c) transferring a pattern from said patterned high temperature organic-based masking material layer created in step (b) through at least one feature layer underlying said patterned high temperature organic-based material, wherein said at least one feature layer comprises a dielectric material having a thickness greater than 1,000 Å.
Claim 16
Dependent Claim 21 words
The method of claim 13 , wherein said high temperature organic-based masking material is a CVD deposited α-C or α-FC film.
Claim 17
Dependent Claim 53 words
The method of claim 14 , wherein said CVD deposited α-C or α-FC film is formed from a starting material selected from the group consisting of CH 4 , C 2 H 2 , CF 4 , C 2 F 6 , C 4 F 8 , NF 3 , and combinations thereof.
Claim 18
Dependent Claim 15 words
The method of claim 13 , wherein said dielectric material is an inorganic dielectric material.
Claim 19
Dependent Claim 28 words
The method of claim 16 , wherein said inorganic dielectric material is selected from the group consisting of silicon-comprising materials which also contain O, C, H, or N.
Claim 20
Dependent Claim 38 words
The method of claim 17 , wherein said inorganic dielectric material is selected from the group consisting of silicon oxide, doped silicon oxide, silicon oxynitride, carbon-containing silicon oxide, BPSG, FSG, SOG, silicon nitride, silicon carbide, and combinations thereof.
Claim 21
Dependent Claim 15 words
The method of claim 13 , wherein said dielectric material is an organic dielectric material.
Claim 22
Dependent Claim 15 words
The method of claim 14 , wherein said dielectric material is an organic dielectric material.
Claim 23
Dependent Claim 38 words
The method of claim 20 , wherein said organic dielectric material is selected from the group consisting of Poly(arylene)ethers, Poly(arylene)ether oxazoles, Parylene-N, Polyimides, Polynaphthalene-N, Polyphenyl-Quinoxalines, Polybenzoxazoles, Polyindane, Polynorborene, Polystyrene, Polyphenyleneoxide, Polyethylene, Polypropylene, divinylsiloxane bis-benzocyclobutene (BCB) and combinations thereof.
Claim 24
Dependent Claim 22 words
The method of claim 13 , wherein residual high-temperature organic-based masking layer material present after step (b) is removed using plasma etching.
Claim 25
Dependent Claim 32 words
The method of claim 13 , wherein residual high-temperature organic-based masking layer material present after step( b) is removed using a combination of enhanced physical bombardment with a chemically reactive ion component.

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