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US5612304A Expired / Lapsed US ⏱️ 0.0 years remaining

Redox reagent-containing post-etch residue cleaning composition

Assignee: OCG Microelectronic Materials Inc
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Filing: 1995-07-07
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Granted: 1997-03-18
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Expires: 2015-07-07
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Abstract

Abstract A noncorrosive post-etch residue cleaning composition containing: (a) 1-70% by weight of an organic polar solvent having a dipole moment of more than 3.5; (b) 1-70% by weight of selected amine compounds having at least one hydroxyl group and a boiling point higher than 150° C. at atmospheric pressure; (c) 0.1-10% by weight of selected amino acid having at least one hydroxyl group; (d) 1-20% by weight of selected redox reagent having a redox potential in the range between +1.0 V and -2.0 V vs. SHE (at pH=7); and (e) 0-90% by weight of water.

Inventors

  • 👤 Kenji Honda
  • 👤 Rodney Hurditch

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 09:40
CPC Classifications
C; C11; C11D; C11D7/00; C11D7/22; C11D7/32; C11D7/3209; C11D3/00; C11D3/0005; C11D3/0073; C11D7/26; C11D7/261; C11D7/268; C11D7/3218; C11D7/3245; C11D7/3281; C11D7/50; C11D7/5004; C11D7/5009; C11D7/5013; G; G03; G03F; G03F7/00; G03F7/26; G03F7/42; G03F7/422; G03F7/425; H; H10; H10P; H10P95/00; H10P95/08; C11D7/34

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 270 words
A post-etch residue cleaner composition, comprising: (a) from about 1 to about 70% by weight of an organic polar solvent having a dipole moment of more than 3.5; (b) from about 1 to about 70% by weight of an alkanolamine compound having a boiling point higher than 150° C. at atmospheric pressure; (c) from about 0.1 to about 10% by weight of an amino acid selected from the group consisting of compounds having the formula (I): ##STR4## wherein p is an integer ranging from 1-3; R 1 and R 2 are each independently selected from the group consisting of hydrogen and compounds having the formula (II): ##STR5## wherein R 5 , R 6 , and R 7 are each independently selected from hydrogen, --OH, --CH 2 OH, alkyl, alkoxy, phenyl, and mono-, di- or tri-hydroxy-substituted phenyl groups; and R 3 and R 4 are each independently selected from the group consisting of hydroxy and compounds having the formula (III): ##STR6## wherein X', Y', and Z' are each independently selected from hydrogen, --OH, --CH 2 OH, --CH 2 CH 2 OH, alkyl, or alkoxy group, and at least one of them is --OH, --CH 2 OH or --CH 2 CH 2 OH; (d) from about 1 to about 20% by weight of a redox reagent having a redox potential in the range between +1.0 V and -2.0 V vs. SHE (at pH=7) selected from the group consisting of sugar alcohols, piperidine, aniline, o-phenylenediamine, hydrazine, 1,10-phenanthroline and benzidine; and (e) optionally, from about 0% to about 90% by weight of water; all percents based on the total weight of the cleaner composition.
Claim 2
Dependent Claim 270 words
A post-etch residue cleaner composition, comprising: (a) from about 1 to about 70% by weight of an organic polar solvent having a dipole moment of more than 3.5; (b) from about 1 to about 70% by weight of an alkanolamine compound having a boiling point higher than 150° C. at atmospheric pressure; (c) from about 0.1 to about 10% by weight of an amino acid selected from the group consisting of compounds having the formula (I): ##STR4## wherein p is an integer ranging from 1-3; R 1 and R 2 are each independently selected from the group consisting of hydrogen and compounds having the formula (II): ##STR5## wherein R 5 , R 6 , and R 7 are each independently selected from hydrogen, --OH, --CH 2 OH, alkyl, alkoxy, phenyl, and mono-, di- or tri-hydroxy-substituted phenyl groups; and R 3 and R 4 are each independently selected from the group consisting of hydroxy and compounds having the formula (III): ##STR6## wherein X', Y', and Z' are each independently selected from hydrogen, --OH, --CH 2 OH, --CH 2 CH 2 OH, alkyl, or alkoxy group, and at least one of them is --OH, --CH 2 OH or --CH 2 CH 2 OH; (d) from about 1 to about 20% by weight of a redox reagent having a redox potential in the range between +1.0 V and -2.0 V vs. SHE (at pH=7) selected from the group consisting of sugar alcohols, piperidine, aniline, o-phenylenediamine, hydrazine, 1,10-phenanthroline and benzidine; and (e) optionally, from about 0% to about 90% by weight of water; all percents based on the total weight of the cleaner composition.
Claim 3
Dependent Claim 14 words
The cleaner composition of claim 1, wherein said solvent (a) comprises a cyclic amide.
Claim 4
Dependent Claim 20 words
The cleaner composition of claim 2, wherein said cyclic amide is selected from the group consisting of N-alkyl-2-pyrrolidones and 1,3-dialkyl-2-imidazolidinones.
Claim 5
Dependent Claim 33 words
The cleaner composition of claim 2, wherein said solvent (a) is an admixture of N-hydroxyethyl-pyrrolididone (HEP) with 1,3-dimethyl-2-imidozolidinone (DMI) wherein the ratio of HEP:DMI is from about 95:5% to about 5:95% by weight.
Claim 6
Dependent Claim 12 words
The cleaner composition of claim 1, wherein said solvent (a) comprises dimethylsulfoxide.
Claim 7
Dependent Claim 32 words
The cleaner composition of claim 1, wherein said solvent (a) is an admixture of N-hydroxyethyl-pyrrolididone (HEP) with dimethylsulfoxide (DMSO) wherein the ratio of HEP:DMSO is from 95:5% to about 5.95% by weight.
Claim 8
Dependent Claim 22 words
The cleaner composition of claim 12, wherein said alkanolamine is selected from the group consisting of monoethanolamine, diethanolamine, triethanolamine, 2-(2-aminoethoxy)ethanol and 2-(2-aminoethylamino)ethanol.
Claim 9
Dependent Claim 15 words
The cleaner composition of claim 1, wherein said redox reagent (d) is a sugar alcohol.
Claim 10
Dependent Claim 21 words
The cleaner composition of claim 8, wherein said sugar alcohol is selected from the group consisting of erythritols, penitols, and hexitols.
Claim 11
Dependent Claim 24 words
The cleaner composition of claim 9, wherein said sugar alcohol is a penitol and is selected from the group consisting of D-arabitol and D-xylitol.
Claim 12
Dependent Claim 24 words
The cleaner composition of claim 9, wherein said sugar alcohol is a hexitol and is selected from the group consisting of D-sorbitol and D-mannitol.
Claim 13
Dependent Claim 13 words
The cleaner composition of claim 1, wherein said redox reagent (d) is piperidine.
Claim 14
Dependent Claim 13 words
The cleaner composition of claim 1, wherein said redox reagent (d) is aniline.
Claim 15
Dependent Claim 13 words
The cleaner composition of claim 1, wherein said redox reagent (d) is o-phenylenediamine.
Claim 16
Dependent Claim 13 words
The cleaner composition of claim 1, wherein said redox reagent (d) is hydrazine.
Claim 17
Dependent Claim 13 words
The cleaner composition of claim 1, wherein said redox reagent (d) is 1,10-phenanthroline.
Claim 18
Dependent Claim 13 words
The cleaner composition of claim 1, wherein said redox reagent (d) is benzidine.
Claim 19
Dependent Claim 30 words
The cleaner composition of claim 1, wherein said redox reagent (d) is present from about 3% to about 10% by weight, based on the total weight of said cleaner composition.
Claim 20
Dependent Claim 43 words
The cleaner composition of claim 1, wherein said amino acid (c) is selected from the group consisting of tricine, bicine, DL-homoserine, D-homoserine, L-homoserine, DL-threonine, D-allo-threonine, L-allo-threonine, D-threonine, L-threonine, DL-3-hydroxy-norvaline, DL-methyltyrosine, D-4-hydroxyphenylglycine, DL-tyrosine, D-tyrosine, L-tyrosine, 3-(3,4-dihydroxyphenyl)-DL-alanine, 3-(3,4-dihydroxyphenyl)-L-alanine, 3-(2,4,5-trihydroxyphenyl)-DL-alanine, DL-alphamethyltyrosine, L-alpha-methyltyrosine, (--)-3-(3,4-dihydroxyphenyl)-2-methyl-L-alanine, DL-threo-3-phenylserine, and DL-threo-3,4-dihydroxyphenylserine.
Claim 21
Dependent Claim 23 words
The cleaner composition of claim 18, wherein said amino acid is selected from the group consisting of tricine, bicine, 3-(3,4-dihydroxyphenyl)-DL-alanine, 3-(2,4,5-trihydroxyphenyl)-DL-alanine, and DL-threo-3,4-dihydroxyphenylserine.
Claim 22
Dependent Claim 13 words
The cleaner composition of claim 1, wherein said cleaner composition further comprises water.

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