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US5334332A Expired / Lapsed US ⏱️ 0.0 years remaining

Cleaning compositions for removing etching residue and method of using

Assignee: EKC Technology Inc
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Filing: 1992-07-09
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Granted: 1994-08-02
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Expires: 2012-07-09
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Abstract

Abstract A stripping and cleaning composition for removing resists and etching residue from substrates containing hydroxylamine and at least one alkanolamine is described. Further, a cleaning composition for removing etching residue from semiconductor substrates containing hydroxylamine, at least one alkanolamine, at least one chelating agent, and water is described. The preferred chelating agent is 1,2-dihydroxybenzene or a derivative thereof. The chelating agent provides added stability and effectiveness to the cleaning composition.

Inventors

  • 👤 Wai M. Lee

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 18:07
CPC Classifications
H; H10; H10P; H10P70/00; H10P70/20; H10P70/27; H10P70/273; B; B24; B24B; B24B37/00; B24B37/04; B24B37/042; C; C09; C09D; C09D9/00; C11; C11D; C11D3/00; C11D3/16; C11D3/20; C11D3/2003; C11D3/2041; C11D3/2058; C11D3/2065; C11D3/2075; C11D3/2086; C11D3/26; C11D3/30; C11D3/34; C11D3/3427; C11D3/3472; C11D3/43; C11D7/00; C11D7/22; C11D7/26; C11D7/261; C11D7/262; C11D7/263; C11D7/265; C11D7/267; C11D7/32; C11D7/3209; C11D7/3218; C11D7/3227; C11D7/3245; C11D7/3254; C11D7/3263; C11D7/3272; C11D7/3281; C11D7/34; C11D7/50; C11D7/5004; C11D7/5013; C23; C23G; C23G1/00; C23G1/02; C23G1/10; C23G1/103; C23G1/14; C23G1/20; C23G1/205; G; G03; G03F; G03F7/00; G03F7/26; G03F7/42; G03F7/422; G03F7/423; G03F7/425; H10P50/00; H10P50/20; H10P50/28; H10P50/286; H10P50/287; H10P70/23; H10P70/234; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/063; H10W20/071; H10W20/081; C11D2111/00; C11D2111/10; C11D2111/14; C11D2111/22; C11D2111/24; H10P70/10; H10P70/15

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 67 words
A composition for removing etching residue from a resist-free substrate, said composition consisting essentially of 5-50% hydroxylamine, 10-80% of at least one alkanolamine which is miscible with said hydroxylamine and a balance of water wherein said hydroxylamine and said alkanolamine are present in sufficient amounts to remove etching residue from said resist-free substrate and said resist was removed from said substrate by means other than said composition.
Claim 2
Dependent Claim 67 words
A composition for removing etching residue from a resist-free substrate, said composition consisting essentially of 5-50% hydroxylamine, 10-80% of at least one alkanolamine which is miscible with said hydroxylamine and a balance of water wherein said hydroxylamine and said alkanolamine are present in sufficient amounts to remove etching residue from said resist-free substrate and said resist was removed from said substrate by means other than said composition.
Claim 3
Dependent Claim 59 words
A composition for removing etching residue from a substrate consisting essentially of 5-50% hydroxylamine, 10-80% of at least one alkanolamine which is miscible with said hydroxylamine, 5-30% of at least one chelating agent, and a balance of water wherein the hydroxylamine, said alkanolamine and said chelating agent are present in sufficient amounts to remove etching residue from a substrate.
Claim 4
Dependent Claim 59 words
A composition for removing etching residue from a substrate consisting essentially of 5-50% hydroxylamine, 10-80% of at least one alkanolamine which is miscible with said hydroxylamine, 5-30% of at least one chelating agent, and a balance of water wherein the hydroxylamine, said alkanolamine and said chelating agent are present in sufficient amounts to remove etching residue from a substrate.
Claim 5
Dependent Claim 19 words
A composition according to claim 1 wherein said at least one chelating agent is 1,2-dihydroxybenzene or a derivative thereof.
Claim 6
Dependent Claim 65 words
A composition for removing etching residue from a substrate consisting essentially of 5-50% hydroxylamine, 10-80% of at least one alkanolamine which is miscible with said hydroxylamine, 5-30% of a chelating agent having a formula ##STR7## wherein R═OH or COOH, and a balance of water wherein the hydroxylamine, said alkanolamine, and said chelating agent are present in sufficient amounts to remove etching residue from a substrate.
Claim 7
Dependent Claim 65 words
A composition for removing etching residue from a substrate consisting essentially of 5-50% hydroxylamine, 10-80% of at least one alkanolamine which is miscible with said hydroxylamine, 5-30% of a chelating agent having a formula ##STR7## wherein R═OH or COOH, and a balance of water wherein the hydroxylamine, said alkanolamine, and said chelating agent are present in sufficient amounts to remove etching residue from a substrate.
Claim 8
Dependent Claim 86 words
A composition for removing etching residue from a substrate consisting essentially of 5-50% hydroxylamine, 10-80% of at least one alkanolamine which is miscible with said hydroxylamine, 5-30% of a chelating agent having a formula of ##STR8## wherein R 1 , R 2 , R 3 and R 4 ═H or NH 4 , or the ammonium salt of said compound, and a balance of water wherein the hydroxylamine, said alkanolamine, and said chelating agent are present in sufficient amounts to remove etching residue from a substrate.
Claim 9
Dependent Claim 86 words
A composition for removing etching residue from a substrate consisting essentially of 5-50% hydroxylamine, 10-80% of at least one alkanolamine which is miscible with said hydroxylamine, 5-30% of a chelating agent having a formula of ##STR8## wherein R 1 , R 2 , R 3 and R 4 ═H or NH 4 , or the ammonium salt of said compound, and a balance of water wherein the hydroxylamine, said alkanolamine, and said chelating agent are present in sufficient amounts to remove etching residue from a substrate.
Claim 10
Dependent Claim 30 words
A composition according to either of claim 1, 2, 3, 4, or 5 wherein the alkanol group of said at least one alkanolamine contains from 1 to 5 carbon atoms.
Claim 11
Dependent Claim 31 words
A composition according to either of claim 1, 2, 3, 4, or 5 wherein said at least one alkanolamine is selected from a group consisting essentially of monoamines, diamines, and triamines.
Claim 12
Dependent Claim 64 words
A composition according to either of claim 1, 2, 3, 4, or 5 wherein said at least one alkanolamine has the formula R 1 R 2 --N--CH 2 CH 2 --O--R 3 wherein R 1 and R 2 can be H, CH 3 , CH 3 CH 2 , or CH 2 CH 2 OH and R 3 is CH 2 CH 2 OH.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-08-01 1998-01-31 1998-08-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-08-01 2002-01-31 2002-08-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-08-01 2006-01-31 2006-08-02 $7700.00 Window Closed / Lapsed

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