US5612304A
Expired / Lapsed
US
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Redox reagent-containing post-etch residue cleaning composition
Assignee: OCG Microelectronic Materials Inc
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Filing: 1995-07-07
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Granted: 1997-03-18
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Expires: 2015-07-07
Abstract
Abstract A noncorrosive post-etch residue cleaning composition containing: (a) 1-70% by weight of an organic polar solvent having a dipole moment of more than 3.5; (b) 1-70% by weight of selected amine compounds having at least one hydroxyl group and a boiling point higher than 150° C. at atmospheric pressure; (c) 0.1-10% by weight of selected amino acid having at least one hydroxyl group; (d) 1-20% by weight of selected redox reagent having a redox potential in the range between +1.0 V and -2.0 V vs. SHE (at pH=7); and (e) 0-90% by weight of water.
Inventors
- 👤 Kenji Honda
- 👤 Rodney Hurditch
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 06:05
CPC Classifications
C; C11; C11D; C11D7/00; C11D7/22; C11D7/32; C11D7/3209; C11D3/00; C11D3/0005; C11D3/0073; C11D7/26; C11D7/261; C11D7/268; C11D7/3218; C11D7/3245; C11D7/3281; C11D7/50; C11D7/5004; C11D7/5009; C11D7/5013; G; G03; G03F; G03F7/00; G03F7/26; G03F7/42; G03F7/422; G03F7/425; H; H10; H10P; H10P95/00; H10P95/08; C11D7/34
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
270 words
A post-etch residue cleaner composition, comprising: (a) from about 1 to about 70% by weight of an organic polar solvent having a dipole moment of more than 3.5; (b) from about 1 to about 70% by weight of an alkanolamine compound having a boiling point higher than 150° C. at atmospheric pressure; (c) from about 0.1 to about 10% by weight of an amino acid selected from the group consisting of compounds having the formula (I): ##STR4## wherein p is an integer ranging from 1-3; R 1 and R 2 are each independently selected from the group consisting of hydrogen and compounds having the formula (II): ##STR5## wherein R 5 , R 6 , and R 7 are each independently selected from hydrogen, --OH, --CH 2 OH, alkyl, alkoxy, phenyl, and mono-, di- or tri-hydroxy-substituted phenyl groups; and R 3 and R 4 are each independently selected from the group consisting of hydroxy and compounds having the formula (III): ##STR6## wherein X', Y', and Z' are each independently selected from hydrogen, --OH, --CH 2 OH, --CH 2 CH 2 OH, alkyl, or alkoxy group, and at least one of them is --OH, --CH 2 OH or --CH 2 CH 2 OH; (d) from about 1 to about 20% by weight of a redox reagent having a redox potential in the range between +1.0 V and -2.0 V vs. SHE (at pH=7) selected from the group consisting of sugar alcohols, piperidine, aniline, o-phenylenediamine, hydrazine, 1,10-phenanthroline and benzidine; and (e) optionally, from about 0% to about 90% by weight of water; all percents based on the total weight of the cleaner composition.
Claim 2
Dependent Claim
270 words
A post-etch residue cleaner composition, comprising: (a) from about 1 to about 70% by weight of an organic polar solvent having a dipole moment of more than 3.5; (b) from about 1 to about 70% by weight of an alkanolamine compound having a boiling point higher than 150° C. at atmospheric pressure; (c) from about 0.1 to about 10% by weight of an amino acid selected from the group consisting of compounds having the formula (I): ##STR4## wherein p is an integer ranging from 1-3; R 1 and R 2 are each independently selected from the group consisting of hydrogen and compounds having the formula (II): ##STR5## wherein R 5 , R 6 , and R 7 are each independently selected from hydrogen, --OH, --CH 2 OH, alkyl, alkoxy, phenyl, and mono-, di- or tri-hydroxy-substituted phenyl groups; and R 3 and R 4 are each independently selected from the group consisting of hydroxy and compounds having the formula (III): ##STR6## wherein X', Y', and Z' are each independently selected from hydrogen, --OH, --CH 2 OH, --CH 2 CH 2 OH, alkyl, or alkoxy group, and at least one of them is --OH, --CH 2 OH or --CH 2 CH 2 OH; (d) from about 1 to about 20% by weight of a redox reagent having a redox potential in the range between +1.0 V and -2.0 V vs. SHE (at pH=7) selected from the group consisting of sugar alcohols, piperidine, aniline, o-phenylenediamine, hydrazine, 1,10-phenanthroline and benzidine; and (e) optionally, from about 0% to about 90% by weight of water; all percents based on the total weight of the cleaner composition.
Claim 3
Dependent Claim
14 words
The cleaner composition of claim 1, wherein said solvent (a) comprises a cyclic amide.
Claim 4
Dependent Claim
20 words
The cleaner composition of claim 2, wherein said cyclic amide is selected from the group consisting of N-alkyl-2-pyrrolidones and 1,3-dialkyl-2-imidazolidinones.
Claim 5
Dependent Claim
33 words
The cleaner composition of claim 2, wherein said solvent (a) is an admixture of N-hydroxyethyl-pyrrolididone (HEP) with 1,3-dimethyl-2-imidozolidinone (DMI) wherein the ratio of HEP:DMI is from about 95:5% to about 5:95% by weight.
Claim 6
Dependent Claim
12 words
The cleaner composition of claim 1, wherein said solvent (a) comprises dimethylsulfoxide.
Claim 7
Dependent Claim
32 words
The cleaner composition of claim 1, wherein said solvent (a) is an admixture of N-hydroxyethyl-pyrrolididone (HEP) with dimethylsulfoxide (DMSO) wherein the ratio of HEP:DMSO is from 95:5% to about 5.95% by weight.
Claim 8
Dependent Claim
22 words
The cleaner composition of claim 12, wherein said alkanolamine is selected from the group consisting of monoethanolamine, diethanolamine, triethanolamine, 2-(2-aminoethoxy)ethanol and 2-(2-aminoethylamino)ethanol.
Claim 9
Dependent Claim
15 words
The cleaner composition of claim 1, wherein said redox reagent (d) is a sugar alcohol.
Claim 10
Dependent Claim
21 words
The cleaner composition of claim 8, wherein said sugar alcohol is selected from the group consisting of erythritols, penitols, and hexitols.
Claim 11
Dependent Claim
24 words
The cleaner composition of claim 9, wherein said sugar alcohol is a penitol and is selected from the group consisting of D-arabitol and D-xylitol.
Claim 12
Dependent Claim
24 words
The cleaner composition of claim 9, wherein said sugar alcohol is a hexitol and is selected from the group consisting of D-sorbitol and D-mannitol.
Claim 13
Dependent Claim
13 words
The cleaner composition of claim 1, wherein said redox reagent (d) is piperidine.
Claim 14
Dependent Claim
13 words
The cleaner composition of claim 1, wherein said redox reagent (d) is aniline.
Claim 15
Dependent Claim
13 words
The cleaner composition of claim 1, wherein said redox reagent (d) is o-phenylenediamine.
Claim 16
Dependent Claim
13 words
The cleaner composition of claim 1, wherein said redox reagent (d) is hydrazine.
Claim 17
Dependent Claim
13 words
The cleaner composition of claim 1, wherein said redox reagent (d) is 1,10-phenanthroline.
Claim 18
Dependent Claim
13 words
The cleaner composition of claim 1, wherein said redox reagent (d) is benzidine.
Claim 19
Dependent Claim
30 words
The cleaner composition of claim 1, wherein said redox reagent (d) is present from about 3% to about 10% by weight, based on the total weight of said cleaner composition.
Claim 20
Dependent Claim
43 words
The cleaner composition of claim 1, wherein said amino acid (c) is selected from the group consisting of tricine, bicine, DL-homoserine, D-homoserine, L-homoserine, DL-threonine, D-allo-threonine, L-allo-threonine, D-threonine, L-threonine, DL-3-hydroxy-norvaline, DL-methyltyrosine, D-4-hydroxyphenylglycine, DL-tyrosine, D-tyrosine, L-tyrosine, 3-(3,4-dihydroxyphenyl)-DL-alanine, 3-(3,4-dihydroxyphenyl)-L-alanine, 3-(2,4,5-trihydroxyphenyl)-DL-alanine, DL-alphamethyltyrosine, L-alpha-methyltyrosine, (--)-3-(3,4-dihydroxyphenyl)-2-methyl-L-alanine, DL-threo-3-phenylserine, and DL-threo-3,4-dihydroxyphenylserine.
Claim 21
Dependent Claim
23 words
The cleaner composition of claim 18, wherein said amino acid is selected from the group consisting of tricine, bicine, 3-(3,4-dihydroxyphenyl)-DL-alanine, 3-(2,4,5-trihydroxyphenyl)-DL-alanine, and DL-threo-3,4-dihydroxyphenylserine.
Claim 22
Dependent Claim
13 words
The cleaner composition of claim 1, wherein said cleaner composition further comprises water.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2000-03-17 | 2000-09-16 | 2001-03-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2004-03-17 | 2004-09-16 | 2005-03-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2008-03-17 | 2008-09-16 | 2009-03-18 | $7700.00 | Window Closed / Lapsed |