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US5565304A Expired / Lapsed US ⏱️ 0.0 years remaining

Chemically amplified radiation-sensitive composition used in a process for fabricating a semiconductor device

Assignee: Olin Microelectronic Chemicals Inc
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Filing: 1995-06-05
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Granted: 1996-10-15
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Expires: 2015-06-05
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Abstract

Abstract A chemically amplified-type radiation-sensitive composition comprising: (a) an alkali-soluble binder resin made by a condensation reaction of: (i) hydroxystyrene moiety having formula [1] or [2]: <IMAGE> [1] <IMAGE> [2] wherein x is an integer from 2 to 300; with (ii) a monomethylolated phenolic compound having a formula [8]: <IMAGE> [3] wherein R1 and R2 are individually selected from the group consisting of lower alkyl group having 1-4 carbon atoms, lower alkoxy group having 1-4 carbon atoms, amino group, and carboxylic acid group; wherein R3 and R4 are individually selected from the group consisting of hydrogen, lower alkyl group having 1-4 carbon atoms, lower alkoxy groups having 1-4 carbon atoms, an amino group, and a carboxylic group; and wherein a mole ratio of the hydroxystyrene moiety to the monomethylolated phenolic compound is from about 1:10 to about 10:1; (b) at least one alkaline dissolution inhibitor containing acid-cleavable groups; and (c) at least one compound that results in generation of an acidic moiety under irradiation.

Inventors

  • 👤 Kenji Honda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:35
CPC Classifications
C; C08; C08G; C08G8/00; C08G8/38; G; G03; G03F; G03F7/00; G03F7/004; G03F7/0045; G03F7/022; G03F7/023; G03F7/0233; G03F7/039; G03F7/0392; H; H10; H10P; H10P76/00; H10P76/20; H10P76/204; H10P76/2041; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/106

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 216 words
A process for fabricating a semiconductor device comprising the steps of: (1) forming a radiation-sensitive region on a device substrate; (2) exposing said region to said radiation to form a pattern; (3) developing said pattern; and (4) employing said pattern to define areas of said device; wherein said radiation-sensitive region is a radiation-sensitive composition comprising in admixture: (a) an alkali-soluble binder resin made by a condensation reaction of: (i) hydroxy styrene moiety having formula [1] or [2]: ##STR8## wherein x is an integer from 2 to 300; with (ii) a monomethylolated phenolic compound having a formula [8]: ##STR9## wherein R 1 and R 2 are individually selected from the group consisting of lower alkyl group having 1-4 carbon atoms, lower alkoxy group having 1-4 carbon atoms, amino group, and carboxylic acid group; wherein R 3 and R 4 are individually selected from the group consisting of hydrogen, lower alkyl group having 1-4 carbon atoms, lower alkoxy groups having 1-4 carbon atoms, an amino group, and a carboxylic group; and wherein a mole ratio of the hydroxystyrene moiety to the monomethylolated phenolic compound is from about 1:10 to about 10:1; (b) at least one alkaline dissolution inhibitor containing acid-cleavable groups; and (c) at least one compound that results in the generation of an acidic moiety under irradiation.
Claim 2
Dependent Claim 216 words
A process for fabricating a semiconductor device comprising the steps of: (1) forming a radiation-sensitive region on a device substrate; (2) exposing said region to said radiation to form a pattern; (3) developing said pattern; and (4) employing said pattern to define areas of said device; wherein said radiation-sensitive region is a radiation-sensitive composition comprising in admixture: (a) an alkali-soluble binder resin made by a condensation reaction of: (i) hydroxy styrene moiety having formula [1] or [2]: ##STR8## wherein x is an integer from 2 to 300; with (ii) a monomethylolated phenolic compound having a formula [8]: ##STR9## wherein R 1 and R 2 are individually selected from the group consisting of lower alkyl group having 1-4 carbon atoms, lower alkoxy group having 1-4 carbon atoms, amino group, and carboxylic acid group; wherein R 3 and R 4 are individually selected from the group consisting of hydrogen, lower alkyl group having 1-4 carbon atoms, lower alkoxy groups having 1-4 carbon atoms, an amino group, and a carboxylic group; and wherein a mole ratio of the hydroxystyrene moiety to the monomethylolated phenolic compound is from about 1:10 to about 10:1; (b) at least one alkaline dissolution inhibitor containing acid-cleavable groups; and (c) at least one compound that results in the generation of an acidic moiety under irradiation.
Claim 3
Dependent Claim 12 words
The process of claim 1 wherein said hydroxy styrene is poly (para-hydroxystyrene).
Claim 4
Dependent Claim 12 words
The process of claim 1 wherein said monomethylolated phenolic compound is 2,4-dimethyl-6-methylolphenol.
Claim 5
Dependent Claim 27 words
The process of claim 1 wherein said alkali-soluble binder resin (a) is from about 90% to about 40% by weight of the solids in said radiation-sensitive composition.
Claim 6
Dependent Claim 73 words
The process of claim 1 wherein said alkaline dissolution inhibitor (b) is selected from a family of oligomeric phenolic compounds having a molecular weight from 200 to 1,000, the hydroxyl groups of which are protected with substituents which can be deprotected in the presence of acidic compounds releasing small molecules having a molecular weight from about 20 to about 100 which do not affect the dissolution of the radiation-sensitive composition in alkali developers.
Claim 7
Dependent Claim 27 words
The process of claim 1 wherein said alkaline dissolution inhibitor (b) is from about 5% to about 30% by weight of the solids of said radiation-sensitive composition.
Claim 8
Dependent Claim 29 words
The process of claim 1 wherein said acid generating compound (c) is selected from a family of the compounds which generate small acidic molecules having pKa less than 4.
Claim 9
Dependent Claim 26 words
The process of claim 1 wherein said acid generating compound (c) is from about 5% to 30% by weight of the solids of said radiation-sensitive composition.
Claim 10
Dependent Claim 11 words
The process of claim 1 wherein said radiation comprises ultraviolet radiation.
Claim 11
Dependent Claim 15 words
The process of claim 1 wherein the source of said radiation comprises an excimer laser.
Claim 12
Dependent Claim 26 words
The process of claim 1 wherein said radiation-sensitive region is formed by coating said device substrate with the radiation-sensitive composition and spinning said coated device substrate.
Claim 13
Dependent Claim 16 words
The process of claim 1 wherein said step of employing said pattern comprises etching or metallization.

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