US4032513A
Expired / Lapsed
US
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Process of producing alkenylphenol polymers
Assignee: Maruzen Petrochemical Co Ltd
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Filing: 1976-03-30
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Granted: 1977-06-28
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Expires: 1996-03-30
Abstract
Abstract A process of producing a high molecular weight alkenylphenol polymer which comprises cationically polymerizing an alkenylphenol, such as vinylphenol, in the presence of a nitrile using a cationic polymerization initiator in a homogeneous reaction system. The resulting alkenylphenol polymer is useful as a starting material for preparing a thermosetting resin, a high molecular weight electrolytic substance, an ion exchange membrane, adhesives, glass-fiber-reinforced composite materials, etc.
Inventors
- 👤 Hiroshi Fujiwara
- 👤 Asao Takahashi
- 👤 Motomu Miyamoto
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 02:35
CPC Classifications
C; C08; C08G; C08G61/00; C08G61/02; C08F; C08F12/00; C08F12/02; C08F12/04; C08F12/14; C08F12/22; C08F12/24
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
73 words
A process of producing an alkenylphenol polymer which comprises cationically polymerizing an alkenylphenol in the presence of a nitrile using a cationic polymerization initiator, wherein said nitrile is a saturated aliphatic mononitrile or an aromatic nitrile having a boiling point below about 200° C. at 760 mm Hg and the concentration of the alkenylphenol monomer in said nitrile solution is from about 1 to about 50% based on the weight of said nitrile.
Claim 2
Dependent Claim
73 words
A process of producing an alkenylphenol polymer which comprises cationically polymerizing an alkenylphenol in the presence of a nitrile using a cationic polymerization initiator, wherein said nitrile is a saturated aliphatic mononitrile or an aromatic nitrile having a boiling point below about 200° C. at 760 mm Hg and the concentration of the alkenylphenol monomer in said nitrile solution is from about 1 to about 50% based on the weight of said nitrile.
Claim 3
Dependent Claim
37 words
The process of claim 1, wherein said cationic polymerization initiator is at least one selected from the group consisting of boron trifluoride, a complex salt of boron trifluoride, aluminum chloride, tin tetrachloride, vanadium oxychloride and diethylaluminum monochloride.
Claim 4
Dependent Claim
26 words
The process of claim 1, wherein said cationic polymerization is used in an amount of from about 0.01 to about 5 mole% to said alkenylphenol monomer.
Claim 5
Dependent Claim
24 words
The process of claim 1, wherein the polymerization reaction is carried out at a temperature of from about +50° C. to about -100° C.
Claim 6
Dependent Claim
20 words
The process of claim 1, wherein said alkenylphenol monomer and said cationic polymerization initiator are used as a nitrile solution.
Claim 7
Dependent Claim
19 words
The process of claim 1, wherein the water content in the reaction mixture is lower than about 1,000 ppm.
Claim 8
Dependent Claim
24 words
The process of claim 1, wherein the nitrile solution of said alkenylphenol is contacted with a drying agent and dehydrated before the polymerization reaction.
Claim 9
Dependent Claim
24 words
The process of claim 1, wherein the resulting reaction product is poured into water or benzene to thereby isolate the polymer and recover it.
Claim 10
Dependent Claim
23 words
The process of claim 1, wherein the resulting reaction product is distilled to remove said nitrile, whereby the polymer is isolated and recovered.
Claim 11
Dependent Claim
21 words
The process of claim 1, wherein said nitrile is present as a solvent for the alkenylphenol monomer and the alkenylphenol polymer.
References Cited (Backward Citations)
US3422062A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-06-27 | 1980-12-27 | 1981-06-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-06-27 | 1984-12-27 | 1985-06-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-06-27 | 1988-12-27 | 1989-06-28 | $7700.00 | Window Closed / Lapsed |