Chemically modified hydroxy styrene polymer resins and their use in photoactive resist compositions wherein the modifying agent is monomethylol phenol

Claim 2

An alkali-soluble binder resin made by a condensation reaction consisting of reacting a hydroxy styrene moiety having formulae (I) or (II): ##STR6## wherein x is an integer from 2 to 3001 with a monomethylolated phenolic compound having a formula (III): ##STR7## wherein R 1 and R 2 are individually selected from the group consisting of lower alkyl group having 1-4 carbon atoms, lower alkoxy group having 1-4 carbon atoms, amino group, and carboxylic acid group; wherein R 3 and R 4 are individually selected from the group consisting of hydrogen, lower alkyl group having 1-4 carbon atoms, lower alkoxy groups having 1-4 carbon atoms, an amino group, and a carboxylic group; and wherein the mole ratio of the hydroxy styrene moiety to the monomethylolated phenolic compound is from about 1:10 to about 10:1.

Claim 3

The alkali-soluble novolak binder resin of claim 1 wherein said hydroxy styrene is poly(parahydroxy styrene).

Claim 4

The alkali-soluble novolak binder resin of claim 1 wherein said methylolated phenolic compound is 2,4-dimethyl-6-methylolphenol.

Claim 5

A radiation-sensitive composition dissolved in a solvent comprising an admixture: (a) a photoactive compound; (b) an alkali-soluble binder resin made by a condensation reaction of hydroxy styrene moiety having formulae (I) or (II): ##STR8## wherein x is an integer from 2 to 300; with a monomethylolated phenolic compound having a formula (III): ##STR9## wherein R 1 and R 2 are individually selected from the group consisting of lower alkyl group having 1-4 carbon atoms, lower alkoxy group having 1-4 carbon atoms, amino group, and carboxylic acid group; wherein R 3 and R 4 are individually selected from the group consisting of hydrogen, lower alkyl group having 1-4 carbon atoms, lower alkoxy groups having 1-4 carbon atoms, an amino group, and a carboxylic group; and wherein the mole ratio of the hydroxy styrene moiety to the monomethylolated phenolic compound is from about 1:10 to about 10:1 wherein the photoactive compound makes up from about 5% to about 40% by weight of the solids of said radiation-sensitive composition; and the alkali-soluble novolak resin makes up from about 95% to about 60% by weight of the solids in said radiation-sensitive composition.

Claim 6

A radiation-sensitive composition dissolved in a solvent comprising an admixture: (a) a photoactive compound; (b) an alkali-soluble binder resin made by a condensation reaction of hydroxy styrene moiety having formulae (I) or (II): ##STR8## wherein x is an integer from 2 to 300; with a monomethylolated phenolic compound having a formula (III): ##STR9## wherein R 1 and R 2 are individually selected from the group consisting of lower alkyl group having 1-4 carbon atoms, lower alkoxy group having 1-4 carbon atoms, amino group, and carboxylic acid group; wherein R 3 and R 4 are individually selected from the group consisting of hydrogen, lower alkyl group having 1-4 carbon atoms, lower alkoxy groups having 1-4 carbon atoms, an amino group, and a carboxylic group; and wherein the mole ratio of the hydroxy styrene moiety to the monomethylolated phenolic compound is from about 1:10 to about 10:1 wherein the photoactive compound makes up from about 5% to about 40% by weight of the solids of said radiation-sensitive composition; and the alkali-soluble novolak resin makes up from about 95% to about 60% by weight of the solids in said radiation-sensitive composition.

Claim 7

The radiation-sensitive composition of claim 4 wherein said hydroxy styrene is poly(parahydroxy styrene).

Claim 8

The radiation-sensitive composition of claim 4 wherein said monomethylolated phenolic compound is 2,4-dimethyl-6-methylolphenol.

Claim 9

The radiation-sensitive composition of claim 1 wherein said photoactive compound is an o-quinonediazide compound.