US7214414B2
Expired / Lapsed
US
⏱️ 0.0 years remaining
Biodegradable polymer blends for use in making films, sheets and other articles of manufacture
Assignee: BioTec Biologische Naturverpackungen GmbH and Co KG
•
Filing: 2005-04-12
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Granted: 2007-05-08
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Expires: 2025-04-12
Abstract
Abstract Biodegradable polymer blends suitable for laminate coatings, wraps and other packaging materials are manufactured from a blend of suitable biodegradable polymers, such as at least one “hard” biopolymer and at least one “soft” biopolymer. “Hard” biopolymers tend to be more brittle and rigid and typically have a glass transition temperature greater than about 10° C. “Soft” biopolymers tend to be more flexible and pliable and typically have a glass transition temperature less than about 0° C. While hard and soft polymers each possess certain intrinsic benefits, certain blends of hard and soft polymers have been discovered which possess synergistic properties superior to those of either hard or soft polymers by themselves. Biodegradable polymers include polyesters, polyesteramides, polyesterurethanes, thermoplastic starch, and other natural polymers. The polymer blends may optionally include an inorganic filler. Films and sheets made from the polymer blends may be textured so as to increase the bulk hand feel. Wraps will typically be manufactured to have good “dead-fold” properties so as to remain in a wrapped position and not spring back to an “unwrapped” form.
Inventors
- 👤 Kishan Khemani
- 👤 Harald Schmidt
- 👤 Simon Hodson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 06:56
CPC Classifications
C; C08; C08L; C08L77/00; C08L77/12; C08L67/00; C08L67/02; C08L67/04; C08L3/00; C08L3/02; C08L67/03; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1303; Y10T428/1307; Y10T428/1334; Y10T428/1352
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
231 words
A biodegradable thermoplastic composition formed by extruding a thermoplastic melt using an extruder, comprising: a synthetic thermoplastic biodegradable polymer portion comprising at least one polymer selected from the group consisting of polyethylene terephthalates modified by replacing a portion of terephthalate groups with aliphatic diacid ester groups, aliphatic-aromatic copolyesters formed from at least one aromatic diacid, at least one aliphatic diacid, and at least one aliphatic diol, polylactic acid, polyhydroxybutyrate, polyhydroxybutyrate-hydroxyvalerate copolymers, aliphatic polyesters including units formed from a lactide, aliphatic polyesters including units formed from a hydroxyacid having at least 5 carbon atoms, a polyester including units formed from succinic acid and an aliphatic diol, and terpolymers including units formed from each of glycolide, lactide and ε-caprolactone; and thermoplastic starch that is substantially free of high boiling liquid plasticizers selected from the group consisting of glycerin, propylene glycol and sorbitol and that is initially melted by heating and mixing the starch in the presence of water in an amount of at least the natural water content of native starch granules within an extruder so as to form a thermoplastic starch melt consisting of starch and at least the natural water content of native starch granules and then subsequently dried by venting after the starch is blended with the synthetic thermoplastic biodegradable polymer within the extruder, wherein the biodegradable composition is suitable for formation into at least one of sheets or films.
Claim 2
Dependent Claim
231 words
A biodegradable thermoplastic composition formed by extruding a thermoplastic melt using an extruder, comprising: a synthetic thermoplastic biodegradable polymer portion comprising at least one polymer selected from the group consisting of polyethylene terephthalates modified by replacing a portion of terephthalate groups with aliphatic diacid ester groups, aliphatic-aromatic copolyesters formed from at least one aromatic diacid, at least one aliphatic diacid, and at least one aliphatic diol, polylactic acid, polyhydroxybutyrate, polyhydroxybutyrate-hydroxyvalerate copolymers, aliphatic polyesters including units formed from a lactide, aliphatic polyesters including units formed from a hydroxyacid having at least 5 carbon atoms, a polyester including units formed from succinic acid and an aliphatic diol, and terpolymers including units formed from each of glycolide, lactide and ε-caprolactone; and thermoplastic starch that is substantially free of high boiling liquid plasticizers selected from the group consisting of glycerin, propylene glycol and sorbitol and that is initially melted by heating and mixing the starch in the presence of water in an amount of at least the natural water content of native starch granules within an extruder so as to form a thermoplastic starch melt consisting of starch and at least the natural water content of native starch granules and then subsequently dried by venting after the starch is blended with the synthetic thermoplastic biodegradable polymer within the extruder, wherein the biodegradable composition is suitable for formation into at least one of sheets or films.
Claim 3
Dependent Claim
36 words
A biodegradable thermoplastic composition as defined in claim 1 , wherein the synthetic thermoplastic biodegradable polymer portion comprises at least one stiff synthetic thermoplastic biodegradable polymer having a glass transition temperature greater than about 10° C.
Claim 4
Dependent Claim
36 words
A biodegradable thermoplastic composition as defined in claim 1 , wherein the synthetic thermoplastic biodegradable polymer portion comprises at least one soft synthetic thermoplastic biodegradable polymer having a glass transition temperature less than about 0° C.
Claim 5
Dependent Claim
36 words
A biodegradable thermoplastic composition as defined in claim 1 , wherein the thermoplastic starch retains at least some crystallinity so as to be a stiff polymer having a glass transition temperature greater than about 10° C.
Claim 6
Dependent Claim
19 words
A biodegradable thermoplastic composition as defined in claim 1 , wherein the thermoplastic starch has little or no crystallinity.
Claim 7
Dependent Claim
22 words
A biodegradable thermoplastic composition as defined in claim 1 , wherein the thermoplastic starch is substantially free of glycerin and propylene glycol.
Claim 8
Dependent Claim
20 words
A biodegradable thermoplastic composition as defined in claim 1 , wherein the composition is in the form of a granulate.
Claim 9
Dependent Claim
29 words
A biodegradable thermoplastic composition as defined in claim 1 , wherein the composition is in the form of at least one of a sheet, film, bag, coating, or pouch.
Claim 10
Dependent Claim
19 words
A biodegradable thermoplastic composition as defined in claim 1 , wherein the sheet or film is a food wrap.
Claim 11
Dependent Claim
192 words
A biodegradable thermoplastic composition formed by extruding a thermoplastic melt using an extruder, comprising: a soft synthetic thermoplastic biodegradable polymer having a glass transition temperature less than about 0° C.; and a stiff thermoplastic polymer portion comprising at least one polymer having a glass transition temperature greater than about 10° C., the stiff thermoplastic polymer portion comprising thermoplastic starch that is substantially free of high boiling liquid plasticizers selected from the group consisting of glycerin, propylene glycol and sorbitol and that is initially melted by heating and mixing the starch in the presence of water in an amount of at least the natural water content of native starch granules within an extruder so as to form a thermoplastic starch melt consisting of starch and at least the natural water content of native starch granules and then subsequently dried by venting after the starch is blended with the soft synthetic thermoplastic biodegradable polymer within the extruder, the thermoplastic starch retaining at least some crystallinity so as to have a glass transition temperature greater than about 10° C., wherein the biodegradable composition is suitable for formation into at least one of sheets or films.
Claim 12
Dependent Claim
192 words
A biodegradable thermoplastic composition formed by extruding a thermoplastic melt using an extruder, comprising: a soft synthetic thermoplastic biodegradable polymer having a glass transition temperature less than about 0° C.; and a stiff thermoplastic polymer portion comprising at least one polymer having a glass transition temperature greater than about 10° C., the stiff thermoplastic polymer portion comprising thermoplastic starch that is substantially free of high boiling liquid plasticizers selected from the group consisting of glycerin, propylene glycol and sorbitol and that is initially melted by heating and mixing the starch in the presence of water in an amount of at least the natural water content of native starch granules within an extruder so as to form a thermoplastic starch melt consisting of starch and at least the natural water content of native starch granules and then subsequently dried by venting after the starch is blended with the soft synthetic thermoplastic biodegradable polymer within the extruder, the thermoplastic starch retaining at least some crystallinity so as to have a glass transition temperature greater than about 10° C., wherein the biodegradable composition is suitable for formation into at least one of sheets or films.
Claim 13
Dependent Claim
34 words
A biodegradable thermoplastic composition as defined in claim 10 , the soft synthetic thermoplastic biodegradable polymer comprising an aliphatic-aromatic copolyester including units formed from adipic acid, dialkyl terephthalate, and at least one aliphatic diol.
Claim 14
Dependent Claim
18 words
A biodegradable thermoplastic composition as defined in claim 11 , the biodegradable thermoplastic composition further comprising a lubricant.
Claim 15
Dependent Claim
20 words
A biodegradable thermoplastic composition as defined in claim 10 , wherein the composition is in the form of a granulate.
Claim 16
Dependent Claim
31 words
A biodegradable thermoplastic composition as defined in claim 10 , wherein the composition is in the form of at least one of a sheet, film, bag, coating, food wrap, or pouch.
Claim 17
Dependent Claim
169 words
A biodegradable thermoplastic composition formed by extruding a thermoplastic melt using an extruder, consisting essentially of: a soft synthetic thermoplastic biodegradable polymer having a glass transition temperature less than about −20° C. and that is an aliphatic-aromatic copolyester including units formed from adipic acid, dialkyl terephthalate, and at least one aliphatic diol; thermoplastic starch that is substantially free of high boiling liquid plasticizers selected from the group consisting of glycerin, propylene glycol and sorbitol and that is initially melted by heating and mixing the starch in the presence of water in an amount of at least the natural water content of native starch granules within an extruder so as to form a thermoplastic starch melt consisting of starch and at least the natural water content of native starch granules and then subsequently dried by venting after the starch is blended with the soft synthetic thermoplastic biodegradable polymer within the extruder; and a lubricant, wherein the biodegradable composition is suitable for formation into at least one of sheets or films.
Claim 18
Dependent Claim
169 words
A biodegradable thermoplastic composition formed by extruding a thermoplastic melt using an extruder, consisting essentially of: a soft synthetic thermoplastic biodegradable polymer having a glass transition temperature less than about −20° C. and that is an aliphatic-aromatic copolyester including units formed from adipic acid, dialkyl terephthalate, and at least one aliphatic diol; thermoplastic starch that is substantially free of high boiling liquid plasticizers selected from the group consisting of glycerin, propylene glycol and sorbitol and that is initially melted by heating and mixing the starch in the presence of water in an amount of at least the natural water content of native starch granules within an extruder so as to form a thermoplastic starch melt consisting of starch and at least the natural water content of native starch granules and then subsequently dried by venting after the starch is blended with the soft synthetic thermoplastic biodegradable polymer within the extruder; and a lubricant, wherein the biodegradable composition is suitable for formation into at least one of sheets or films.
Claim 19
Dependent Claim
20 words
A biodegradable thermoplastic composition as defined in claim 15 , wherein the composition is in the form of a granulate.
Claim 20
Dependent Claim
31 words
A biodegradable thermoplastic composition as defined in claim 15 , wherein the composition is in the form of at least one of a sheet, film, bag, coating, food wrap, or pouch.
Claim 21
Independent Claim
278 words
A method of manufacturing a biodegradable thermoplastic composition that is suitable for formation into at least one of sheets or films, comprising: within an extruder, forming a thermoplastic starch melt that is substantially free of high boiling liquid plasticizers selected from the group consisting of glycerin, propylene glycol and sorbitol by heating and mixing starch in the presence of water in an amount of at least the natural water content of native starch granules within an extruder so as to form a thermoplastic starch melt consisting of starch and at least the natural water content of native starch granules; prior to venting any of the water from the thermoplastic starch melt within the extruder, blending the thermoplastic starch melt with a synthetic thermoplastic biodegradable polymer within the extruder to form a blended melt, the synthetic thermoplastic biodegradable polymer comprising at least one polymer selected from the group consisting of polyethylene terephthalates modified by replacing a portion of terephthalate groups with aliphatic diacid ester groups, aliphatic-aromatic copolyesters formed from at least one aromatic diacid, at least one aliphatic diacid, and at least one aliphatic diol, polylactic acid, polyhydroxybutyrate, polyhydroxybutyrate-hydroxyvalerate copolymers, aliphatic polyesters including units formed from a lactide, aliphatic polyesters including units formed from a hydroxyacid having at least 5 carbon atoms, a polyester including units formed from succinic acid and an aliphatic diol, and terpolymers including units formed from each of glycolide, lactide and ε-caprolactone; venting water from the thermoplastic starch melt while in the extruder so as to dry the thermoplastic starch melt after the starch has been blended with the soft synthetic thermoplastic biodegradable polymer prior to extrusion; and extruding the blended melt from the extruder.
Claim 22
Independent Claim
278 words
A method of manufacturing a biodegradable thermoplastic composition that is suitable for formation into at least one of sheets or films, comprising: within an extruder, forming a thermoplastic starch melt that is substantially free of high boiling liquid plasticizers selected from the group consisting of glycerin, propylene glycol and sorbitol by heating and mixing starch in the presence of water in an amount of at least the natural water content of native starch granules within an extruder so as to form a thermoplastic starch melt consisting of starch and at least the natural water content of native starch granules; prior to venting any of the water from the thermoplastic starch melt within the extruder, blending the thermoplastic starch melt with a synthetic thermoplastic biodegradable polymer within the extruder to form a blended melt, the synthetic thermoplastic biodegradable polymer comprising at least one polymer selected from the group consisting of polyethylene terephthalates modified by replacing a portion of terephthalate groups with aliphatic diacid ester groups, aliphatic-aromatic copolyesters formed from at least one aromatic diacid, at least one aliphatic diacid, and at least one aliphatic diol, polylactic acid, polyhydroxybutyrate, polyhydroxybutyrate-hydroxyvalerate copolymers, aliphatic polyesters including units formed from a lactide, aliphatic polyesters including units formed from a hydroxyacid having at least 5 carbon atoms, a polyester including units formed from succinic acid and an aliphatic diol, and terpolymers including units formed from each of glycolide, lactide and ε-caprolactone; venting water from the thermoplastic starch melt while in the extruder so as to dry the thermoplastic starch melt after the starch has been blended with the soft synthetic thermoplastic biodegradable polymer prior to extrusion; and extruding the blended melt from the extruder.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2010-05-07 | 2010-11-06 | 2011-05-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2014-05-07 | 2014-11-06 | 2015-05-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2018-05-07 | 2018-11-06 | 2019-05-08 | $7700.00 | Window Closed / Lapsed |