US5569692A
Expired / Lapsed
US
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Biodegradable compositions and films or moulded articles obtained therefrom
Assignee: Novamont SpA
•
Filing: 1995-08-21
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Granted: 1996-10-29
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Expires: 2015-08-21
Abstract
Abstract In order to prepare a starch-based composition usable for the production of articles of biodegradable plastics material, a starch is mixed in a heated extruder with a high-boiling plasticizer and a destructuring agent for a time sufficient to cause the starch to be destructured, in dependence on the destructuring agent used, at a temperature below the boiling point of the plasticizer used and between 120° and 170° C. The composition thus obtained is particularly suitable for the formulation of polymer mixtures with polymers which have relatively high melting points, since it can be processed at temperatures higher than 120° C. and is suitable for extrusion at low pressure with these polymers. In particular, compositions thus obtained and mixed with polyvinyl alcohol and/or ethylene vinyl alcohol are suitable for the formation of films by blow-extrusion, since they have the desired characteristics of mechanical strength and resistance to tearing and perforation, or for the formation of articles finished by injection moulding, thermoforming or blowing.
Inventors
- 👤 Catia Bastioli
- 👤 Roberto Lombi
- 👤 Gianfranco Del Tredici
- 👤 Italo Guanella
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 20:18
CPC Classifications
C; C08; C08B; C08B30/00; C08B30/12; B; B29; B29C; B29C48/00; B29C48/022; C08L; C08L3/00; C08L3/02; B29C48/03; B29C48/04; B29C48/07; B29C48/08
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
48 words
A biodegradable composition comprising destructured starch, a thermoplastic polymer, and a plasticizer having a boiling point higher than 150° C. in an amount from 20 to 100% based on the weight of starch, said destructured-starch being obtained by destructuring starch as it is, without the addition of water.
Claim 2
Dependent Claim
48 words
A biodegradable composition comprising destructured starch, a thermoplastic polymer, and a plasticizer having a boiling point higher than 150° C. in an amount from 20 to 100% based on the weight of starch, said destructured-starch being obtained by destructuring starch as it is, without the addition of water.
Claim 3
Dependent Claim
129 words
A biodegradable composition according to claim 1, the biodegradable composition comprising a destructured-starch-based composition and a thermoplastic polymer, the biodegradable composition being produced by contacting the destructured-starch-based composition with the thermoplastic polymer, wherein prior to contacting the destructured-starch-based composition with the thermoplastic polymer, the destructured-starch-based composition is produced by a method comprising: mixing in the absence of added water and in a heated extruder: (a) starch that is not dried beforehand, and (b) a high-boiling plasticizer, wherein the quantity of high-boiling plasticizer is from 20 to 100% of the weight of the starch, and (c) a urea destructuring agent, for a time sufficient to bring about destructuring of the starch and at a temperature (i) below the boiling point of the plasticizer, and (ii) between 120° and 170° C.
Claim 4
Dependent Claim
22 words
A biodegradable composition according to claim 2, wherein the starch, prior to being destructured, contains less than 13% by weight of water.
Claim 5
Dependent Claim
21 words
A biodegradable composition according to claim 3, wherein the starch, prior to being destructured, contains from 10-13% by weight of water.
Claim 6
Dependent Claim
28 words
A biodegradable composition according to claim 1, wherein the plasticizer is selected from the group consisting of glycerine, polyethylene glycol, ethylene glycol, propylene glycol, sorbitol, and mixtures thereof.
Claim 7
Dependent Claim
47 words
A biodegradable composition according to claim 2, wherein the destructured-starch-based composition further comprises a copolymer selected from the group consisting of ethylene/acrylic acid, polyvinyl alcohol, and mixtures thereof, and wherein the quantity of the copolymer is up to 15% of the total weight of the destructured-starch-based composition.
Claim 8
Dependent Claim
28 words
A biodegradable composition according to claim 2, wherein the urea destructuring agent is present in an amount of from 2 to 20% of the weight of the starch.
Claim 9
Dependent Claim
43 words
A biodegradable composition according to claim 2, wherein the destructured-starch-based composition further comprises additives selected from the group consisting of UV stabilizers, flameproofing agents, cross-linking agents, fungicides, herbicides, antioxidants, fertilizers, opacifiers, and stabilizers which do not interfere with the destructuring of said starch.
Claim 10
Dependent Claim
11 words
A moulded article comprising a biodegradable composition according to claim 1.
Claim 11
Dependent Claim
10 words
A film comprising a biodegradable composition according to claim 1.
Claim 12
Dependent Claim
141 words
A biodegradable composition comprising: i. destructured starch; ii. a thermoplastic polymer; and iii. a plasticizer having a boiling point higher than 150° C., in an amount from 20 to 100% by weight based on the weight of the destructured starch, wherein the biodegradable composition is obtained by a process which includes a process step of destructuring starch prior to contacting it with the thermoplastic polymer by: (A) mixing in a heated extruder (1) starch that is not dried beforehand, (2) a plasticizer having a boiling point higher than 150° C. wherein the quantity of plasticizer is from 20 to 100% of the weight of the starch, and (3) a urea destructuring agent, (B) for a time sufficient to bring about destructuring of the starch, (C) at a temperature below the boiling point of the plasticizer, and between 120° and 170° C.
Claim 13
Dependent Claim
141 words
A biodegradable composition comprising: i. destructured starch; ii. a thermoplastic polymer; and iii. a plasticizer having a boiling point higher than 150° C., in an amount from 20 to 100% by weight based on the weight of the destructured starch, wherein the biodegradable composition is obtained by a process which includes a process step of destructuring starch prior to contacting it with the thermoplastic polymer by: (A) mixing in a heated extruder (1) starch that is not dried beforehand, (2) a plasticizer having a boiling point higher than 150° C. wherein the quantity of plasticizer is from 20 to 100% of the weight of the starch, and (3) a urea destructuring agent, (B) for a time sufficient to bring about destructuring of the starch, (C) at a temperature below the boiling point of the plasticizer, and between 120° and 170° C.
Claim 14
Dependent Claim
22 words
A biodegradable composition according to claim 11, wherein the starch prior to being destructured contains less than 13% by weight of water.
Claim 15
Dependent Claim
21 words
A biodegradable composition according to claim 11, wherein the starch prior to being destructured contains from 10-13% by weight of water.
Claim 16
Dependent Claim
28 words
A biodegradable composition according to claim 11, wherein the plasticizer is selected from the group consisting of glycerine, polyethylene glycol, ethylene glycol, propylene glycol, sorbitol, and mixtures thereof.
Claim 17
Dependent Claim
49 words
A biodegradable composition according to claim 11, further comprising a copolymer selected from the group consisting of ethylene/acrylic acid, polyvinyl alcohol, and mixtures thereof, wherein the quantity of the copolymer is up to 15% of the total weight of the destructured-starch-based composition produced in steps (A), (B), and (C).
Claim 18
Dependent Claim
28 words
A biodegradable composition according to claim 11, wherein the urea destructuring agent is present in an amount of from 2 to 20% of the weight of the starch.
Claim 19
Dependent Claim
46 words
A biodegradable composition according to claim 11, further comprising additives to the destructured starch, the additives being selected from the group consisting of UV stabilizers, flameproofing agents, cross-linking agents, fungicides, herbicides, antioxidants, fertilizers, opacifiers, and stabilizers which do not interfere with the destructuring of said starch.
Claim 20
Dependent Claim
10 words
A film comprising a biodegradable composition according to claim 11.
Claim 21
Dependent Claim
11 words
A moulded article comprising a biodegradable composition according to claim 11.
References Cited (Backward Citations)
US5095054A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1999-10-29 | 2000-04-29 | 2000-10-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2003-10-29 | 2004-04-29 | 2004-10-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2007-10-29 | 2008-04-29 | 2008-10-29 | $7700.00 | Window Closed / Lapsed |