US5219646A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polyester blends and their use in compostable products such as disposable diapers
Assignee: EIDP Inc
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Filing: 1992-02-13
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Granted: 1993-06-15
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Expires: 2012-02-13
Abstract
Abstract The invention provides novel blends of starch with polyesters, and shaped articles of such blends, including fibers, foams and films, nonwovens from the fibers and disposable products such as diapers. The products are degradable under the conditions typically existing in waste composting processes, have low ingredient costs and yet provide strength and toughness properties adequate for end uses such as in disposable diapers. The polyesters are based upon polyethylene terephthalate copolymerized with other ingredients, including non-aromatic diacids, such as adipic and glutaric acids, polyethylene ether groups, such as diethylene glycol or higher polyalkylene glycols, and hydroxy acids.
Inventors
- 👤 Francis G. Gallagher
- 👤 Hyunkook Shin
- 👤 Raymond F. Tietz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 00:24
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/18; A; A61; A61F; A61F13/00; A61F13/15; A61F13/15203; A61F13/15252; A61L; A61L15/00; A61L15/16; A61L15/22; A61L15/225; A61L15/26; A61L15/42; A61L15/62; C08G; C08G63/00; C08G63/02; C08G63/60; C08G63/66; C08G63/668; C08G63/672; C08G63/68; C08G63/688; C08G63/6884; C08G63/6886; C08L; C08L3/00; C08L3/02; C08L67/00; D; D01; D01F; D01F6/00; D01F6/78; D01F6/84; D01F6/86; D01F6/88; D01F6/92; A61F13/51; A61F2013/51002; A61F2013/51023; A61F2013/51035; A61F13/514; A61F13/51401; A61F2013/51409; A61F2013/51433; C08J2367/00; C08J2367/02; C08L2201/00; C08L2201/06; Y; Y10; Y10S; Y10S521/00; Y10S521/916; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31786; Y10T428/3179; Y10T428/31971; Y10T442/00; Y10T442/60; Y10T442/637; Y10T442/674; Y10T442/675
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
288 words
A fiber and film forming blend of starch, in amount by weight 1 to 80%, and of a polyester, in amount by weight 99 to 20%, wherein said polyester consists essentially of recurring structural units of the formulae: --[--C(O)--R--C(O)--OGO--].sub.a --[--C(O)--Q--O--].sub.b -- wherein up to about 40 mole % of R is selected from the group consisting of a chemical bond and one or more divalent, non-aromatic, C 1 -C 10 hydrocarbylene radicals, and the remainder of R is at least about 85 mole % p-phenylene radical, wherein G is up to about 30 mole % of a polyethylene ether radical selected from the group consisting of --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 -- and --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 -- and the remainder of G is selected from the group consisting of polyalkylene ether radicals of molecular weight at least about 250, and --(CH 2 ) 2 --, --(CH 2 ) 3 --, and --(CH 2 ) 4 -- radicals, wherein Q is derived from an hydroxy acid of formula HO[--C(O)--Q--O--].sub.x H, where x is an integer, such hydroxy acid having a melting point at least 5° C. below its decomposition temperature, and Q is selected from the group consisting of a chemical bond and hydrocarbylene radicals --(CH 2 ) n --, where n is an integer from 1 to 5, --C(R')H--, and --C(R')HCH 2 --, wherein R' is selected from the group of --CH 3 and --CH 2 CH 3 , and wherein "a" and "b" are mole fractions of the polymer, and the mole fraction "a" may be 0.6 to 1 and, correspondingly, mole fraction "b" may be 0 to 0.4, and wherein about 0.1 to about 15 mole % of the polymer contains alkali metal or alkaline earth metal sulfo groups.
Claim 2
Dependent Claim
288 words
A fiber and film forming blend of starch, in amount by weight 1 to 80%, and of a polyester, in amount by weight 99 to 20%, wherein said polyester consists essentially of recurring structural units of the formulae: --[--C(O)--R--C(O)--OGO--].sub.a --[--C(O)--Q--O--].sub.b -- wherein up to about 40 mole % of R is selected from the group consisting of a chemical bond and one or more divalent, non-aromatic, C 1 -C 10 hydrocarbylene radicals, and the remainder of R is at least about 85 mole % p-phenylene radical, wherein G is up to about 30 mole % of a polyethylene ether radical selected from the group consisting of --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 -- and --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 -- and the remainder of G is selected from the group consisting of polyalkylene ether radicals of molecular weight at least about 250, and --(CH 2 ) 2 --, --(CH 2 ) 3 --, and --(CH 2 ) 4 -- radicals, wherein Q is derived from an hydroxy acid of formula HO[--C(O)--Q--O--].sub.x H, where x is an integer, such hydroxy acid having a melting point at least 5° C. below its decomposition temperature, and Q is selected from the group consisting of a chemical bond and hydrocarbylene radicals --(CH 2 ) n --, where n is an integer from 1 to 5, --C(R')H--, and --C(R')HCH 2 --, wherein R' is selected from the group of --CH 3 and --CH 2 CH 3 , and wherein "a" and "b" are mole fractions of the polymer, and the mole fraction "a" may be 0.6 to 1 and, correspondingly, mole fraction "b" may be 0 to 0.4, and wherein about 0.1 to about 15 mole % of the polymer contains alkali metal or alkaline earth metal sulfo groups.
Claim 3
Dependent Claim
22 words
A blend according to claim 1, containing, by weight, 5 to 70% of starch and complementally 30 to 95% of said polyester.
Claim 4
Dependent Claim
28 words
A blend according to claim 1 or 2, wherein about 0.1 to about 2.5 mole % of the polyester contains alkali metal or alkaline earth metal sulfo groups.
Claim 5
Dependent Claim
10 words
A fiber of the blend of claim 1 or 2.
Claim 6
Dependent Claim
11 words
A non-woven sheet of the blend of claim 1 or 2.
Claim 7
Dependent Claim
10 words
A film of the blend of claim 1 or 2.
Claim 8
Dependent Claim
10 words
A foam of the blend of claim 1 or 2.
Claim 9
Dependent Claim
18 words
A composite of the film of claim 6 and of a layer of nonwoven sheet or of paper.
Claim 10
Dependent Claim
26 words
A disposable diaper which includes an absorbent body portion having on one surface thereof a water permeable sheet of the blend of claim 1 or 2.
Claim 11
Dependent Claim
26 words
A disposable diaper which includes an absorbent body portion having on one surface thereof a water impermeable sheet of the blend of claim 1 or 2.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1996-06-14 | 1996-12-14 | 1997-06-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-06-14 | 2000-12-14 | 2001-06-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-06-14 | 2004-12-14 | 2005-06-15 | $7700.00 | Window Closed / Lapsed |