US5262458A
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US
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Biodegradable articles based on starch and process for producing them
Assignee: Novamont SpA
•
Filing: 1990-03-08
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Granted: 1993-11-16
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Expires: 2010-03-08
Abstract
Abstract PCT No. PCT/EP90/00375 Sec. 371 Date Nov. 5, 1990 Sec. 102(e) Date Nov. 5, 1990 PCT Filed Mar. 8, 1990 PCT Pub. No. WO90/10671 PCT Pub. Date Sep. 20, 1990.Formed articles comprising destructurized starch, an ethylene-acrylic acid copolymer and a product of the interaction of starch and ethylene-acrylic acid copolymer wherein the starch not bound to the copolymer is in the form of particles having sizes below 1 micron. The water content of such articles is lower than the one usually present in the starch. Said formed articles can also contain urea in an amount no higher than 30% by weight and/or ammonia in an amount not higher than 0.5% by weight. The process for obtaining such articles comprises the steps of extruding starch, an ethylene-acrylic acid copolymer and optionally water, urea and/or ammonia at a temperature ranging from 90 DEG to 150 DEG C., reducing the water content to values lower than 6% by weight and injection molding or extrusion blowing the resulting composition.
Inventors
- 👤 Catia Bastioli
- 👤 Vittorio Bellotti
- 👤 Luciano Del Giudice
- 👤 Gianfranco Del Tredici
- 👤 Roberto Lombi
- 👤 Angelos Rallis
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 23:02
CPC Classifications
C; C08; C08L; C08L3/00; C08L3/02; C08B; C08B30/00; C08B30/12; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08L23/0846; C08L23/0869; A; A61; A61F; A61F13/00; A61F13/15; A61F13/15203; A61F13/15252
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
80 words
Articles based on Starch, insoluble in water, comprising: (1) a phase consisting of destructurized starch in the form of particles having an average number diameter below 1 micron; (2) a phase consisting of an ethylene-acrylic acid copolyner (EAA); (3) a phase consisting of an IPN (interpenetrated network) resulting from the interaction between starch and ethylene-acrylic acid copolymer and, (4) a water content in the range from 0 to 2% by weight calculated on the total weight of the three phases.
Claim 2
Dependent Claim
80 words
Articles based on Starch, insoluble in water, comprising: (1) a phase consisting of destructurized starch in the form of particles having an average number diameter below 1 micron; (2) a phase consisting of an ethylene-acrylic acid copolyner (EAA); (3) a phase consisting of an IPN (interpenetrated network) resulting from the interaction between starch and ethylene-acrylic acid copolymer and, (4) a water content in the range from 0 to 2% by weight calculated on the total weight of the three phases.
Claim 3
Dependent Claim
69 words
Articles based on starch according to claim 1, wherein said ethylene-acrylic acid copolymer has an acrylic acid content ranging from 3 to 30% by weight and the destructured starch phase which is not bound to the ethylene-acrylic acid copolymer, is finely and uniformly dispersed in the mix in the form of particles having an average number diameter below 1 micron and a dispersion of the particles sizes below 3.
Claim 4
Dependent Claim
88 words
Articles based on starch according to claim 1 comprising: from 10 to 90% by weight of a total ethylene-acrylic acid copolymer, having an acrylic acid content ranging from 3 to 30% by weight, and less than 2% by weight of water; wherein less than 40% and preferably less than 20% by weight of the total starch is free and in the form of particles having an average number diameter lower than 1 micron, the remaining starch being bound to the ethylene-acrylic acid copolymer to form said interaction product.
Claim 5
Dependent Claim
24 words
Articles based on starch according to claim 3, wherein from 80 to 100% of the total starch is bound to the ethylene-acrylic acid copolymer:
Claim 6
Dependent Claim
24 words
Articles based on starch according to claims 2 or 3, wherein the average number diameter if the particles ranges from 0.1 to 0.5 microns.
Claim 7
Dependent Claim
23 words
Articles based on starch according to claim 1, wherein the ethylene-acrylic acid copolymer has an acrylic acid content equal to 20% by weight.
Claim 8
Dependent Claim
25 words
Articles based on starch according to claim 1, preceding claims, wherein the water content ranges from 0 to 2% by weight referred to the mix.
Claim 9
Dependent Claim
26 words
Articles based on starch according to claim 1, containing, in addition, urea in an amount not exceeding 30% by the weight with respect to the mix.
Claim 10
Dependent Claim
24 words
Articles based on starch according to claim 1, containing, in addition, ammonia in amount not exceeding 0.5% by weight with respect to the mix.
Claim 11
Dependent Claim
20 words
Articles based on starch according to claim 1, containing polyethylene, polyvinyl alcohol and/or antioxidants, stabilizers, antiflame agents, fertilizers, opacifiers, plasticizers.
Claim 12
Dependent Claim
164 words
A process for producing starch-based articles comprising: supplying to a heated extruder a material including starch and an ethylene-acrylic acid copolymer in a starch/copolymer ratio of from 1:9 to 9:1, and a quantity of water of from 10 to 25% of the total weight of the starch component, and processing said material in the extruder which is heated to a temperature of from 90° and 150° C. according to a stage sequence comprising: a first mixing stage in which the starch supplied is intimately mixed with the copolymer to destructurize the starch and achieve interpenetration of the starch and copolymer phase, a stage in which the material output from the mixing step is degassed to reduce its water content to less than 2% of the weight of the composition, a transportation and compression stage in which the degassed material is transported and compressed to a pressure greater than 500 kPa and the material is extruded at a temperature of between 105° and 130° C.
Claim 13
Dependent Claim
164 words
A process for producing starch-based articles comprising: supplying to a heated extruder a material including starch and an ethylene-acrylic acid copolymer in a starch/copolymer ratio of from 1:9 to 9:1, and a quantity of water of from 10 to 25% of the total weight of the starch component, and processing said material in the extruder which is heated to a temperature of from 90° and 150° C. according to a stage sequence comprising: a first mixing stage in which the starch supplied is intimately mixed with the copolymer to destructurize the starch and achieve interpenetration of the starch and copolymer phase, a stage in which the material output from the mixing step is degassed to reduce its water content to less than 2% of the weight of the composition, a transportation and compression stage in which the degassed material is transported and compressed to a pressure greater than 500 kPa and the material is extruded at a temperature of between 105° and 130° C.
Claim 14
Dependent Claim
27 words
A process according to claim 11 including a first transportation stage at a temperature of between 60° and 100° C. immediately upstream of the first mixing stage.
Claim 15
Dependent Claim
34 words
A process according to claim 11, in which the material supplied to the extruder is subjected to shear deformation at a rate of between 50 and 5000 seconds -1 during the first mixing stage.
Claim 16
Dependent Claim
27 words
A process according to claim 11, in which the first mixing stage extends for a distance of 4 to 20 times the diameter of the extruder screw.
Claim 17
Dependent Claim
41 words
A process according to claim 11, in which the stage for the transportation of the degassed material extends for a distance of 4 to 20 times the diameter of the extruder screw and contains mixing elements which can prevent separation phenomena.
Claim 18
Dependent Claim
22 words
A process according to claim 11, in which a compression ratio of from 1:1.5 to 1:4 is applied in the compression stage.
Claim 19
Dependent Claim
25 words
A process according to claim 11, in which the starch material is selected from the group consisting of unmodified starches, modified starches, amylose and amylopectin.
Claim 20
Dependent Claim
56 words
A process according to claim 11, in which the material supplied to the extruder includes a quantity of ammonia of up to 7% of the weight of the dry starch, and in which the ammonia content is reduced to no more than 0.2% by weight of the weight of the extruded composition in the degassing stage.
Claim 21
Dependent Claim
27 words
A process according to claim 11, in which the material supplied to the extruder includes a quantity of urea up to 30% by weight of the composition.
Claim 22
Dependent Claim
26 words
A process according to claim 11, in which the starch and the copolymer are supplied to the extruder in a ratio of from 1:4 and 4:1.
Claim 23
Dependent Claim
32 words
A process according to claim 12, in which the material supplied to the extruder includes a quantity of water of from 10 to 15% of the weight of the dry starch component.
Claim 24
Dependent Claim
63 words
A process according to claim 11, for the production of molded articles wherein the extruded composition having a water content of less than 2% wt is injection molded at a temperature ranging from 130° to 180° C. under shear strain rates ranging from 1,000 and 10,000 sec -1 and for a time ranging from 10 to 120 seconds, depending on the article thickness.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1996-11-15 | 1997-05-17 | 1997-11-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-11-15 | 2001-05-17 | 2001-11-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-11-15 | 2005-05-17 | 2005-11-16 | $7700.00 | Window Closed / Lapsed |