US4673438A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polymer composition for injection molding
Assignee: Novon International LLC
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Filing: 1985-11-08
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Granted: 1987-06-16
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Expires: 2005-11-08
Abstract
Abstract Capsules and other shaped products formed from a moldable starch composition in an injection molding device is disclosed in the present invention. The composition comprising starch having a molecular mass range of 10,000 to 20,000,000 Dalton, and a water content range from 5 to 30% by weight. The starch contains about 0 to 100% of amylose, and about 100 to 0% of amylo-pectin.
Inventors
- 👤 Fritz Wittwer
- 👤 Ivan Tomka
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 23:19
CPC Classifications
A; A61; A61J; A61J3/00; A61J3/07; A61K; A61K9/00; A61K9/48; A61K9/4816; B; B29; B29C; B29C45/00; B29C45/0001; C; C08; C08L; C08L3/00; B29K; B29K2003/00; B29K2995/00; B29K2995/0037; B29K2995/0059; B29L; B29L2031/00; B29L2031/712; B29L2031/7174
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
137 words
A process for forming starch into an article using an injection molding technique which process comprises: (A) maintaining a starch/water composition at a water content between 5-30% by weight of the composition under controlled conditions of temperature and pressure, (b) heating said starch/water composition at elevated pressure above its glass transition temperature and melting point while maintaining said water content, to form a melt, (c) further heating and plasticizing said molten starch/water composition to dissolve the starch in the water to form an essentially molecularly dispersed solution of the melt, (d) injecting the starch/water melt into a mold cavity while maintaining said predetermined water content, (e) cooling the composition in the mold to form a molded product at a temperature below the glass transition temperature of said composition and, (f) ejecting the molded product from said mold.
Claim 2
Dependent Claim
137 words
A process for forming starch into an article using an injection molding technique which process comprises: (A) maintaining a starch/water composition at a water content between 5-30% by weight of the composition under controlled conditions of temperature and pressure, (b) heating said starch/water composition at elevated pressure above its glass transition temperature and melting point while maintaining said water content, to form a melt, (c) further heating and plasticizing said molten starch/water composition to dissolve the starch in the water to form an essentially molecularly dispersed solution of the melt, (d) injecting the starch/water melt into a mold cavity while maintaining said predetermined water content, (e) cooling the composition in the mold to form a molded product at a temperature below the glass transition temperature of said composition and, (f) ejecting the molded product from said mold.
Claim 3
Dependent Claim
22 words
A process according to claim 1 wherein the elevated temperatures in each step is in the range from 80° to 240° C.
Claim 4
Dependent Claim
24 words
A process according to claim 1 or 2 wherein the elevated pressure is in the range from 600×10 5 to 30000×10 5 Newton/square meter.
Claim 5
Dependent Claim
27 words
A process according to claim 1, 2 or 3 wherein the starch is derived from a corn, wheat, potato, rice or tapioca starch or a mixture thereof.
Claim 6
Dependent Claim
36 words
A process according to any one of claims 1 to 4 wherein the native starch is mixed with at least one number of a class consisting of an extenders, a plasticizers, a lubricants and coloring agents.
Claim 7
Dependent Claim
26 words
A process according to claim 1 wherein a plasticizer is present in an amount of from 0.5 to 40% based upon the weight of the starch.
Claim 8
Dependent Claim
25 words
A process according to claim 1 wherein a lubricant is present in an amount of 0.001 to 10% based on the weight of the starch.
Claim 9
Dependent Claim
29 words
A process according to claim 1 or 6 wherein a coloring agent is present in an amount of from 0.001% to 10% based on the weight of the starch.
Claim 10
Dependent Claim
76 words
A process according to claim 1 wherein an extender is added and chosen from sunflower proteins, soybean proteins, cotton seed proteins, peanut proteins, blood proteins, egg proteins, rape seed proteins and acetylated derivatives thereof; gelatin, crosslinked gelatin, vinylacetate, polysaccharides such as cellulose, methylcellulose, hydroxypropyl-cellulose, hydroxypropylmethylcellulose, hydroxymethyl-cellulose, hydroxyethylcellulose, sodium carboxy methycellulose, polyvinylpyrrolidone, agar-agar, gum arabic, guar, dextran, chitin, polymaltose, polyfructose, pectin, alginates, alginic acids, monosaccharides preferably glucose, fructose, saccharose; and oligosaccharides lactose, bentonite, silicates, carbonates and bicarbonates.
Claim 11
Dependent Claim
37 words
A process according to claim 6 wherein the plasticizer is chosen from: polyethylene glycol and low molecular weight organic plasticizers, including glycerol, sorbitol, dictylsodium sulphosuccinate, triethyl citrate, tributyl citrate, 1,2 propyleneglycol, mono-, di-, and tri-acetates of glycerol.
Claim 12
Dependent Claim
32 words
A process according to claim 7 wherein the lubricant is chosen from: lipids; unsaturated and saturated plant fatty acids and salts thereof; stearates of aluminum, calcium, magnesium and tin; talc and silicones.
Claim 13
Dependent Claim
29 words
A process according to claim 11 wherein the lubricant is a glyceride, a phospholipide or a mixture thereof in an amount of from 0.001-10% by weight of the starch.
Claim 14
Dependent Claim
50 words
A process according to any one of claims 1, 2, 3, 4, 6, 7, or 9 wherein the starch is mixed with one or more polymer having enteric properties and being chosen from: hydroxypropylmethylcellulosephthalate (HPMCP), cellulose-acetylphthalate (CAP), acrylates and methacrylates, polyvinylacetatephthalate (PVAP), phthalated gelatin, succinated geltin, crotonic acid, and shellac.
Claim 15
Dependent Claim
19 words
An injection molded article made according to the process of claims 1, 2, 3, 4, 6, 7 or 9.
Claim 16
Dependent Claim
22 words
A capsule whenever produced by a process as claimed in any one of claims 1, 2, 3, 4, 6, 7 or 9.
Claim 17
Dependent Claim
85 words
A starch/water composition characterized in that said composition is obtained by (a) maintaining a starch/water composition at a water content of 5-30% by weight of the composition under controlled conditions of temperature and pressure, (b) heating said starch/water composition under pressure above its glass transition temperature and melting point while maintaining said water content, to form a melt, (c) further heating and plasticizing said molten starch/water composition to dissolve the starch in the water to form melt as a molecularly dispersed solution of said melt.
Claim 18
Dependent Claim
85 words
A starch/water composition characterized in that said composition is obtained by (a) maintaining a starch/water composition at a water content of 5-30% by weight of the composition under controlled conditions of temperature and pressure, (b) heating said starch/water composition under pressure above its glass transition temperature and melting point while maintaining said water content, to form a melt, (c) further heating and plasticizing said molten starch/water composition to dissolve the starch in the water to form melt as a molecularly dispersed solution of said melt.
Claim 19
Dependent Claim
19 words
A composition according to claim 16 characterized in that said composition is held at a temperature of 80°-240° C.
Claim 20
Dependent Claim
25 words
A composition according to claim 17 characterized in that said composition is held at a pressure of 600×10 5 to 3000×10 5 N/M 2 .
Claim 21
Dependent Claim
18 words
A molded article formed from a composition according to any one of the claims 16, 17 or 18.
Claim 22
Dependent Claim
52 words
A self-sustaining molded article made from starch having a microstructure formed by heating a starch-water mixture wherein the water content is between 5 and 30% by weight beyond the glass transition and melting temperatures of starch to form a melt as a molecularly dispersed solution and cooling said melt to minimize shrinkage.
Claim 23
Dependent Claim
52 words
A self-sustaining molded article made from starch having a microstructure formed by heating a starch-water mixture wherein the water content is between 5 and 30% by weight beyond the glass transition and melting temperatures of starch to form a melt as a molecularly dispersed solution and cooling said melt to minimize shrinkage.
Claim 24
Dependent Claim
14 words
A composition according to claim 17 wherein the temperature is greater than 100° C.
Claim 25
Dependent Claim
15 words
A composition according to claim 16 wherein the water content is between 15 and 22%.
Claim 26
Dependent Claim
15 words
A composition according to claim 16 wherein the water content is between 15 and 19%.
Claim 27
Dependent Claim
14 words
A process according to claim 6 wherein plasticizer is present from 0.5-10% by weight.
References Cited (Backward Citations)
US2602755A
Cited
US3117014A
Cited
US3137592A
Cited
DE2001533A1
Cited
US3911159A
Cited
JPS5319645B2
Cited
US4076846A
Cited
US3954104A
Cited
US4216240A
Cited
US4138013A
Cited
US4232047A
Cited
US4415593A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-06-15 | 1990-12-15 | 1991-06-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-06-15 | 1994-12-15 | 1995-06-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-06-15 | 1998-12-15 | 1999-06-16 | $7700.00 | Window Closed / Lapsed |