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US6143476A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for high temperature etching of patterned layers using an organic mask stack

Assignee: Applied Materials Inc
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Filing: 1997-12-12
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Granted: 2000-11-07
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Expires: 2017-12-12
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Abstract

Abstract The present disclosure pertains to a method of patterning a semiconductor device feature which provides for the easy removal of any residual masking layer which remains after completion of a pattern etching process. The method provides for a multi-layered masking structure which includes a layer of high-temperature organic-based masking material overlaid by either a layer of a high-temperature inorganic masking material which can be patterned to provide an inorganic hard mask, or by a layer of high-temperature imageable organic masking material which can be patterned to provide an organic hard mask. The hard masking material is used to transfer a pattern to the high-temperature organic-based masking material, and then the hard masking material is removed. The high-temperature organic-based masking material is used to transfer the pattern to an underlying semiconductor device feature.

Inventors

  • 👤 Yan Ye
  • 👤 Allen Zhao
  • 👤 Peter Chang-Lin Hsieh
  • 👤 Diana Xiaobing Ma

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 15:10
CPC Classifications
H; H10; H10P; H10P50/00; H10P50/73; H10P50/20; H10P50/28; H10P50/286; H10P50/287; H10P50/71; H10P76/00; H10P76/20; H10P76/204; H10P76/2041; H10W; H10W20/00; H10W20/01; H10W20/071; H10W20/081; H10W20/084; H10P14/00; H10P14/60; H10P14/68; H10P14/683; H10P14/687; H10P14/69; H10P14/6902; H10P14/692; H10P14/6921; H10P14/69215; H10P50/26; H10P50/264; H10P50/266; H10P50/267; H10P50/282; H10P50/283

Claims Analysis

Total Claims: 39
Claim 1
Independent Claim 86 words
A method for patterning semiconductor device features comprising the steps of: (a) transferring a pattern from a patterned photoresist layer through a layer of high-temperature inorganic masking material; (b) transferring the pattern from a multi-layered structure remaining after step (a) through an underlying layer of a high-temperature organic-based masking material; (c) removing any photoresist material which remains after step (b); and (d) transferring the pattern from the multi-layered structure present after step (c) through at least one metal-comprising feature layer underlying said high-temperature organic-based masking material.
Claim 2
Independent Claim 86 words
A method for patterning semiconductor device features comprising the steps of: (a) transferring a pattern from a patterned photoresist layer through a layer of high-temperature inorganic masking material; (b) transferring the pattern from a multi-layered structure remaining after step (a) through an underlying layer of a high-temperature organic-based masking material; (c) removing any photoresist material which remains after step (b); and (d) transferring the pattern from the multi-layered structure present after step (c) through at least one metal-comprising feature layer underlying said high-temperature organic-based masking material.
Claim 3
Dependent Claim 25 words
The method of claim 1, including an additional step: (e) removing residual high-temperature organic-based masking layer material from a surface of said metal-comprising feature layer.
Claim 4
Dependent Claim 35 words
The method of claim 2, including an additional step: (f) applying a planarizing layer of an organic-based material having a dielectric constant which is advantageous for purposes of increasing the gate speed of a transistor.
Claim 5
Dependent Claim 30 words
The method of claim 1, including an additional step following step (c), said step comprising: (c-2) removing any portion of said high-temperature inorganic masking material which remains after step (c).
Claim 6
Dependent Claim 23 words
The method of claim 1, wherein said step (b) transfer through said high-temperature organic-based masking material is achieved using an anisotropic plasma etch.
Claim 7
Dependent Claim 25 words
The method of claim 1, wherein said step (c) removal of photoresist is achieved using an oxygen-based plasma in a manner which produces anisotropic etching.
Claim 8
Dependent Claim 20 words
The method of claim 1, wherein said step (d) pattern transfer is achieved in a manner which produces anisotropic etching.
Claim 9
Dependent Claim 34 words
The method of claim 1, wherein said at least one metal-comprising feature layer comprises a metal selected from the group consisting of copper, platinum, silver, gold, iridium, rubidium, ruthenium, tungsten, and barium strontium titanate.
Claim 10
Dependent Claim 24 words
The method of claim 8, wherein said at least one metal-comprising feature layer comprises copper, and said copper is etched using enhanced physical bombardment.
Claim 11
Dependent Claim 33 words
The method of claim 8, wherein said at least one metal-comprising feature layer comprises copper, and said copper is etched using a combination of enhanced physical bombardment with a chemically reactive ion component.
Claim 12
Independent Claim 37 words
The method of claims 8, wherein said at least one metal-comprising feature layer comprises copper, and said copper is etched using a chemistry selected from the group consisting of HCl chemistry, HBr chemistry, or a combination thereof.
Claim 13
Dependent Claim 28 words
The method of claim 7, wherein the thickness of said high-temperature inorganic masking material is designed so that this material is consumed during the step (d) pattern transfer.
Claim 14
Dependent Claim 21 words
The method of claim 2, wherein said high-temperature organic-based masking layer material is removed in a manner which produces anisotropic etching.
Claim 15
Dependent Claim 27 words
The method of claim 2, wherein said high-temperature organic-based masking layer material is removed using a combination of enhanced physical bombardment with a chemically reactive ion component.
Claim 16
Dependent Claim 31 words
The method of claim 2, wherein said high-temperature organic-based masking layer material is removed using a chemistry selected from the group consisting of HCl chemistry, HBr chemistry, or a combination thereof.
Claim 17
Dependent Claim 19 words
The method of claim 2, wherein said high-temperature organic-based masking layer material is removed using a wet stripping technique.
Claim 18
Dependent Claim 19 words
The method of claim 16, wherein said wet stripping technique passivates at least one surface of said feature layer.
Claim 19
Dependent Claim 25 words
The method of claim 1, including an additional step prior to step (a), wherein said high-temperature organic-based masking layer is deposited using a plasma-based technique.
Claim 20
Dependent Claim 26 words
The method of claim 1, including an additional step (x) prior to step (a), wherein said high-temperature organic-based masking layer is deposited using a CVD technique.
Claim 21
Independent Claim 88 words
A method for patterning semiconductor device features comprising the steps of: (a) developing an imaged layer of high-temperature imageable material into a pattern using a plasma etching technique, to produce a patterned mask which can be used to transfer a desired pattern through underlying layers; (b) transferring the pattern formed in step a) through an underlying layer of high-temperature organic-based masking material, and (c) transferring the pattern from the multi-layered structure present after step (b) through at least one metal-comprising feature layer underlying said high-temperature organic-based masking material.
Claim 22
Independent Claim 88 words
A method for patterning semiconductor device features comprising the steps of: (a) developing an imaged layer of high-temperature imageable material into a pattern using a plasma etching technique, to produce a patterned mask which can be used to transfer a desired pattern through underlying layers; (b) transferring the pattern formed in step a) through an underlying layer of high-temperature organic-based masking material, and (c) transferring the pattern from the multi-layered structure present after step (b) through at least one metal-comprising feature layer underlying said high-temperature organic-based masking material.
Claim 23
Dependent Claim 24 words
The method of claim 20, including an additional step: (d) removing residual high-temperature organic-based masking layer material from a surface of said feature layer.
Claim 24
Dependent Claim 35 words
The method of claim 21, including an additional step: (e) applying a planarizing layer of an organic-based material having a dielectric constant which is advantageous for purposes of increasing the gate speed of a transistor.
Claim 25
Dependent Claim 23 words
The method of claim 20, wherein said step (b) transfer through said high-temperature organic-based masking material is achieved using an anisotropic plasma etch.
Claim 26
Dependent Claim 22 words
The method of claim 21, wherein said step (d) masking layer material removal is achieved in a manner which produces anisotropic etching.
Claim 27
Dependent Claim 33 words
The method of claim 21, wherein at least one metal-comprising feature layer comprises a metal selected from the group consisting of copper, platinum, silver, gold, iridium, ribidium, ruthenium, tungsten, and barium strontium titanate.
Claim 28
Dependent Claim 24 words
The method of claim 25, wherein said at least one metal-comprising feature layer comprises copper, and said copper is etched using enhanced physical bombardment.
Claim 29
Dependent Claim 33 words
The method of claim 25, wherein said at least one metal-comprising feature layer comprises copper, and said copper is etched using a combination of enhanced physical bombardment with a chemically reactive ion component.
Claim 30
Dependent Claim 37 words
The method of claim 25, wherein said at least one metal-comprising feature layer comprises copper, and said copper is etched using a chemistry selected from the group consisting of HCl chemistry, HBr chemistry, or a combination thereof.
Claim 31
Dependent Claim 28 words
The method of claim 21, wherein the thickness of said high-temperature inorganic masking material is designed so that this material is consumed during the step (c) pattern transfer.
Claim 32
Dependent Claim 21 words
The method of claim 21, wherein said high-temperature organic-based masking layer material is removed in a manner which produces anisotropic etching.
Claim 33
Dependent Claim 27 words
The method of claim 21, wherein said high-temperature organic-based masking layer material is removed using a combination of enhanced physical bombardment with a chemically reactive ion component.
Claim 34
Dependent Claim 31 words
The method of claim 21, wherein said high-temperature organic-based masking layer material is removed using a chemistry selected from the group consisting of HCl chemistry, HBr chemistry, or a combination thereof.
Claim 35
Dependent Claim 19 words
The method of claim 21, wherein said high-temperature organic-based masking layer material is removed using a wet stripping technique.
Claim 36
Dependent Claim 19 words
The method of claim 33, wherein said wet stripping technique passivates at least one surface of said feature layer.
Claim 37
Dependent Claim 29 words
The method of claim 23, including an additional step (x) prior to step (a), wherein said high-temperature imageable material is material is deposited using a silane-based or TEOS-based chemistry.
Claim 38
Dependent Claim 26 words
The method of claim 35, including an additional step (y) prior to step (x), wherein said high-temperature organic-based masking layer is deposited using a plasma-based technique.
Claim 39
Dependent Claim 26 words
The method of claim 35, including an additional step (z) prior to step (x), wherein said high-temperature organic-based masking layer is deposited using a CVD technique.

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Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2003-11-07 2004-05-08 2004-11-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2007-11-07 2008-05-08 2008-11-07 $3760.00 Window Closed / Lapsed
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