Method of forming contacts in vias formed over interconnect layers

Claim 1

A method of fabricating a semiconductor device incorporating a via and an interconnect layer of aluminum or aluminum alloy, the method comprising the steps of: (a) providing a silicon wafer structure; (b) forming an interconnect layer of aluminum or aluminum alloy on the structure; (c) forming a capping layer over the interconnect layer, the capping layer being composed of electrically conductive material; (d) forming a dielectric layer on the capping layer; and (e) selectively depositing an electrically conductive contact on the capping layer in a contact hole of the dielectric layer thereby to form a via, the materials of the capping layer and of the contact being selected wherein after the contact has been deposited on the capping layer at the interlace therebetween there is substantial absence of non-conductive compounds formed from the material of the capping layer, wherein the contact is tungsten and has been deposited in a two stage deposition process in which in the first stage a tungsten containing species is introduced, in the absence of a reducing agent for such species, over the silicon wafer structure, wherein the tunasten containing species reacts with the capping layer in the contact hole to deposit a tungsten seed layer on the capping layer, and in the second stage a reducing agent for that species is additionally introduced over the silicon wafer structure so as to reduce the tungsten containing species and deposit tungsten over the seed layer in the contact hole.

Claim 2

A method of fabricating a semiconductor device incorporating a via and an interconnect layer of aluminum or aluminum alloy, the method comprising the steps of: (a) providing a silicon wafer structure; (b) forming an interconnect layer of aluminum or aluminum alloy on the structure; (c) forming a capping layer over the interconnect layer, the capping layer being composed of electrically conductive material; (d) forming a dielectric layer on the capping layer; and (e) selectively depositing an electrically conductive contact on the capping layer in a contact hole of the dielectric layer thereby to form a via, the materials of the capping layer and of the contact being selected wherein after the contact has been deposited on the capping layer at the interlace therebetween there is substantial absence of non-conductive compounds formed from the material of the capping layer, wherein the contact is tungsten and has been deposited in a two stage deposition process in which in the first stage a tungsten containing species is introduced, in the absence of a reducing agent for such species, over the silicon wafer structure, wherein the tunasten containing species reacts with the capping layer in the contact hole to deposit a tungsten seed layer on the capping layer, and in the second stage a reducing agent for that species is additionally introduced over the silicon wafer structure so as to reduce the tungsten containing species and deposit tungsten over the seed layer in the contact hole.

Claim 8

A method of fabricating a semiconductor device incorporating a via and an interconnect layer of aluminum or aluminum alloy, the method comprising the steps of: (a) providing a silicon wafer structure; (b) forming an interconnect layer of aluminum or aluminum alloy on the structure; (c) forming a capping layer over the interconnect layer, the capping layer being selected from the group consisting of tungsten, titanium and titanium nitride; (d) forming a dielectric layer on the capping layer; and (e) selectively depositing a tungsten contact on the capping layer in a contact hole of the dielectric layer thereby to form a via, wherein the contact is deposited in a two stage deposition process in which in the first stage a tungsten containing species is introduced, in the absence of a reducing agent for such species, over the wafer structure, wherein the tungsten containing species reacts with the capping layer in the contact hole to deposit a tungsten seed layer on the capping layer, and in the second stage a reducing agent for that species is additionally introduced over the silicon wafer structure so as to reduce the tungsten containing species and deposit tungsten over the seed layer in the contact hole.

Claim 9

A method of fabricating a semiconductor device incorporating a via and an interconnect layer of aluminum or aluminum alloy, the method comprising the steps of: (a) providing a silicon wafer structure; (b) forming an interconnect layer of aluminum or aluminum alloy on the structure; (c) forming a capping layer over the interconnect layer, the capping layer being selected from the group consisting of tungsten, titanium and titanium nitride; (d) forming a dielectric layer on the capping layer; and (e) selectively depositing a tungsten contact on the capping layer in a contact hole of the dielectric layer thereby to form a via, wherein the contact is deposited in a two stage deposition process in which in the first stage a tungsten containing species is introduced, in the absence of a reducing agent for such species, over the wafer structure, wherein the tungsten containing species reacts with the capping layer in the contact hole to deposit a tungsten seed layer on the capping layer, and in the second stage a reducing agent for that species is additionally introduced over the silicon wafer structure so as to reduce the tungsten containing species and deposit tungsten over the seed layer in the contact hole.

Claim 14

A method of fabricating a semiconductor device incorporating a via and a conductive interconnect layer, the method comprising the steps of: (a) providing a silicon wafer structure; (b) forming a conductive interconnect layer on the structure; (c) forming a capping layer over the interconnect layer, the capping layer being composed of electrically conductive material; (d) forming a dielectric layer on the capping layer; and (e) selectively depositing an electrically conductive contact on the capping layer in a contact hole of the dielectric layer thereby to form a via, the materials of the capping layer and of the contact being selected wherein after the contact has been deposited on the capping layer at the interface therebetween there is substantial absence of non-conductive compounds formed from the material of the capping layer, wherein the contact is tungsten and has been deposited in a two stage deposition process in which in the first stage a tungsten containing species is introduced, in the absence of a reducing agent for such species, over the silicon wafer structure, wherein the tungsten containing species reacts with the capping layer in the contact hole to deposit a tungsten seed layer on the capping layer, and in the second stage a reducing agent for that species is additionally introduced over the silicon wafer structure so as to reduce the tungsten containing species and deposit tungsten over the seed layer in the contact hole.

Claim 15

A method of fabricating a semiconductor device incorporating a via and a conductive interconnect layer, the method comprising the steps of: (a) providing a silicon wafer structure; (b) forming a conductive interconnect layer on the structure; (c) forming a capping layer over the interconnect layer, the capping layer being composed of electrically conductive material; (d) forming a dielectric layer on the capping layer; and (e) selectively depositing an electrically conductive contact on the capping layer in a contact hole of the dielectric layer thereby to form a via, the materials of the capping layer and of the contact being selected wherein after the contact has been deposited on the capping layer at the interface therebetween there is substantial absence of non-conductive compounds formed from the material of the capping layer, wherein the contact is tungsten and has been deposited in a two stage deposition process in which in the first stage a tungsten containing species is introduced, in the absence of a reducing agent for such species, over the silicon wafer structure, wherein the tungsten containing species reacts with the capping layer in the contact hole to deposit a tungsten seed layer on the capping layer, and in the second stage a reducing agent for that species is additionally introduced over the silicon wafer structure so as to reduce the tungsten containing species and deposit tungsten over the seed layer in the contact hole.

Claim 21

A method of fabricating a semiconductor device incorporating a via and a conductive interconnect layer, the method comprising the steps of: (a) providing a silicon wafer structure; (b) forming a conductive interconnect layer on the structure; (c) forming a capping layer over the interconnect layer, the capping layer being selected from the group consisting of tungsten, titanium and titanium nitride; (d) forming a dielectric layer on the capping layer; and (e) selectively depositing a tungsten contact on the capping layer in a contact hole of the dielectric layer thereby to form a via, wherein the contact is deposited in a two stage deposition process in which in the first stage a tungsten containing species is introduced, in the absence of a reducing agent for such species, over the wafer structure, wherein the tungsten containing species reacts with the capping layer in the contact hole to deposit a tungsten seed layer on the capping layer, and in the second stage a reducing agent for that species is additionally introduced over the silicon wafer structure so as to reduce the tungsten containing species and deposit tungsten over the seed layer in the contact hole.

Claim 22

A method of fabricating a semiconductor device incorporating a via and a conductive interconnect layer, the method comprising the steps of: (a) providing a silicon wafer structure; (b) forming a conductive interconnect layer on the structure; (c) forming a capping layer over the interconnect layer, the capping layer being selected from the group consisting of tungsten, titanium and titanium nitride; (d) forming a dielectric layer on the capping layer; and (e) selectively depositing a tungsten contact on the capping layer in a contact hole of the dielectric layer thereby to form a via, wherein the contact is deposited in a two stage deposition process in which in the first stage a tungsten containing species is introduced, in the absence of a reducing agent for such species, over the wafer structure, wherein the tungsten containing species reacts with the capping layer in the contact hole to deposit a tungsten seed layer on the capping layer, and in the second stage a reducing agent for that species is additionally introduced over the silicon wafer structure so as to reduce the tungsten containing species and deposit tungsten over the seed layer in the contact hole.