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US5116665A Expired / Lapsed US ⏱️ 0.0 years remaining

Multilayer protective coating for a substrate, process for protecting a substrate by a plasma deposition of such a coating, coatings obtained and applications thereof

Assignee: LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
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Filing: 1989-05-11
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Granted: 1992-05-26
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Expires: 2009-05-11
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Abstract

Abstract The present invention relates to a multilayer protective coating for a substrate and a process for protecting a substrate by the deposition of a continuous, transparent, amorphous, inorganic coating essentially comprising silicon, carbon, nitrogen, oxygen and hydrogen by means of a plasma. The invention also concerns the application of the coatings according to the invention in the protection of substrates and in particular against electrostatic charges.

Inventors

  • 👤 Jean-Marie Gauthier
  • 👤 Francois Coeuret
  • 👤 Claude Bonet

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 02:50
CPC Classifications
C; C23; C23C; C23C16/00; C23C16/22; C23C16/30; C03; C03C; C03C17/00; C03C17/34; C03C17/3411; C03C17/3429; C03C17/3435; C03C17/3441; C03C17/3482; C23C16/02; C23C16/0227; C23C16/0245; C23C16/308; Y; Y02; Y02T; Y02T50/00; Y02T50/60; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24942; Y10T428/2495; Y10T428/24967; Y10T428/24975; Y10T428/26; Y10T428/263; Y10T428/264; Y10T428/265; Y10T428/31504; Y10T428/31507; Y10T428/31652; Y10T428/31663

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 149 words
A coated body comprising a polymeric substrate having a surface coated with at least two silicon-based transparent layers each formed of a deposited material consisting essentially of silicon, carbon, nitrogen, oxygen and hydrogen, a first of said layers, deposited on the substrate surface being formed of a material having the formula SiC x N y O z H t , in which x does not exceed 0.5; y does not exceed 0.15; z is 0.6-0.8 and t is 0.6-1.2, wherein a second said layer, deposited on said first layer, is formed of a material having the formula SiC x' C x' N y' O z' H t' , in which x' does not exceed 0.5; y' is 0.3-0.8; z' is 1.3-2.5 and t' is 0.5-1.2, and wherein the thickness of the first layer is between 1 and 30 nm and the thicknes of the second layer is 1.25-1.5 μm.
Claim 2
Dependent Claim 149 words
A coated body comprising a polymeric substrate having a surface coated with at least two silicon-based transparent layers each formed of a deposited material consisting essentially of silicon, carbon, nitrogen, oxygen and hydrogen, a first of said layers, deposited on the substrate surface being formed of a material having the formula SiC x N y O z H t , in which x does not exceed 0.5; y does not exceed 0.15; z is 0.6-0.8 and t is 0.6-1.2, wherein a second said layer, deposited on said first layer, is formed of a material having the formula SiC x' C x' N y' O z' H t' , in which x' does not exceed 0.5; y' is 0.3-0.8; z' is 1.3-2.5 and t' is 0.5-1.2, and wherein the thickness of the first layer is between 1 and 30 nm and the thicknes of the second layer is 1.25-1.5 μm.
Claim 3
Dependent Claim 19 words
A body according to claim 1, wherein x' is 0.3-1; y' is 0.5-0.8; z' is 1.3-2; t' is 0.6-1.
Claim 4
Dependent Claim 19 words
A body according to claim 1, wherein the thickness of the first layer is between 5 and 20 nm.
Claim 5
Dependent Claim 12 words
A body according to claim 1, wherein said polymeric substrate is transparent.
Claim 6
Dependent Claim 13 words
A body according to claim 4, wherein said polymeric substrate is a polycarbonate.
Claim 7
Dependent Claim 19 words
A body according to claim 1, wherein the first and second layers are each plasma deposited from precursor gases.
Claim 8
Dependent Claim 147 words
A coated body comprising a transparent polymeric substrate having a surface and at least first and second layers of silicon-based amorphous polymer superimposed on the surface, the first layer being deposited on said surface and having a thickness not exceeding 0.030 μm, the second layer being deposited on the first layer and having a thickness greater than 1 μm, wherein the first layer is formed of a material having the formula SiC x N y O z H t , in which x does not exceed 0.5; y does not exceed 0.15; z is comprised between 0.4-1 and t is comprised between 0.6-1.2, and the second layer is formed of a material having the formula SiC x' N y' O z' H t' , in which x' does not exceed 0.5; y' is comprised between 0.3-0.8; z' is comprised between 1.3-2.5 and t' is comprised between 0.5-1.2.
Claim 9
Dependent Claim 147 words
A coated body comprising a transparent polymeric substrate having a surface and at least first and second layers of silicon-based amorphous polymer superimposed on the surface, the first layer being deposited on said surface and having a thickness not exceeding 0.030 μm, the second layer being deposited on the first layer and having a thickness greater than 1 μm, wherein the first layer is formed of a material having the formula SiC x N y O z H t , in which x does not exceed 0.5; y does not exceed 0.15; z is comprised between 0.4-1 and t is comprised between 0.6-1.2, and the second layer is formed of a material having the formula SiC x' N y' O z' H t' , in which x' does not exceed 0.5; y' is comprised between 0.3-0.8; z' is comprised between 1.3-2.5 and t' is comprised between 0.5-1.2.
Claim 10
Dependent Claim 26 words
The body of claim 7, wherein the transparent polymeric substrate is selected from the group consisting of polycarbonate, acrylonitrile polystyrene, crystalline polystyrene, polyimide, polyamide and polyester.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-05-26 1995-11-25 1996-05-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-05-26 1999-11-25 2000-05-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-05-26 2003-11-25 2004-05-26 $7700.00 Window Closed / Lapsed

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