Method for forming a metal film on a substrate

Claim 1

A method for forming a metal deposited film on a substrate in a film forming space, which comprises: introducing into a reaction space a gaseous or gasifiable starting material containing a transition metal element for formation of said metal film and fluorine as a gaseous halogenic oxidizing agent having the property of oxidation action on said starting material for formation of said metal film; forming a mixture to effect chemical contact between said starting material and said fluorine through a gas introducing conduit system and thereby chemically producing a plural number of precursors including precursors in an excited state, said gas introducing conduit system including a plurality of coaxially aligned conduits each having an exit orifice with an outer conduit adapted to carry said fluorine and at least one inner conduit adapted to carry the starting material, said coaxially aligned conduits extending into said reaction space such that the exit orifice of said at least one inner conduit is set back from the exit orifice of the outer conduit to enable the fluorine in the outer conduit to surround the starting material exiting said at least one inner conduit, said substrate positioned form 5 mm. to 15 cm. from the exit orifice of said outer conduit; and depositing said metal film on said substrate including at least one of said precursors as the feeding source for the constituent element of the film.

Claim 2

A method for forming a metal deposited film on a substrate in a film forming space, which comprises: introducing into a reaction space a gaseous or gasifiable starting material containing a transition metal element for formation of said metal film and fluorine as a gaseous halogenic oxidizing agent having the property of oxidation action on said starting material for formation of said metal film; forming a mixture to effect chemical contact between said starting material and said fluorine through a gas introducing conduit system and thereby chemically producing a plural number of precursors including precursors in an excited state, said gas introducing conduit system including a plurality of coaxially aligned conduits each having an exit orifice with an outer conduit adapted to carry said fluorine and at least one inner conduit adapted to carry the starting material, said coaxially aligned conduits extending into said reaction space such that the exit orifice of said at least one inner conduit is set back from the exit orifice of the outer conduit to enable the fluorine in the outer conduit to surround the starting material exiting said at least one inner conduit, said substrate positioned form 5 mm. to 15 cm. from the exit orifice of said outer conduit; and depositing said metal film on said substrate including at least one of said precursors as the feeding source for the constituent element of the film.