Patent US4605804A successfully refreshed from Google Patents.
US4605804A
Expired / Lapsed
US
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Acid-catalyzed organic compound conversion
Assignee: Mobil Oil AS
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Filing: 1985-10-15
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Granted: 1986-08-12
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Expires: 2005-10-15
Abstract
Abstract Substitution of aluminum or gallium for boron or iron contained in the framework of a high silica content zeolite is effected by treating the zeolite in liquid water in the presence of a compound of aluminum or gallium. Catalyst comprising the treated zeolite is used for conducting acid-catalyzed reactions of organic compounds, e.g. conversion of oxygenates to hydrocarbons.
Inventors
- 👤 Clarence D. Chang
- 👤 Joseph N. Miale
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 17:28
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/40; B01J29/70; B01J29/7007; B01J2229/00; B01J2229/10; B01J2229/26; B01J2229/30; B01J2229/36; B01J2229/42; Y; Y10; Y10S; Y10S423/00; Y10S423/22; Y10S423/23; Y10S423/29; Y10S423/33
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
104 words
A process for converting feedstock comprising organic compounds selected from the group consisting of alcohol, compound containing a carbonyl group, ether and mixtures thereof to conversion product comprising hydrocarbon compounds which comprises contacting said feedstock at conditions sufficient to convert said feedstick to said product hydrocarbons, with a catalyst composition prepared by a method for substituting aluminum or gallium for boron or iron contained in the robust framework of a high silica content crystalline zeolite, which method comprises hydrothermally treating said zeolite in the presence of a compound of said aluminum or gallium, said hydrothermal treatment being under conditions effective to induce said substitution.
Claim 2
Dependent Claim
104 words
A process for converting feedstock comprising organic compounds selected from the group consisting of alcohol, compound containing a carbonyl group, ether and mixtures thereof to conversion product comprising hydrocarbon compounds which comprises contacting said feedstock at conditions sufficient to convert said feedstick to said product hydrocarbons, with a catalyst composition prepared by a method for substituting aluminum or gallium for boron or iron contained in the robust framework of a high silica content crystalline zeolite, which method comprises hydrothermally treating said zeolite in the presence of a compound of said aluminum or gallium, said hydrothermal treatment being under conditions effective to induce said substitution.
Claim 3
Dependent Claim
14 words
The process of claim 1 wherein said aluminum or gallium compound is water soluble.
Claim 4
Dependent Claim
14 words
The process of claim 1 wherein said aluminum or gallium compound is an oxide.
Claim 5
Dependent Claim
17 words
The process of claim 3 wherein said aluminum compound is an oxide binder composited with said zeolite.
Claim 6
Dependent Claim
24 words
The process of claim 1 wherein said high silica content crystalline zeolite has the structure of ZSM-5, ZSM-11, ZSM-12, ZSM-23, ZSM-35, ZSM-38 or ZSM-48.
Claim 7
Dependent Claim
11 words
The process of claim 4 wherein said oxide binder is alumina.
Claim 8
Dependent Claim
13 words
The process of claim 5 wherein said zeolite has the structure of ZSM-5.
Claim 9
Dependent Claim
13 words
The process of claim 6 wherein said zeolite has the structure of ZSM-5.
Claim 10
Dependent Claim
22 words
The process of claim 1 wherein said hydrothermal treatment conditions include a temperature of from about 50° C. to about 375° C.
Claim 11
Dependent Claim
50 words
A process of claim 1 wherein said conversion conditions include a temperature of from about 275° C. to about 600° C., a pressure of from about 0.5 atmosphere to about 50 atmospheres and a liquid hourly space velocity of from about 0.5 hr -1 to about 100 hr -1 .
Claim 12
Dependent Claim
10 words
The process of claim 1 wherein said alcohol is methanol.
Claim 13
Dependent Claim
109 words
A process for converting feedstock comprising organic compounds selected from the group consisting of alcohol, compound containing a carbonyl group, ether and mixtures thereof to conversion product comprising hydrocarbon compounds which comprises contacting said feedstock at conditions sufficient to convert said feedstick to said product hydrocarbons, with a catalyst composition prepared by a method for substituting aluminum or gallium for boron or iron contained in the robust framework of a high silica content crystalline zeolite having the structure of ZSM-5, which method comprises hydrothermally treating said zeolite in the presence of a compound of said aluminum or gallium, said hydrothermal treatment being under conditions effective to induce said substitution.
Claim 14
Dependent Claim
109 words
A process for converting feedstock comprising organic compounds selected from the group consisting of alcohol, compound containing a carbonyl group, ether and mixtures thereof to conversion product comprising hydrocarbon compounds which comprises contacting said feedstock at conditions sufficient to convert said feedstick to said product hydrocarbons, with a catalyst composition prepared by a method for substituting aluminum or gallium for boron or iron contained in the robust framework of a high silica content crystalline zeolite having the structure of ZSM-5, which method comprises hydrothermally treating said zeolite in the presence of a compound of said aluminum or gallium, said hydrothermal treatment being under conditions effective to induce said substitution.
Claim 15
Dependent Claim
14 words
The process of claim 12 wherein said aluminum or gallium compound is water soluble.
Claim 16
Dependent Claim
14 words
The process of claim 12 wherein said aluminum or gallium compound is an oxide.
Claim 17
Dependent Claim
17 words
The process of claim 14 wherein said aluminum compound is an oxide binder composited with said zeolite.
Claim 18
Dependent Claim
11 words
The process of claim 15 wherein said oxide binder is alumina.
Claim 19
Dependent Claim
50 words
The process of claim 12 wherein said conversion conditions include a temperature of from about 275° C. to about 600° C., a pressure of from about 0.5 atmosphere to about 50 atmospheres and a liquid hourly space velocity of from about 0.5 hr -1 to about 100 hr -1 .
Claim 20
Dependent Claim
10 words
The process of claim 12 wherein said alcohol is methanol.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-08-11 | 1990-02-10 | 1990-08-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-08-11 | 1994-02-10 | 1994-08-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-08-11 | 1998-02-10 | 1998-08-12 | $7700.00 | Window Closed / Lapsed |