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US4515668A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of forming a dielectric layer comprising a gettering material

Assignee: Atmel Corp
•
Filing: 1984-04-25
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Granted: 1985-05-07
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Expires: 2004-04-25
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Abstract

Abstract The present invention comprises a method of forming a thin film dielectric layer on a substrate. The method comprises providing a sputtering chamber having a dielectric target disposed on a target electrode. A substrate to be covered with a thin film dielectric layer is introduced into the sputtering chamber and the substrate is located on a substrate holder electrode spaced from the target electrode. The chamber is then evacuated, and a sputtering atmosphere comprising an inert gas and a gas containing an element of a gettering material is introduced into the chamber. The gas containing an element of a gettering material is transferred into the chamber through a metering valve from a container outside the chamber. An RF potential is applied across the target electrode and the substrate electrode to establish a glow discharge in the region between the electrodes. Finally, a thin film dielectric layer doped with a gettering material is formed by a chemical reaction in the chamber.

Inventors

  • 👤 David J. Brownell
  • 👤 Jon A. Roberts

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 18:19
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/63; H10P14/6326; H10P14/6328; H10P14/6334; H10P14/6336; C; C23; C23C; C23C14/00; C23C14/22; C23C14/34; H10P14/69; H10P14/692; H10P14/6921; H10P14/6922; H10P14/6923; H10W; H10W76/00; H10W76/40; H10W76/42; H10W76/48

Claims Analysis

Total Claims: 29
Claim 1
Independent Claim 151 words
A method of forming a thin film dielectric layer on a substrate, comprising: providing a sputtering chamber having a dielectric target disposed on a target electrdode; introducing into the sputtering chamber a substrate to be covered with a thin film dielectric layer and locating the substrate on a substrate holder electrode spaced from the target electrode; evacuating the chamber; introducing into the chamber a sputtering atmosphere comprising an inert gas and a gas containing an element of a gettering material, the gas containing an element of a gettering material being transferred into the chamber through a metering valve from a container outside the chamber; and applying an RF potential across the target electrode and the substrate holder electrode to establish a glow discharge in the region between the electrodes in order to deposit a thin film dielectric layer doped with a gettering material formed by a chemical reaction in the chamber.
Claim 2
Independent Claim 151 words
A method of forming a thin film dielectric layer on a substrate, comprising: providing a sputtering chamber having a dielectric target disposed on a target electrdode; introducing into the sputtering chamber a substrate to be covered with a thin film dielectric layer and locating the substrate on a substrate holder electrode spaced from the target electrode; evacuating the chamber; introducing into the chamber a sputtering atmosphere comprising an inert gas and a gas containing an element of a gettering material, the gas containing an element of a gettering material being transferred into the chamber through a metering valve from a container outside the chamber; and applying an RF potential across the target electrode and the substrate holder electrode to establish a glow discharge in the region between the electrodes in order to deposit a thin film dielectric layer doped with a gettering material formed by a chemical reaction in the chamber.
Claim 3
Dependent Claim 16 words
The method of claim 1 wherein a DC potential is applied across the substrate holder electrode.
Claim 4
Dependent Claim 20 words
The method of claim 2 wherein the gas containing an element of a gettering material includes phosphorous as an element.
Claim 5
Dependent Claim 30 words
The method of claim 3 wherein the gas containing an element of a gettering material is selected from the group consisting of PH 3 , POCl and PF 3 .
Claim 6
Dependent Claim 13 words
The method of claim 4 wherein the dielectric target comprises SiO 2 .
Claim 7
Dependent Claim 20 words
The method of claim 1 wherein the gas containing an element of a gettering material includes phosphorous as an element.
Claim 8
Dependent Claim 30 words
The method of claim 6 wherein the gas containing an element of a gettering material is selected from the group consisting of PH 3 , POCl and PF 3 .
Claim 9
Dependent Claim 13 words
The method of claim 7 wherein the dielectric target comprises SiO 2 .
Claim 10
Dependent Claim 13 words
The method of claim 1 wherein the dielectric target comprises SiO 2 .
Claim 11
Independent Claim 230 words
A method of forming a dielectric layer doped with a gettering material over a surface of a substrate and of separating the doped layer from the surface by a dielectric layer substantially devoid of the gettering material, comprising: providing a sputtering chamber having a dielectric target disposed on a target electrode; introducing into the sputtering chamber a substrate and locating the substrate on a substrate holder electrode spaced from the target electrode; evacuating the chamber; introducing into the chamber a sputtering atmosphere comprising an inert gas, the sputtering atmosphere being substantially devoid of a gettering material; applying an RF potential across the target electrode and the substrate holder electrode to establish a glow discharge in the region between the electrodes; forming a first dielectric layer substantially devoid of a gettering material onto a surface of the substrate; introducing into the chamber a gas containing an element of a gettering material, the gas containing an element of a gettering material being transferred into the chamber through a metering valve from a container outside the chamber; and applying an RF potential across the target electrode and the substrate holder electrode to establish a glow discharge in the region between the electrodes in order to deposit a second dielectric layer over the first dielectric layer, the second dielectric layer being doped with a gettering material formed by a chemical reaction in the chamber.
Claim 12
Independent Claim 230 words
A method of forming a dielectric layer doped with a gettering material over a surface of a substrate and of separating the doped layer from the surface by a dielectric layer substantially devoid of the gettering material, comprising: providing a sputtering chamber having a dielectric target disposed on a target electrode; introducing into the sputtering chamber a substrate and locating the substrate on a substrate holder electrode spaced from the target electrode; evacuating the chamber; introducing into the chamber a sputtering atmosphere comprising an inert gas, the sputtering atmosphere being substantially devoid of a gettering material; applying an RF potential across the target electrode and the substrate holder electrode to establish a glow discharge in the region between the electrodes; forming a first dielectric layer substantially devoid of a gettering material onto a surface of the substrate; introducing into the chamber a gas containing an element of a gettering material, the gas containing an element of a gettering material being transferred into the chamber through a metering valve from a container outside the chamber; and applying an RF potential across the target electrode and the substrate holder electrode to establish a glow discharge in the region between the electrodes in order to deposit a second dielectric layer over the first dielectric layer, the second dielectric layer being doped with a gettering material formed by a chemical reaction in the chamber.
Claim 13
Dependent Claim 108 words
The method of claim 10 wherein the last forming step is followed by the steps of: evacuating the chamber; providing a sputtering atmosphere comprising an inert gas, the sputtering atmosphere being substantially devoid of a gettering material; and applying an RF potential across the target electrode and the substrate holder electrode to establish a glow discharge in the region between the electrodes in order to deposit a third dielectric layer over the second layer of dielectric material doped with a gettering material; whereby the second layer of dielectric material doped with the gettering material is disposed between two layers of dielectric material substantially devoid of the gettering material.
Claim 14
Dependent Claim 16 words
The method of claim 11 wherein a DC potential is applied across the substrate holder electrode.
Claim 15
Dependent Claim 20 words
The method of claim 12 wherein the gas containing an element of a gettering material includes phosphorous as an element.
Claim 16
Dependent Claim 30 words
The method of claim 13 wherein the gas containing an element of a gettering material is selected from the group consisting of PH 3 , POCl and PF 3 .
Claim 17
Dependent Claim 13 words
The method of claim 14 wherein the dielectric target comprises SiO 2 .
Claim 18
Dependent Claim 20 words
The method of claim 11 wherein the gas containing an element of a gettering material includes phosphorous as an element.
Claim 19
Dependent Claim 30 words
The method of claim 16 wherein the gas containing an element of a gettering material is selected from the group consisting of PH 3 , POCl and PF 3 .
Claim 20
Dependent Claim 13 words
The method of claim 17 wherein the dielectric target comprises SiO 2 .
Claim 21
Dependent Claim 13 words
The method of claim 11 wherein the dielectric target comprises SiO 2 .
Claim 22
Dependent Claim 16 words
The method of claim 10 wherein a DC potential is applied across the substrate holder electrode.
Claim 23
Dependent Claim 20 words
The method of claim 20 wherein the gas containing an element of a gettering material includes phosphorous as an element.
Claim 24
Dependent Claim 30 words
The method of claim 21 wherein the gas containing an element of a gettering material is selected from the group consisting of PH 3 , POCl and PF 3 .
Claim 25
Dependent Claim 13 words
The method of claim 22 wherein the dielectric target comprises SiO 2 .
Claim 26
Dependent Claim 20 words
The method of claim 10 wherein the gas containing an element of a gettering material includes phosphorous as an element.
Claim 27
Dependent Claim 30 words
The method of claim 24 wherein the gas containing an element of a gettering material is selected from the group consisting of PH 3 , POCl and PF 3 .
Claim 28
Dependent Claim 13 words
The method of claim 25 wherein the dielectric target comprises SiO 2 .
Claim 29
Dependent Claim 13 words
The method of claim 10 wherein the dielectric target comprises SiO 2 .

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-05-06 1988-11-05 1989-05-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-05-06 1992-11-05 1993-05-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-05-06 1996-11-05 1997-05-07 $7700.00 Window Closed / Lapsed

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