Patent US4470189A successfully refreshed from Google Patents.
US4470189A
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Process for making polycide structures
Assignee: International Business Machines Corp
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Filing: 1983-05-23
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Granted: 1984-09-11
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Expires: 2003-05-23
Abstract
Abstract An improved method for making polycide structures for use in electrode and wiring interconnection applications. It includes depositing a layer of polysilicon on an insulating layer and forming on this polysilicon layer a silicide structure and a silicon capping layer. The deposited layers are defined and etched through dry etching techniques using a dry etching mask made of a refractory metal that does not form a volatile halide in a dry etching environment. Metals with such characteristics include cobalt (Co), nickel (Ni), iron (Fe), and manganese (Mn). The metal mask and the other deposited layers may be formed and defined using a photoresist mask as a deposition mask formed to be compatible with lift-off techniques. The silicide may be deposited either through a chemical vapor deposition process or through evaporation techniques. If it is formed through the co-evaporation of metal and silicon, then the structure is subjected to a low temperature reaction annealing step at a temperature between 500° and 600° C. prior to dry etching. To avoid a diffusion of the metal mask into the silicon layer, during this low temperature annealing, the process provides for the formation of a diffusion barrier layer between the metal mask and the silicon layer. Following the removal of the metal mask and the diffusion barrier layer, the structure is annealed at a temperature sufficient to cause the homogenization of the silicide layer.
Inventors
- 👤 Stanley Roberts
- 👤 Francis R. White
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 19:58
CPC Classifications
H; H10; H10D; H10D30/00; H10D30/01; H10D30/021; H10D30/0223; H10D64/00; H10D64/01; H10D64/013; H10D64/01302; H10D64/01304; H10D64/01306; H10D64/01308; H10D64/01312; H10D64/01326; H10P; H10P50/00; H10P50/20; H10P50/26; H10P50/264; H10P50/266; H10P50/267; H10P50/268; H10P50/60; H10P50/66; H10P50/663; H10P50/667; H10P76/00; H10P76/20; H10P76/202; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/056; H10W20/058; H10W20/064; H10W20/066; Y; Y10; Y10S; Y10S148/00; Y10S148/084; Y10S438/00; Y10S438/942; Y10S438/948; Y10S438/951
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
191 words
A process for making a polycide structure comprising the steps of: depositing a polysilicon layer on an insulating layer; forming on said polysilicon layer a photoresist mask defining and exposing predetermined areas of said polysilicon layer; co-depositing silicon and a silicide forming metal on exposed portions of said polysilicon layer, thereby forming a composite metal-silicon layer on said polysilicon layer; depositing a layer of silicon over said metal-silicon layer; depositing a diffusion barrier layer on said layer of silicon; depositing a layer of a metal on said diffusion barrier layer, said metal selected from a group consisting of refractory metals that resist etching in a dry etching environment and which metals can be selectively removed from the underlying layers by wet etching techniques; removing said photoresist mask and all excess materials on said mask; reaction annealing said structure to cause said silicide forming metal and said silicon in said composite metal-silicon layer to react and form a metal silicide layer; removing through dry etching the exposed portions of said polysilicon layer; removing said layer of refractory metal and said diffusion barrier layer; annealing said structure to homogenize said metal silicide layer.
Claim 2
Dependent Claim
191 words
A process for making a polycide structure comprising the steps of: depositing a polysilicon layer on an insulating layer; forming on said polysilicon layer a photoresist mask defining and exposing predetermined areas of said polysilicon layer; co-depositing silicon and a silicide forming metal on exposed portions of said polysilicon layer, thereby forming a composite metal-silicon layer on said polysilicon layer; depositing a layer of silicon over said metal-silicon layer; depositing a diffusion barrier layer on said layer of silicon; depositing a layer of a metal on said diffusion barrier layer, said metal selected from a group consisting of refractory metals that resist etching in a dry etching environment and which metals can be selectively removed from the underlying layers by wet etching techniques; removing said photoresist mask and all excess materials on said mask; reaction annealing said structure to cause said silicide forming metal and said silicon in said composite metal-silicon layer to react and form a metal silicide layer; removing through dry etching the exposed portions of said polysilicon layer; removing said layer of refractory metal and said diffusion barrier layer; annealing said structure to homogenize said metal silicide layer.
Claim 3
Dependent Claim
31 words
A process as set forth in claim 1 wherein said layer of refractory metal on said diffusion barrier layer is selected from the group consisting of cobalt, iron, nickel, and manganese.
Claim 4
Dependent Claim
18 words
A process as set forth in claim 2 wherein said diffusion barrier layer is a layer of tungsten.
Claim 5
Dependent Claim
16 words
A process as set forth in claim 3 wherein said dry etching is a RIE step.
Claim 6
Dependent Claim
23 words
A process as set forth in claim 4 wherein said insulating layer is a layer of silicon dioxide formed on a silicon substrate.
Claim 7
Dependent Claim
22 words
A process as set forth in claim 5, wherein said reaction annealing takes place at a temperature between 500° and 600° C.;
Claim 8
Dependent Claim
86 words
A process as set forth in claim 6, which further includes the step of forming source and drain regions in said silicon substrate following the removal of said exposed portions of said polysilicon layer and said refractory metal and said diffusion barrier layer, wherein said regions are formed by ion implantation through said silicon dioxide layer using the structure of said deposited layers as a gate electrode and wherein said gate electrode acts as an implantation mask for the formation of self-aligned source and drain regions.
Claim 9
Dependent Claim
27 words
A claim as set forth in claim 7 wherein said annealing to homogenize said metal silicide layer takes place at a temperature between 950° and 1100° C.
Claim 10
Dependent Claim
234 words
A process for making a polycide structure comprising the steps of: forming an insulating layer on a silicon substrate; depositing a polysilicon layer on said insulating layer; depositing a photoresist layer onto said insulating layer; forming an opening in said photoresist layer to expose predetermined portions of the surface of said polysilicon layer; co-depositing a refractory metal and silicon through said opening to form a composite metal-silicon layer on said exposed surface of said polysilicon layer; depositing silicon onto said composite metal-silicon layer to form a silicon layer; depositing a layer of tungsten onto said silicon layer to form a diffusion barrier layer; depositing a layer of a metal selected from the group consisting of cobalt, nickel, iron, and manganese onto said diffusion barrier layer to form a metal mask; removing through wet etching the remains of said photoresist layer, thereby exposing underlying portions of said polysilicon layer; reaction annealing said layers in an inert atmosphere at a temperature which is high enough to cause said composite metal-silicon layer to partially convert into a metal-silicide but not high enough to cause a reaction between said silicon layer and said diffusion barrier layer; removing through dry etching said exposed portions of said polysilicon layer down to the underlying deposited layers using said metal mask removing said metal mask and said layer of tungsten; annealing said layers at a temperature sufficient to homogenize said metal-silicide layer.
Claim 11
Dependent Claim
234 words
A process for making a polycide structure comprising the steps of: forming an insulating layer on a silicon substrate; depositing a polysilicon layer on said insulating layer; depositing a photoresist layer onto said insulating layer; forming an opening in said photoresist layer to expose predetermined portions of the surface of said polysilicon layer; co-depositing a refractory metal and silicon through said opening to form a composite metal-silicon layer on said exposed surface of said polysilicon layer; depositing silicon onto said composite metal-silicon layer to form a silicon layer; depositing a layer of tungsten onto said silicon layer to form a diffusion barrier layer; depositing a layer of a metal selected from the group consisting of cobalt, nickel, iron, and manganese onto said diffusion barrier layer to form a metal mask; removing through wet etching the remains of said photoresist layer, thereby exposing underlying portions of said polysilicon layer; reaction annealing said layers in an inert atmosphere at a temperature which is high enough to cause said composite metal-silicon layer to partially convert into a metal-silicide but not high enough to cause a reaction between said silicon layer and said diffusion barrier layer; removing through dry etching said exposed portions of said polysilicon layer down to the underlying deposited layers using said metal mask removing said metal mask and said layer of tungsten; annealing said layers at a temperature sufficient to homogenize said metal-silicide layer.
Claim 12
Dependent Claim
19 words
A process as set forth in claim 9, wherein said refractory metal and said silicon are deposited by co-evaporation.
Claim 13
Dependent Claim
29 words
A process as set forth in claim 10 wherein said refractory metal is a metal selected from the group consisting of molybdenum, tungsten, tantalum, iridium, titanium, cobalt, and rhodium.
Claim 14
Dependent Claim
20 words
A process as set forth in claim 11 wherein said dry etching of said polysilicon layer is accomplished through RIE.
Claim 15
Dependent Claim
27 words
A process as set forth in claim 12 wherein said metal mask is removed by wet etching with a mixture of hydrochloric acid, hydrogen peroxide, and water.
Claim 16
Dependent Claim
27 words
A process as set forth in claim 13 wherein said tungsten layer is removed by wet etching with a mixture of ammonium hydroxide, hydrogen peroxide, and water.
Claim 17
Dependent Claim
25 words
A process as set forth in claim 14 wherein said annealing to homogenize said metal-silicide layer takes place at temperature between 950° and 1100° C.
Claim 18
Dependent Claim
30 words
A process as set forth in claim 15 which further includes forming source and drain regions in said substrate through ion implantation using said deposited layers as an implantation mask.
Claim 19
Dependent Claim
166 words
A process for making a polycide structure comprising the steps of: depositing a polysilicon layer on an insulating layer; depositing a metal silicide layer on exposed portions of said polysilicon layer; depositing a layer of silicon over said layer of metal silicide; forming on said polysilicon layer a photoresist mask defining and exposing predetermined areas on said polysilicon layer; depositing a metal layer on said layer of silicon, said metal selected from a group consisting of refractory metals that do not form volatile halides in a reactive ion etching environment and which metals can be removed using reactive ion etching techniques with etchants that remove said metal without removing the underlying layers; removing said photoresist mask and all excess materials on said mask; removing through reactive ion etching portions of said silicon, said metal silicide and said polysilicon layers, using said layer of refractory metal as an etching mask; removing said metal layer through wet etching techniques; annealing said structure to homogenize said metal silicide layer.
Claim 20
Dependent Claim
166 words
A process for making a polycide structure comprising the steps of: depositing a polysilicon layer on an insulating layer; depositing a metal silicide layer on exposed portions of said polysilicon layer; depositing a layer of silicon over said layer of metal silicide; forming on said polysilicon layer a photoresist mask defining and exposing predetermined areas on said polysilicon layer; depositing a metal layer on said layer of silicon, said metal selected from a group consisting of refractory metals that do not form volatile halides in a reactive ion etching environment and which metals can be removed using reactive ion etching techniques with etchants that remove said metal without removing the underlying layers; removing said photoresist mask and all excess materials on said mask; removing through reactive ion etching portions of said silicon, said metal silicide and said polysilicon layers, using said layer of refractory metal as an etching mask; removing said metal layer through wet etching techniques; annealing said structure to homogenize said metal silicide layer.
Claim 21
Dependent Claim
28 words
A process as set forth in claim 17 wherein said metal layer is made of a metal selected from the group consisting of cobalt, iron, nickel, and manganese.
References Cited (Backward Citations)
US4180596A
Cited
US4128670A
Cited
US4329706A
Cited
US4360414A
Cited
US4352716A
Cited
US4362597A
Cited
US4389257A
Cited
US4378628A
Cited
US4398341A
Cited
US4414057A
Cited
US4411734A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-09-11 | 1988-03-12 | 1988-09-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-09-11 | 1992-03-12 | 1992-09-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-09-11 | 1996-03-12 | 1996-09-11 | $7700.00 | Window Closed / Lapsed |