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US6063639A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for fabricating ferroelectric capacitor of nonvolatile semiconductor memory device using plasma

Assignee: SK Hynix Inc
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Filing: 1999-10-28
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Granted: 2000-05-16
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Expires: 2019-10-28
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Abstract

Abstract A method for fabricating a ferroelectric capacitor of nonvolatile semiconductor memory device includes the steps of forming an amorphous layer on a resulting structure after performing a specific process, forming perovskite nuclei within the amorphous layer by an oxidation reaction in plasma atmosphere and performing a thermal process for growing the grains to form a ferroelectric thin film. The perovskite nuclei are formed at a low temperature, so that the ferroelectric capacitor has improved properties such as high density, high polarization and low leakage current.

Inventors

  • 👤 Nam Kyeong Kim
  • 👤 Seung Jin Yeom

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:29
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/63; H10P14/6302; H10P14/6322; H10D; H10D1/00; H10D1/60; H10D1/68; H10D1/682; H10D64/00; H10D64/60; H10D64/66; H10D64/68; H10D64/689; H10P14/6304; H10P14/6319; H10P14/6326; H10P14/6328; H10P14/6334; H10P14/6336; H10P95/00; H10P95/90; H10P14/69; H10P14/692; H10P14/6938; H10P14/69398

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 56 words
A method for fabricating a ferroelectric capacitor, comprising the steps of: a) forming an amorphous layer on a resulting structure after performing a specific process; b) forming perovskite nuclei within the amorphous layer by an oxidation reaction in plasma atmosphere; and c) performing a thermal process for growing the grains to form a ferroelectric thin film.
Claim 2
Independent Claim 56 words
A method for fabricating a ferroelectric capacitor, comprising the steps of: a) forming an amorphous layer on a resulting structure after performing a specific process; b) forming perovskite nuclei within the amorphous layer by an oxidation reaction in plasma atmosphere; and c) performing a thermal process for growing the grains to form a ferroelectric thin film.
Claim 3
Dependent Claim 54 words
The method as recited in claim 1, wherein the step b) further includes the step of diffusing one or a combination selected from the groups consisting of N 2 O(gas), O 2 (gas), H 2 O(gas), N 2 O(gas)+H 2 O(liquid) and O 2 (gas)H 2 O(liquid) into a chamber which maintains plasma atmosphere.
Claim 4
Dependent Claim 38 words
The method as recited in claim 2, wherein the plasma atmosphere in the step b) is maintained at a plasma power of 80 W to 800 W using RF (radio frequency) method or ECR (electron cyclotron resonance) method.
Claim 5
Dependent Claim 22 words
The method as recited in claim 3, wherein the plasma atmosphere is maintained at a pressure of 0.5 Torr to 5 Torr.
Claim 6
Dependent Claim 22 words
The method as recited in claim 4, wherein the plasma atmosphere is maintained at a temperature of 350° C. to 550° C.
Claim 7
Dependent Claim 31 words
The method as recited in claim 2, wherein the amorphous layer includes one or a combination selected from the groups consisting of strontium (Sr), bismuth (Bi), tantalum (Ta) and niobium (Nb).
Claim 8
Dependent Claim 20 words
The method as recited in claim 6, wherein the step b) further includes the step of baking the amorphous layer.
Claim 9
Dependent Claim 31 words
The method as recited in claim 7, wherein the baking process includes a first process for volatilizing xylene and butyl acetate and a second process for volatilizing 2-ethylhexanoate and 2-ethylhexanoic acid.
Claim 10
Dependent Claim 22 words
The method as recited in claim 8, wherein the baking process is performed at a temperature of 150° C. to 300° C.
Claim 11
Dependent Claim 25 words
The method as recited in claim 9, wherein the amorphous layer in step a) is formed to a thickness of 800 Å to 3000 Å.
Claim 12
Dependent Claim 38 words
The method as recited in claim 10, wherein the plasma atmosphere in the step b) is maintained at a plasma power of 80 W to 200 W using RF (radio frequency) method or ECR (electron cyclotron resonance) method.
Claim 13
Dependent Claim 22 words
The method as recited in claim 11, wherein the plasma atmosphere is maintained at a pressure of 0.5 Torr to 5 Torr.
Claim 14
Dependent Claim 22 words
The method as recited in claim 12, wherein the plasma atmosphere is maintained at a temperature of 350° C. to 550° C.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2003-05-16 2003-11-15 2004-05-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2007-05-16 2007-11-15 2008-05-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2011-05-16 2011-11-15 2012-05-16 $7700.00 Window Closed / Lapsed

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