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Liquid precursors for formation of metal oxides

Assignee: Harvard University
•
Filing: 1998-04-17
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Granted: 1999-11-09
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Expires: 2018-04-17
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Abstract

Abstract A liquid precursor is provided for the formation of metal oxide films comprising a mixture of two ro more types of beta-diketonate ligands bound to one or more metals. For example, a liquid mixture was formed of the mixed aluminum beta-diketonates derived from two or more of the ligands 2,6-dimethyl-3,5-heptanedione; 2,7-dimethyl-3,5-heptanedione; 2,6-dimethyl-3,5-octanedione; 2,2,6-trimethyl-3,5-heptanedione; 2,8-dimethyl-4,6-nonanedione; 2,7-dimethyl-4,6-nonanedione; 2,2,7-trimethyl-3,5-octanedione; and 2,2,6-trimethyl-3,5-octanedione. Films of metal oxides are deposited from vaporized precursor mixtures of metal beta-diketonates and, optionally, oxygen or other sources of oxygen. This process may be used to deposit high-purity, transparent metal oxide films on a substrate. The liquid mixtures may also be used for spray coating, spin coating and sol-gel deposition of materials.

Inventors

  • 👤 Roy G. Gordon

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 02:37
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/02; C23C18/12; C23C18/1204; C23C18/1208; C23C18/1216; C23C16/00; C23C16/22; C23C16/30; C23C16/40; C23C18/125; C23C18/1254

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 66 words
A process for forming a metal-containing film, comprising: providing a mixture of metal beta-diketonates, said metal beta-diketonates containing one or more metal types and two or more beta-diketonate types, in which at least one of the metal beta-diketonates contains two or more types of beta-diketonate ligand bound to the metal; and contacting the mixture to a surface in a deposition process to deposit a metal-containing material.
Claim 2
Dependent Claim 66 words
A process for forming a metal-containing film, comprising: providing a mixture of metal beta-diketonates, said metal beta-diketonates containing one or more metal types and two or more beta-diketonate types, in which at least one of the metal beta-diketonates contains two or more types of beta-diketonate ligand bound to the metal; and contacting the mixture to a surface in a deposition process to deposit a metal-containing material.
Claim 3
Dependent Claim 16 words
The process of claim 1 in which the deposited material comprises one or more metal oxides.
Claim 4
Dependent Claim 22 words
The process of claim 1 in which the metal or metals are selected from the group consisting of barium, strontium and titanium.
Claim 5
Dependent Claim 23 words
The process of claim 1 in which the metal or metals are selected from the group consisting of strontium, bismuth, niobium and tantalum.
Claim 6
Dependent Claim 22 words
The process of claim 1, wherein a sol-gel process is used to deposit material containing one or more metals or metal oxides.
Claim 7
Dependent Claim 24 words
The process of claim 1, wherein a spray-coating or spin-coating process is used to deposit material containing one or more metals or metal oxides.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2002-11-08 2003-05-10 2003-11-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2006-11-08 2007-05-10 2007-11-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2010-11-08 2011-05-10 2011-11-09 $7700.00 Window Closed / Lapsed

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