US5747594A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polyolefin compositions exhibiting heat resistivity, low hexane-extractives and controlled modulus
Assignee: Dow Chemical Co
•
Filing: 1997-01-27
•
Granted: 1998-05-05
•
Expires: 2017-01-27
Abstract
Abstract The subject invention provides a polymer mixture having high heat resistivity, low hexane extractive and controllably lower or higher modulus. The mixture is comprised of at least one first substantially linear ethylene polymer, Component (A), and at least one second ethylene polymer which is a homogeneously branched polymer, heterogeneously branched linear polymer or a non-short chain branched linear polymer. When fabricated into film, the mixture is characterized by a heat seal initiation temperature which is substantially lower than its Vicat softening point as well as a high ultimate hot tack strength. When fabricated as a molded article, the mixture is characterized by high microwave warp distortion while maintaining a lower modulus. The polymer mixture is particularly well-suited for use in multilayer film structures as a sealant layer for such applications as cook-in packages, hot-fill packages, and barrier shrink films. In molding applications, the mixture is well-suited as freezer-to-microwave food storage containers and lids which maintain good flexibility at low temperature to allow easy openability of such containers.
Inventors
- 👤 Jacquelyn A. deGroot
- 👤 Lonnie G. Hazlitt
- 👤 Pradeep Jain
- 👤 Seema V. Karande
- 👤 Laura K. Mergenhagen
- 👤 Dan G. Moldovan
- 👤 Kenneth B. Stewart
- 👤 Nicole F. Whiteman
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 20:18
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/04; B; B29; B29C; B29C48/00; B29C48/022; B29C48/03; B29C48/07; B29C48/08; B29C48/09; B29C48/10; B32; B32B; B32B27/00; B32B27/32; B32B27/322; C08J; C08J5/00; C08J5/18; C08L23/06; C08L23/08; C08L23/0807; C08L23/0815; C09; C09J; C09J123/00; C09J123/02; C09J123/04; C09J123/08; C09J123/0807; C09J123/0815; C08F; C08F110/00; C08F110/02; C08F210/00; C08F210/16; C08F2410/00; C08F2410/08; C08F2420/00; C08F2420/02; C08F4/00; C08F4/42; C08F4/44; C08F4/60; C08F4/62; C08F4/64; C08F4/659; C08F4/65908; C08F4/65912; C08J2323/00; C08J2323/02; C08J2323/04; C08J2323/08; C08L2205/00; C08L2205/02; C08L2314/00; C08L2314/06; C08L2666/00; C08L2666/02; C08L2666/04; C08L2666/06; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1334; Y10T428/1352; Y10T428/139; Y10T428/1393; Y10T428/1397; Y10T428/24; Y10T428/24942; Y10T428/24992; Y10T428/28; Y10T428/2813; Y10T428/2817; Y10T428/2826; Y10T428/31504; Y10T428/31855; Y10T428/31909; Y10T428/31913
Claims Analysis
Total Claims: 28
Claim 1
Independent Claim
439 words
A polymer mixture suitable for fabricating packaging films and coatings comprising (A) from 15 to 60 weight percent, based on the total weight of the mixture, of at least one first ethylene polymer which is a substantially linear ethylene-alpha olefin polymer having a density in the range of 0.850 to 0.920 g/cc, wherein the substantially linear ethylene polymer is further characterized as having i. a melt flow ratio, I 10 /I 2 ≧5.63, ii. a molecular weight distribution, M w /M n , as determined by gel permeation chromatography and defined by the equation: (M w /M n )≦(I 10 /I 2 )-4.63, iii. a gas extrusion rheology such that the critical shear rate at onset of surface melt fracture for the substantially linear ethylene polymer is at least 50 percent greater than the critical shear rate at the onset of surface melt fracture for a linear ethylene polymer, wherein the substantially linear ethylene polymer and the linear ethylene polymer comprise the same comonomer or comonomers, the linear ethylene polymer has an I 2 , M w /M n and density within ten percent of the substantially linear ethylene polymer and wherein the respective critical shear rates of the substantially linear ethylene polymer and the linear ethylene polymer are measured at the same melt temperature using a gas extrusion rheometer, and iv. a single differential scanning calorimetry, DSC, melting peak between -30° and 150° C.; and (B) from 40 to 85 weight percent, based on the total weight of the mixture, of at least one second ethylene polymer which is a homogeneously branched, heterogeneously branched linear, or non-short chain branched linear ethylene polymer having a density between 0.890 and 0.942 g/cc; wherein the polymer mixture is characterized as having a density of from 0.890 to 0.930 g/cc, and a differential between the densities of the first ethylene polymer and the second ethylene polymer of at least 0.015 g/cc with the proviso that where the density of the first ethylene polymer is less than 0.887 g/cc, the density of the second ethylene polymer is greater than 0.920 g/cc, a Vicat softening point of at least 75° C., a compositional hexane extractive of less than 10 percent based on the total weight of the mixture; and wherein (a) a 0.038 mm thick coextruded sealant layer fabricated from the polymer mixture has a heat seal initiation temperature equal to or less than 100° C. and an ultimate hot tack strength of at least 2.56 N/cm, and (b) the Vicat softening point of the polymer mixture is more than 6° C. higher than the heat seal initiation temperature of the coextruded sealant layer.
Claim 2
Dependent Claim
439 words
A polymer mixture suitable for fabricating packaging films and coatings comprising (A) from 15 to 60 weight percent, based on the total weight of the mixture, of at least one first ethylene polymer which is a substantially linear ethylene-alpha olefin polymer having a density in the range of 0.850 to 0.920 g/cc, wherein the substantially linear ethylene polymer is further characterized as having i. a melt flow ratio, I 10 /I 2 ≧5.63, ii. a molecular weight distribution, M w /M n , as determined by gel permeation chromatography and defined by the equation: (M w /M n )≦(I 10 /I 2 )-4.63, iii. a gas extrusion rheology such that the critical shear rate at onset of surface melt fracture for the substantially linear ethylene polymer is at least 50 percent greater than the critical shear rate at the onset of surface melt fracture for a linear ethylene polymer, wherein the substantially linear ethylene polymer and the linear ethylene polymer comprise the same comonomer or comonomers, the linear ethylene polymer has an I 2 , M w /M n and density within ten percent of the substantially linear ethylene polymer and wherein the respective critical shear rates of the substantially linear ethylene polymer and the linear ethylene polymer are measured at the same melt temperature using a gas extrusion rheometer, and iv. a single differential scanning calorimetry, DSC, melting peak between -30° and 150° C.; and (B) from 40 to 85 weight percent, based on the total weight of the mixture, of at least one second ethylene polymer which is a homogeneously branched, heterogeneously branched linear, or non-short chain branched linear ethylene polymer having a density between 0.890 and 0.942 g/cc; wherein the polymer mixture is characterized as having a density of from 0.890 to 0.930 g/cc, and a differential between the densities of the first ethylene polymer and the second ethylene polymer of at least 0.015 g/cc with the proviso that where the density of the first ethylene polymer is less than 0.887 g/cc, the density of the second ethylene polymer is greater than 0.920 g/cc, a Vicat softening point of at least 75° C., a compositional hexane extractive of less than 10 percent based on the total weight of the mixture; and wherein (a) a 0.038 mm thick coextruded sealant layer fabricated from the polymer mixture has a heat seal initiation temperature equal to or less than 100° C. and an ultimate hot tack strength of at least 2.56 N/cm, and (b) the Vicat softening point of the polymer mixture is more than 6° C. higher than the heat seal initiation temperature of the coextruded sealant layer.
Claim 3
Dependent Claim
20 words
The polymer mixture of claim 1, wherein the substantially linear ethylene polymer has at least 0.1 long chain branch/1000 carbons.
Claim 4
Dependent Claim
20 words
The polymer mixture of claim 1, wherein the substantially linear ethylene polymer has at least 0.3 long chain branch/1000 carbons.
Claim 5
Dependent Claim
28 words
The polymer mixture of any of claims 1, wherein the second ethylene polymer, Component (B), is a heterogeneously branched linear ethylene polymer or a substantially linear ethylene polymer.
Claim 6
Dependent Claim
51 words
The polymer mixture of any of claims 1, wherein at least one of the first ethylene polymer, Component (A), or the second ethylene polymer, Component (B), is an interpolymer of ethylene and at least one alpha-olefin selected from the group consisting of 1-propylene, 1-butene, 1-isobutylene, 1-hexene, 4-methyl-1-pentene, 1-pentene, 1-heptene and 1-octene.
Claim 7
Dependent Claim
33 words
The polymer mixture of any of claims 1, wherein at least one of the first ethylene polymer, Component (A), or the second ethylene polymer, Component (B), is a copolymer of ethylene and 1-octene.
Claim 8
Dependent Claim
60 words
The polymer mixture of any of claims 1, wherein the mixture is prepared by mixing the first ethylene polymer and the second ethylene polymer together by at least one of the methods selected from the group consisting of melt mixing extrusion, dry blending, sequential operation of at least two polymerization reactors and parallel operation of at least two polymerization reactors.
Claim 9
Dependent Claim
40 words
The polymer mixture of any of claims 1, wherein at least one of the first ethylene polymer of Component (A) and the second ethylene polymer of Component (B) is characterized by a melt index of 0.1 to 75 g/10 min.
Claim 10
Dependent Claim
27 words
The polymer mixture of claim 1, wherein the compositional hexane extractive level is of at least 40 percent lower than the expected extractive amount for the mixture.
Claim 11
Dependent Claim
27 words
The polymer mixture of claim 1, wherein the compositional hexane extractive level is of at least 50 percent lower than the expected extractive amount for the mixture.
Claim 12
Dependent Claim
31 words
The polymer mixture of any of claims 1, wherein the mixture has a compositional hexane extractive level of less than 15 weight percent based on the total weight of the mixture.
Claim 13
Dependent Claim
31 words
The polymer mixture of any of claims 1, wherein the mixture has a compositional hexane extractive level of less than 10 weight percent based on the total weight of the mixture.
Claim 14
Dependent Claim
31 words
The polymer mixture of any of claims 1, wherein the mixture has a compositional hexane extractive level of less than 6 weight percent based on the total weight of the mixture.
Claim 15
Dependent Claim
32 words
The polymer mixture of claim 1, wherein the Vicat softening point of the polymer mixture is at least 8° C. higher than the heat seal initiation temperature of the film sealant layer.
Claim 16
Dependent Claim
32 words
The polymer mixture of claim 1, wherein the Vicat softening point of the polymer mixture is at least 10° C. higher than the heat seal initiation temperature of the film sealant layer.
Claim 17
Dependent Claim
22 words
The polymer mixture of claim 1, wherein the heat seal initiation temperature of the film sealant layer is less than 90° C.
Claim 18
Dependent Claim
22 words
The polymer mixture of claim 1, wherein the heat seal initiation temperature of the film sealant layer is less than 85° C.
Claim 19
Dependent Claim
20 words
The polymer mixture of any of claims 1 in the form of a film, film layer, coating or molded article.
Claim 20
Dependent Claim
20 words
The polymer mixture of claim 18 in the form of a sealant layer or shrink layer in a packaging structure.
Claim 21
Dependent Claim
15 words
The polymer mixture of claim 19, wherein the packaging structure is a multilayer film structure.
Claim 22
Dependent Claim
17 words
The polymer mixture of claim 18 in the form of a layer in a multilayer film structure.
Claim 23
Dependent Claim
20 words
The polymer mixture of claim 21, wherein the multilayer film structure is at least partly fabricated by a coextrusion technique.
Claim 24
Dependent Claim
26 words
The polymer mixture of claim 21, wherein the multilayer film structure is a cook-in package, hot-fill package, flowable material pouch, shrink film or barrier shrink film.
Claim 25
Dependent Claim
18 words
The polymer mixture of claim 18, wherein the molded article is in the form of a storage container.
Claim 26
Dependent Claim
19 words
The polymer mixture of claim 24, wherein the molded article is in the form of a storage container lid.
Claim 27
Dependent Claim
35 words
The polymer mixture of claim 24, wherein the molded article is fabricated by at least one of the techniques from the group consisting of injection molding, blow molding, compression molding, rotomolding and injection blow molding.
Claim 28
Dependent Claim
18 words
The polymer mixture of claim 21, wherein the molded article is at least partly fabricated by injection molding.
References Cited (Backward Citations)
CA684471A
Cited
US33683A
Cited
US4076698B1
Cited
US4076698A
Cited
US3231636A
Cited
US3014702A
Cited
US2983704A
Cited
US3239197A
Cited
GB942363A
Cited
US3247290A
Cited
US4048428A
Cited
US3340328A
Cited
GB1065568A
Cited
US3555604A
Cited
US3456044A
Cited
US3491073A
Cited
US3371464A
Cited
US3645992A
Cited
US3914342A
Cited
US3998914A
Cited
US4011384A
Cited
US3974241A
Cited
US4205021A
Cited
US4314912A
Cited
US4542886A
Cited
US4390677A
Cited
US4243619A
Cited
US4302566A
Cited
US4194039A
Cited
US5084540A
Cited
US4303710A
Cited
US4259468A
Cited
US4188443A
Cited
US4399180A
Cited
US4438243A
Cited
US4229241A
Cited
US4328328A
Cited
US4303771A
Cited
US4320088A
Cited
US4383095A
Cited
US4588794A
Cited
US4230831A
Cited
US4363904A
Cited
US4359561A
Cited
US4330646A
Cited
US4463153A
Cited
US4467065A
Cited
US4339496A
Cited
US4340640A
Cited
US4340641A
Cited
US4339493A
Cited
US4482687A
Cited
US4330639A
Cited
US4390573A
Cited
US4629771A
Cited
US4424138A
Cited
US4348346A
Cited
US4429079A
Cited
US4380567A
Cited
US4786688A
Cited
US4346834A
Cited
US4339507A
Cited
US4405774A
Cited
US4438238A
Cited
US4387185A
Cited
US4359495A
Cited
US4352849A
Cited
US4597920A
Cited
US4367256A
Cited
US4365044A
Cited
US4352844A
Cited
US4391862A
Cited
US4624991A
Cited
US4354009A
Cited
US4349648A
Cited
US4378451A
Cited
US4359553A
Cited
US4427573A
Cited
US4474740A
Cited
US4465812A
Cited
US4464426A
Cited
US4513038A
Cited
US4370456A
Cited
US4379197A
Cited
US5025072A
Cited
US4486579A
Cited
US4452958A
Cited
US4532189A
Cited
US4519968A
Cited
US4427833A
Cited
US4803253A
Cited
US4410649A
Cited
US4418114A
Cited
US4510303A
Cited
US4461873A
Cited
US4547551A
Cited
US4421162A
Cited
US4563504A
Cited
US4626574A
Cited
US4668463A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2001-05-04 | 2001-11-03 | 2002-05-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2005-05-04 | 2005-11-03 | 2006-05-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2009-05-04 | 2009-11-03 | 2010-05-05 | $7700.00 | Window Closed / Lapsed |