US5707487A
Expired / Lapsed
US
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Method of manufacturing semiconductor device
Assignee: Toshiba Corp
•
Filing: 1994-10-31
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Granted: 1998-01-13
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Expires: 2014-10-31
Abstract
Abstract According to this invention, a method of manufacturing a semiconductor device includes the steps of forming a carbon film on a surface of a substrate, forming a mask pattern on the carbon film, etching the carbon film along the mask pattern to form a carbon film pattern, and reactive ion etching the substrate along the carbon film pattern using a high density plasma produced by application of a high frequency and a magnetic field, application of a microwave, irradiation of an electron beam, application of a high frequency of not less than 27 MHz, or application of a inductive coupled high frequency.
Inventors
- 👤 Masaru Hori
- 👤 Hiroyuki Yano
- 👤 Keiji Horioka
- 👤 Haruo Okano
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 21:54
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/09; G03F7/094; H; H10; H10P; H10P50/00; H10P50/69; H10P50/691; H10P50/692; H10P50/71; H10P50/73; H10P14/00; H10P14/60; H10P14/63; H10P14/6326; H10P14/6328; H10P14/6329; H10P14/6332; H10P14/6334; H10P14/69; H10P14/6902; Y; Y10; Y10S; Y10S438/00; Y10S438/942; Y10S438/948; Y10S438/95
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
181 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a carbon film on a layer, wherein said layer is on a substrate, and said layer comprises aluminum; forming a resist pattern on said carbon film; etching said carbon film along said resist pattern, with a gas comprising oxygen or an oxygen bearing compound, to form a carbon film pattern; and reactive ion etching said layer along said carbon film pattern, with a plasma of a gas comprising a member selected from the group consisting of chlorine, bromine, a chlorine bearing compound and a bromine bearing compound; wherein said plasma is produced by a member selected from the group consisting of (i) application of an alternating current and a magnetic field, (ii) application of microwaves, (iii) irradiation by an electron beam, (iv) application of a radio frequency of 27 MHz or more, and (v) application of an inductively coupled high frequency; and wherein said reactive ion etching is carried out under conditions such that there is a DC voltage across said plasma and said substrate of less than 200V.
Claim 2
Independent Claim
181 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a carbon film on a layer, wherein said layer is on a substrate, and said layer comprises aluminum; forming a resist pattern on said carbon film; etching said carbon film along said resist pattern, with a gas comprising oxygen or an oxygen bearing compound, to form a carbon film pattern; and reactive ion etching said layer along said carbon film pattern, with a plasma of a gas comprising a member selected from the group consisting of chlorine, bromine, a chlorine bearing compound and a bromine bearing compound; wherein said plasma is produced by a member selected from the group consisting of (i) application of an alternating current and a magnetic field, (ii) application of microwaves, (iii) irradiation by an electron beam, (iv) application of a radio frequency of 27 MHz or more, and (v) application of an inductively coupled high frequency; and wherein said reactive ion etching is carried out under conditions such that there is a DC voltage across said plasma and said substrate of less than 200V.
Claim 3
Dependent Claim
28 words
A method according to claim 1, wherein said carbon film is formed by a method selected from the group consisting of sputtering, vacuum evaporation and chemical vapor deposition.
Claim 4
Dependent Claim
23 words
A method according to claim 1, wherein a temperature of said substrate is controlled within a range of -100° C. to 50° C.
Claim 5
Dependent Claim
26 words
A method according to claim 1, wherein said reactive ion etching step is performed such that a gas comprising chlorine is used as an etching gas.
Claim 6
Dependent Claim
15 words
A method according to claim 1, wherein said DC voltage is not less than 30V.
Claim 7
Dependent Claim
27 words
A method according to claim 1, wherein the step of etching said carbon film is performed by reactive ion etching using oxygen gas as an etching gas.
Claim 8
Dependent Claim
25 words
A method according to claim 1, wherein said substrate comprises a SiO 2 film on silicon, and said layer is on said SiO 2 film.
Claim 9
Dependent Claim
16 words
A method according to claim 1, wherein said layer consists of aluminum or an aluminum alloy.
Claim 10
Dependent Claim
25 words
A method according to claim 1, further comprising the step of exposing said layer to a plasma comprising oxygen gas before forming said carbon film.
Claim 11
Dependent Claim
39 words
A method according to claim 1, wherein said plasma is produced by a member selected from the group consisting of: (ii) application of microwaves, (iii) irradiation by an electron beam, and (v) application of an inductively coupled high frequency.
Claim 12
Independent Claim
169 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a carbon film on a layer, wherein said layer is on a substrate, and said layer comprises silicon; forming a resist pattern on said carbon film; etching said carbon film along said resist pattern, with a gas comprising oxygen or an oxygen bearing compound, to form a carbon film pattern; and reactive ion etchings of said layer along said carbon film pattern, with a plasma of a gas comprising a halogen or a halogen bearing compound; wherein said plasma is produced by a member selected from the group consisting of: (i) application of an alternating current and a magnetic field, (ii) application of microwaves (iii) irradiation by an electron beam, (iv) application of a radio frequency of 27 MHz or more, and (v) application of an inductively coupled high frequency; wherein said reactive ion etching is carried out under conditions such that there is a DC voltage across said plasma and said substrate of less than 100V.
Claim 13
Independent Claim
169 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a carbon film on a layer, wherein said layer is on a substrate, and said layer comprises silicon; forming a resist pattern on said carbon film; etching said carbon film along said resist pattern, with a gas comprising oxygen or an oxygen bearing compound, to form a carbon film pattern; and reactive ion etchings of said layer along said carbon film pattern, with a plasma of a gas comprising a halogen or a halogen bearing compound; wherein said plasma is produced by a member selected from the group consisting of: (i) application of an alternating current and a magnetic field, (ii) application of microwaves (iii) irradiation by an electron beam, (iv) application of a radio frequency of 27 MHz or more, and (v) application of an inductively coupled high frequency; wherein said reactive ion etching is carried out under conditions such that there is a DC voltage across said plasma and said substrate of less than 100V.
Claim 14
Dependent Claim
28 words
A method according to claim 11, wherein said reactive ion etching step is performed such that a gas comprising chlorine or bromine is used as an etching gas.
Claim 15
Dependent Claim
15 words
A method according to claim 11, wherein said DC voltage is not less than 30V.
Claim 16
Dependent Claim
27 words
A method according to claim 11, wherein the step of etching said carbon film is performed by reactive ion etching using oxygen gas as an etching gas.
Claim 17
Dependent Claim
25 words
A method according to claim 11, wherein said substrate comprises a SiO 2 film on silicon, and said layer is on said SiO 2 film.
Claim 18
Dependent Claim
13 words
A method according to claim 11, wherein said layer consists essentially of polysilicon.
Claim 19
Dependent Claim
39 words
A method according to claim 11, wherein said plasma is produced by a member selected from the group consisting of: (ii) application of microwaves, (iii) irradiation by an electron beam, and (v) application of an inductively coupled high frequency.
Claim 20
Independent Claim
126 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a carbon film on a layer, wherein said layer is on a substrate, and said layer comprises aluminum; forming a resist pattern on said carbon film; etching said carbon film along said resist pattern, with a gas comprising oxygen or an oxygen bearing compound, to form a carbon film pattern; and reactive ion etching said layer along said carbon film pattern, with a plasma of a gas comprising a member selected from the group consisting of chlorine, bromine, a chlorine bearing compound and a bromine bearing compound; wherein said reactive ion etching is carried out under conditions such that there is a DC voltage across said plasma and said substrate of less than 200V.
Claim 21
Independent Claim
126 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a carbon film on a layer, wherein said layer is on a substrate, and said layer comprises aluminum; forming a resist pattern on said carbon film; etching said carbon film along said resist pattern, with a gas comprising oxygen or an oxygen bearing compound, to form a carbon film pattern; and reactive ion etching said layer along said carbon film pattern, with a plasma of a gas comprising a member selected from the group consisting of chlorine, bromine, a chlorine bearing compound and a bromine bearing compound; wherein said reactive ion etching is carried out under conditions such that there is a DC voltage across said plasma and said substrate of less than 200V.
Claim 22
Dependent Claim
25 words
A method according to claim 18, wherein said substrate comprises a SiO 2 film on silicon, and said layer is on said SiO 2 film.
Claim 23
Independent Claim
215 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a carbon film on a substrate; forming a resist pattern on said carbon film; etching said carbon film along said resist pattern, with a gas comprising oxygen or an oxygen bearing compound, to form a carbon film pattern; and reactive ion etching said substrate along said carbon film pattern, with a plasma of a gas comprising a member selected from the group consisting of chlorine, bromine, a chlorine bearing compound and a bromine bearing compound; wherein said plasma is produced by a member selected from the group consisting of (i) application of an alternating current and a magnetic field (ii) application of microwaves, (iii) irradiation by an electron beam, (iv) application of a radio frequency of 27 MHz or more, and (v) application of an inductively coupled high frequency; and wherein either: (a) a surface of said substrate comprises aluminum, and said reactive ion etching is carried out under conditions such that there is a DC voltage across said plasma and said substrate of less than 200V; or (b) a surface of said substrate comprises silicon, and said reactive ion etching is carried out under conditions such that there is a DC voltage across said plasma and said substrate of less than 100V.
Claim 24
Independent Claim
215 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a carbon film on a substrate; forming a resist pattern on said carbon film; etching said carbon film along said resist pattern, with a gas comprising oxygen or an oxygen bearing compound, to form a carbon film pattern; and reactive ion etching said substrate along said carbon film pattern, with a plasma of a gas comprising a member selected from the group consisting of chlorine, bromine, a chlorine bearing compound and a bromine bearing compound; wherein said plasma is produced by a member selected from the group consisting of (i) application of an alternating current and a magnetic field (ii) application of microwaves, (iii) irradiation by an electron beam, (iv) application of a radio frequency of 27 MHz or more, and (v) application of an inductively coupled high frequency; and wherein either: (a) a surface of said substrate comprises aluminum, and said reactive ion etching is carried out under conditions such that there is a DC voltage across said plasma and said substrate of less than 200V; or (b) a surface of said substrate comprises silicon, and said reactive ion etching is carried out under conditions such that there is a DC voltage across said plasma and said substrate of less than 100V.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2001-01-12 | 2001-07-14 | 2002-01-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2005-01-12 | 2005-07-14 | 2006-01-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2009-01-12 | 2009-07-14 | 2010-01-13 | $7700.00 | Window Closed / Lapsed |