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US5401675A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of depositing conductors in high aspect ratio apertures using a collimator

Assignee: Individual
•
Filing: 1993-03-24
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Granted: 1995-03-28
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Expires: 2013-03-24
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Abstract

Abstract A process for sputter deposition wherein high aspect ratio apertures are coated with conductive films exhibiting low bulk resistivity, low impurity concentrations, and regular morphologies. A collimator is used having an aspect ratio that approximates the aspect ratio of the apertures.

Inventors

  • 👤 Pei-Ing P. Lee
  • 👤 Thomas J. Licata
  • 👤 Thomas L. McDevitt
  • 👤 Paul C. Parries
  • 👤 Scott L. Pennington
  • 👤 James G. Ryan
  • 👤 David C. Strippe

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 15:24
CPC Classifications
H; H10; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/032; H10W20/033; C; C23; C23C; C23C14/00; C23C14/04; C23C14/042; C23C14/044; H10P; H10P14/00; H10P14/40; H10P14/42; H10P14/44; H10W20/056; H05; H05K; H05K3/00; H05K3/40; H05K3/4038; H05K3/4076

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 141 words
In a process for sputtering a barrier layer metallurgy comprising a refractory metal or refractory metal alloy from a sputter target into contact holes having side and bottom surfaces defined in an insulator arranged on a semiconductor substrate, at least some of the contact holes having an aspect ratio on the order of 2:1, the improvement comprising disposing a collimator between said sputter target and the substrate, said collimator being spaced from the substrate, said collimator having at least some openings with an aspect ratio of at least 1:1, and sputtering said refractory metal or refractory metal alloy at a pressure between approximately 0.7 mTorr and 3 mTorr, said refractory metal or refractory metal alloy being formed on said side and bottom surfaces of said contact holes and having a substantially uniform thickness at said side surfaces of said contact holes.
Claim 2
Dependent Claim 141 words
In a process for sputtering a barrier layer metallurgy comprising a refractory metal or refractory metal alloy from a sputter target into contact holes having side and bottom surfaces defined in an insulator arranged on a semiconductor substrate, at least some of the contact holes having an aspect ratio on the order of 2:1, the improvement comprising disposing a collimator between said sputter target and the substrate, said collimator being spaced from the substrate, said collimator having at least some openings with an aspect ratio of at least 1:1, and sputtering said refractory metal or refractory metal alloy at a pressure between approximately 0.7 mTorr and 3 mTorr, said refractory metal or refractory metal alloy being formed on said side and bottom surfaces of said contact holes and having a substantially uniform thickness at said side surfaces of said contact holes.
Claim 3
Dependent Claim 21 words
The process as recited in claim 1, wherein said refractory metal is sputtered at a pressure of less than 1.0 mTorr.
Claim 4
Dependent Claim 13 words
The process as recited in claim 2, wherein said refractory metal comprises titanium.
Claim 5
Dependent Claim 15 words
The process as recited in claim 2, wherein said refractory metal alloy comprises titanium nitride.
Claim 6
Dependent Claim 17 words
The process as recited in claim 4, wherein said deposition is carried out in an N2 ambient.
Claim 7
Dependent Claim 125 words
In a sputtering process for depositing a refractory metal or refractory metal alloy layer from a sputter target onto a substrate having at least some depressions therein with aspect ratios on the order of 2:1, each of said depressions having bottom and side surfaces, the improvement comprising disposing a collimator between the sputter target and the substrate, said collimator being spaced from the substrate, and sputtering said refractory metal or refractory metal alloy layer at a pressure between approximately 0.7 mTorr and 3 mTorr and at a substrate temperature of approximately 150° C., said refractory metal or refractory metal alloy layer being formed on said side and bottom surfaces of said depressions and having a substantially uniform thickness at said side surfaces of said depressions.
Claim 8
Dependent Claim 125 words
In a sputtering process for depositing a refractory metal or refractory metal alloy layer from a sputter target onto a substrate having at least some depressions therein with aspect ratios on the order of 2:1, each of said depressions having bottom and side surfaces, the improvement comprising disposing a collimator between the sputter target and the substrate, said collimator being spaced from the substrate, and sputtering said refractory metal or refractory metal alloy layer at a pressure between approximately 0.7 mTorr and 3 mTorr and at a substrate temperature of approximately 150° C., said refractory metal or refractory metal alloy layer being formed on said side and bottom surfaces of said depressions and having a substantially uniform thickness at said side surfaces of said depressions.
Claim 9
Dependent Claim 159 words
A process for forming a Ti/TiN barrier layer within a 2:1 aspect ratio aperture formed within a passivation layer arranged on a substrate, comprising the steps of: sputtering a layer of titanium onto the substrate through a collimator having 1:1 aspect ratio openings therein, said collimator being spaced from the substrate, said layer of titanium being sputtered at a pressure between 0.7 mTorr and 3 mTorr; sputtering a layer of titanium nitride onto said layer of titanium through said collimator, said second sputtering step being carried out in a working gas consisting essentially of N2 and a pressure between 0.7 mTorr and 3 mTorr, said layers of titanium and titanium nitfide being formed on said sides and bottom of said aperture, and having a substantially uniform thickness on said sides of said aperture; and annealing said layers of titanium and titanium nitride in an N 2 ambient to convert titanium on said sides of said aperture to titanium nitride.
Claim 10
Dependent Claim 159 words
A process for forming a Ti/TiN barrier layer within a 2:1 aspect ratio aperture formed within a passivation layer arranged on a substrate, comprising the steps of: sputtering a layer of titanium onto the substrate through a collimator having 1:1 aspect ratio openings therein, said collimator being spaced from the substrate, said layer of titanium being sputtered at a pressure between 0.7 mTorr and 3 mTorr; sputtering a layer of titanium nitride onto said layer of titanium through said collimator, said second sputtering step being carried out in a working gas consisting essentially of N2 and a pressure between 0.7 mTorr and 3 mTorr, said layers of titanium and titanium nitfide being formed on said sides and bottom of said aperture, and having a substantially uniform thickness on said sides of said aperture; and annealing said layers of titanium and titanium nitride in an N 2 ambient to convert titanium on said sides of said aperture to titanium nitride.
Claim 11
Dependent Claim 17 words
The process as recited in claim 7, wherein said pressure is not greater than approximately 1 mTorr.
Claim 12
Dependent Claim 132 words
A process for sputtering a layer of titanium nitride onto a substrate having at least one depression having side and bottom surfaces, said at least one depression having an aspect ratio on the order of 2:1, comprising the steps of forming said at least one depression on said substrate, and sputtering said layer of titanium nitfide onto the substrate through a collimator spaced from the substrate, said sputtering step being carded out at a pressure between approximately 0.7 mTorr and 3 mTorr, and in a working gas consisting essentially of N2, said layer of titanium nitride being deposited on said side and bottom surfaces of said at least one depression, said layer of titanium nitride being deposited at a substantially uniform thickness on said side surfaces of said at least one depression.
Claim 13
Dependent Claim 132 words
A process for sputtering a layer of titanium nitride onto a substrate having at least one depression having side and bottom surfaces, said at least one depression having an aspect ratio on the order of 2:1, comprising the steps of forming said at least one depression on said substrate, and sputtering said layer of titanium nitfide onto the substrate through a collimator spaced from the substrate, said sputtering step being carded out at a pressure between approximately 0.7 mTorr and 3 mTorr, and in a working gas consisting essentially of N2, said layer of titanium nitride being deposited on said side and bottom surfaces of said at least one depression, said layer of titanium nitride being deposited at a substantially uniform thickness on said side surfaces of said at least one depression.
Claim 14
Dependent Claim 17 words
The process as recited in claim 9, wherein said pressure is not greater than approximately 1 mTorr.
Claim 15
Dependent Claim 20 words
The process as recited in claim 10, wherein said substrate is heated to approximately 1500° C. during said sputtering step.
Claim 16
Dependent Claim 22 words
The process as recited in claim 6, wherein said sputtering process is carried out at a pressure of less than 1.0 mTorr.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-03-27 1998-09-26 1999-03-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-03-27 2002-09-26 2003-03-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-03-27 2006-09-26 2007-03-28 $7700.00 Window Closed / Lapsed

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