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Blends of glycolide and/or lactide polymers and caprolactone and/or trimethylene carbonate polymers and absorbable surgical devices made therefrom

Assignee: United States Surgical Corp
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Filing: 1993-04-12
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Granted: 1994-06-14
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Expires: 2013-04-12
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Abstract

Abstract Polymer blends of glycolide and/or lactide homopolymer and/or glycolide/lactide copolymer and polycaprolactone and/or polytrimethylene carbonate homopolymer or copolymers thereof and absorbable surgical devices manufactured therefrom having improved mechanical properties, such as improved impact resistance and improved cyclic flex, are disclosed.

Inventors

  • 👤 Donald S. Kaplan
  • 👤 Matthew Hermes
  • 👤 Ross R. Muth
  • 👤 John Kennedy

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 16:30
CPC Classifications
A; A61; A61L; A61L31/00; A61L31/14; A61L31/148; A61B; A61B17/00; A61B17/56; A61B17/58; A61B17/68; A61B17/80; A61L27/00; A61L27/40; A61L27/44; A61L27/48; A61L27/50; A61L27/58; A61L31/12; A61L31/125; A61L31/129; C; C08; C08L; C08L67/00; C08L67/04; A61B2017/00004; A61F; A61F2/00; A61F2/02; A61F2/30; A61F2/3094; A61F2/30965

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 44 words
A polymer composition useful in the production of improved absorbable surgical devices, the composition comprising a blend of: a) a copolymer of glycolide and lactide; and b) a copolymer of lactide and trimethylene carbonate having a trimethylene carbonate content of at least about 70%.
Claim 2
Dependent Claim 44 words
A polymer composition useful in the production of improved absorbable surgical devices, the composition comprising a blend of: a) a copolymer of glycolide and lactide; and b) a copolymer of lactide and trimethylene carbonate having a trimethylene carbonate content of at least about 70%.
Claim 3
Dependent Claim 19 words
A composition as in claim 1 wherein said copolymer of glycolide and lactide contains at least about 70% lactide.
Claim 4
Dependent Claim 22 words
A composition as in claim 1 wherein said copolymer of lactide and trimethylene carbonate has a trimethylene carbonate content of about 80%.
Claim 5
Dependent Claim 20 words
A composition as in claim 2 wherein said copolymer of glycolide and lactide has a lactide content of about 80%.
Claim 6
Dependent Claim 26 words
A composition as in claim 1 wherein said blend contains from about 70 to about 80 percent by weight of said copolymer of glycolide and lactide.
Claim 7
Dependent Claim 18 words
A composition as in claim 1 wherein said copolymer of lactide and trimethylene carbonate is a random copolymer.
Claim 8
Dependent Claim 13 words
A composition as in claim 1 wherein said blend is extrudable into fibers.
Claim 9
Dependent Claim 22 words
A composition as in claim 5 wherein said copolymer of lactide and trimethylene carbonate has a trimethylene carbonate content of about 80%.
Claim 10
Dependent Claim 20 words
A composition as in claim 8 wherein said copolymer of glycolide and lactide has a lactide content of about 80%.
Claim 11
Dependent Claim 36 words
The polymer composition of claim 1 wherein the glycolide/lactide copolymer has an inherent viscosity of from about 0.9 to about 2.0 dl/g measured at 30° C. at a concentration of 0.25 g/dl in chloroform or hexafluoroisopropanol.
Claim 12
Dependent Claim 41 words
A polymer composition as in claim 5 wherein said blend contains 25% by weight of said lactide trimethylene carbonate copolymer and 75% of said copolymer of glycolide and lactide, said copolymer of glycolide and lactide containing 82% lactide and 18% glycolide.
Claim 13
Dependent Claim 53 words
An absorbable surgical device derived from a polymer composition comprising a blend of: (a) a glycolide/lactide copolymer; and (b) from about 1 to about 30 weight percent, based on the total weight of the blend, of a copolymer of trimethylene carbonate and lactide having a trimethylene carbonate content of at least about 70%.
Claim 14
Dependent Claim 53 words
An absorbable surgical device derived from a polymer composition comprising a blend of: (a) a glycolide/lactide copolymer; and (b) from about 1 to about 30 weight percent, based on the total weight of the blend, of a copolymer of trimethylene carbonate and lactide having a trimethylene carbonate content of at least about 70%.
Claim 15
Dependent Claim 18 words
An absorbable surgical device as in claim 12 wherein said glycolide/lactide copolymer contains at least about 70% lactide.
Claim 16
Dependent Claim 25 words
An absorbable surgical device as in claim 12 wherein said blend contains from about 70 to abut 80 percent by weight of said glycolide/lactide copolymer.
Claim 17
Dependent Claim 24 words
An absorbable surgical device as in claim 14 wherein said copolymer of lactide and trimethylene carbonate has a trimethylene carbonate content of about 80%.
Claim 18
Dependent Claim 41 words
An absorbable surgical device as in claim 15 wherein said blend contains 25% by weight of said lactide/trimethylene carbonate copolymer and 75% of said copolymers of glycolide and lactide, said copolymer of glycolide and lactide containing 82% lactide and 18% glycolide.
Claim 19
Dependent Claim 23 words
The absorbable surgical device of claim 12 wherein said device is selected from the group consisting of a fastener, pin and bone screw.
Claim 20
Dependent Claim 16 words
An absorbable surgical device as in claim 12 wherein said surgical device is a bone pin.
Claim 21
Dependent Claim 21 words
An absorbable surgical device as in claim 12 wherein said surgical device comprises at least one fiber formed from said blend.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-06-13 1997-12-13 1998-06-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-06-13 2001-12-13 2002-06-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-06-13 2005-12-13 2006-06-14 $7700.00 Window Closed / Lapsed

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