US5143814A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Positive photoresist compositions with o-quinone diazide, novolak and propylene glycol alkyl ether acetate
Assignee: EMD Performance Materials Corp
•
Filing: 1991-10-08
•
Granted: 1992-09-01
•
Expires: 2011-10-08
Abstract
Abstract The invention provides a method for producing a positive working photosensitive element with increased photospeed which comprises coating a formulation containing at least one novolak or polyvinyl phenol resin, at least one o-quinone diazide and a propylene glycol alkyl ether acetate on a substrate, drying, exposing to imaging energy and developing.
Inventors
- 👤 Thomas R. Pampalone
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 06:36
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/022; G03F7/0226; G03F7/0048; G03F7/16; G03F7/168
Claims Analysis
Total Claims: 28
Claim 1
Independent Claim
70 words
A positive photoresist composition consisting essentially of, in admixture, from about 15% to about 99% by weight, based on the solid parts of said composition, of at least one novolak resin, about 1% to about 85% by weight, based on the solid parts of said composition, of at least one o-quinone diazide photosensitizer, and a sufficient amount of propylene glycol alkyl ether acetate to increase the photospeed of said composition.
Claim 2
Dependent Claim
70 words
A positive photoresist composition consisting essentially of, in admixture, from about 15% to about 99% by weight, based on the solid parts of said composition, of at least one novolak resin, about 1% to about 85% by weight, based on the solid parts of said composition, of at least one o-quinone diazide photosensitizer, and a sufficient amount of propylene glycol alkyl ether acetate to increase the photospeed of said composition.
Claim 3
Dependent Claim
16 words
The positive photoresist composition of claim 1 wherein said acetate is propylene glycol methyl ether acetate.
Claim 4
Dependent Claim
34 words
The positive photoresist composition of claim 2 wherein said o-quinone diazide photosensitizer is present in an amount of from about 10% to about 50% by weight, based on the solid parts of said composition.
Claim 5
Dependent Claim
33 words
The positive photoresist composition of claim 3 wherein said novolak resin is present in an amount of from about 50% to about 90% by weight, based on the solid parts of said composition.
Claim 6
Dependent Claim
61 words
The positive photoresist composition of claim 4 wherein said novolak resin is present in an amount of from about 65% to about 85% by weight, based on the solid parts of said composition, and wherein said o-quinone diazide photosensitizer is present in an amount of from about 15% to about 35% by weight, based on the solid parts of said composition.
Claim 7
Dependent Claim
29 words
The positive photoresist composition of claim 1 further comprising one or more additives selected from the group consisting of colorants, anti-striation agents, plasticizers, adhesion promoters, speed enhancers, and surfactants.
Claim 8
Dependent Claim
23 words
The positive photoresist composition of claim 1 wherein the amount of propylene glycol alkyl ether acetate present does not substantially effect development contrast.
Claim 9
Dependent Claim
16 words
The positive photoresist composition of claim 7 wherein said acetate is propylene glycol methyl ether acetate.
Claim 10
Dependent Claim
21 words
A photosensitive element which consists essentially of a substrate and the positive photoresist composition of claim 1 disposed on said substrate.
Claim 11
Dependent Claim
37 words
The element of claim 9 wherein said substrate comprises one or more components selected from the group consisting of silicon, aluminum, polymeric resins, silicon dioxide, doped silicon dioxide, silicon nitride, tantalum, copper, polysilicon, ceramics and aluminum/copper mixtures.
Claim 12
Dependent Claim
78 words
A photosensitive solution suitable for application to a substrate to form a positive photoresist, which consists essentially of at least one novolak resin, at least one o-quinone diazide photosensitizer in an amount sufficient to act as a dissolution rate inhibitor with respect to said resin, and a propylene glycol alkyl ether acetate in an amount sufficient to act as a solvent for said resin and photosensitizer and to facilitate application of said resin and photosensitizer to said substrate.
Claim 13
Dependent Claim
78 words
A photosensitive solution suitable for application to a substrate to form a positive photoresist, which consists essentially of at least one novolak resin, at least one o-quinone diazide photosensitizer in an amount sufficient to act as a dissolution rate inhibitor with respect to said resin, and a propylene glycol alkyl ether acetate in an amount sufficient to act as a solvent for said resin and photosensitizer and to facilitate application of said resin and photosensitizer to said substrate.
Claim 14
Dependent Claim
14 words
The solution of claim 11 wherein said acetate is propylene glycol methyl ether acetate.
Claim 15
Dependent Claim
87 words
A photosensitive solution suitable for application to a substrate to form a positive photoresist consisting essentially of, in admixture, from about 15% to about 99% by weight, based on the solid parts of said solution, of at least one novolak resin, about 1% to about 85% by weight, based on the solid parts of said solution, of at least one o-quinone diazide photosensitizer, and from about 40% to about 90% by weight, based on the overall weight of the solution, of a propylene glycol alkyl ether acetate.
Claim 16
Dependent Claim
87 words
A photosensitive solution suitable for application to a substrate to form a positive photoresist consisting essentially of, in admixture, from about 15% to about 99% by weight, based on the solid parts of said solution, of at least one novolak resin, about 1% to about 85% by weight, based on the solid parts of said solution, of at least one o-quinone diazide photosensitizer, and from about 40% to about 90% by weight, based on the overall weight of the solution, of a propylene glycol alkyl ether acetate.
Claim 17
Dependent Claim
14 words
The solution of claim 13 wherein said acetate is propylene glycol methyl ether acetate.
Claim 18
Dependent Claim
32 words
The solution of claim 14 wherein said o-quinone diazide photosensitizer is present in an amount of from about 10% to about 50% by weight, based on the solid parts of said solution.
Claim 19
Dependent Claim
31 words
The solution of claim 15 wherein said novolak resin is present in an amount of from about 50% to about 90% by weight, based on the solid parts of said solution.
Claim 20
Dependent Claim
59 words
The solution of claim 16 wherein said novolak resin is present in an amount of from about 65% to about 85% by weight, based on the solid parts of said solution, and wherein said o-quinone diazide photosensitizer is present in an amount of from about 15% to about 35% by weight, based on the solid parts of said solution.
Claim 21
Dependent Claim
30 words
The solution of claim 15 wherein said acetate is present in an amount of from about 65% to about 70% by weight, based on the overall weight of the solution.
Claim 22
Dependent Claim
30 words
The solution of claim 13 wherein said acetate is present in an amount of from about 60% to about 83% by weight, based on the overall weight of the solution.
Claim 23
Dependent Claim
27 words
The solution of claim 13 further comprising one or more additives selected from the group consisting of colorants, anti-striation agents, plasticizers, adhesion promoters, speed enhancers, and surfactants.
Claim 24
Dependent Claim
10 words
A substrate coated with the photosensitive solution of claim 13.
Claim 25
Dependent Claim
38 words
The coated substrate of claim 21 wherein said substrate comprises one or more components selected from the group consisting of silicon, aluminum, polymeric resins, silicon dioxide, doped silicon dioxide, silicon nitride, tantalum, copper, polysilicon, ceramics and aluminum/copper mixtures.
Claim 26
Dependent Claim
60 words
A photosensitive positive working composition suitable for use as a photoresist, which consists essentially of, in admixture, at least one novolak resin, at least one o-quinone diazide photosensitizer and a solvent which consists essentially of a sufficient amount of a propylene glycol alkyl ether acetate to increase the effective photospeed of the composition without a substantial effect on development contrast.
Claim 27
Dependent Claim
60 words
A photosensitive positive working composition suitable for use as a photoresist, which consists essentially of, in admixture, at least one novolak resin, at least one o-quinone diazide photosensitizer and a solvent which consists essentially of a sufficient amount of a propylene glycol alkyl ether acetate to increase the effective photospeed of the composition without a substantial effect on development contrast.
Claim 28
Dependent Claim
18 words
The photosensitive positive working composition of claim 23 wherein said acetate component is propylene glycol methyl ether acetate.
References Cited (Backward Citations)
US3228768A
Cited
US3933517A
Cited
US3666473A
Cited
US3785825A
Cited
US3868254A
Cited
US3859099A
Cited
US4267260A
Cited
US4411983A
Cited
US4266001A
Cited
US4308368A
Cited
EP0021719A2
Cited
US4416976A
Cited
US4510227A
Cited
US4378423A
Cited
US4381340A
Cited
US4460674A
Cited
US4355094A
Cited
US4447510A
Cited
US4377631A
Cited
US4409317A
Cited
US4351895A
Cited
US4397937A
Cited
US4439516A
Cited
US4496647A
Cited
US4535059A
Cited
EP0114126A2
Cited
US4482661A
Cited
US4464461A
Cited
JPS60145616A
Cited
EP0164248A2
Cited
US4764450A
Cited
US4550069A
Cited
US4596763A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-09-01 | 1996-03-02 | 1996-09-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-09-01 | 2000-03-02 | 2000-09-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-09-01 | 2004-03-02 | 2004-09-01 | $7700.00 | Window Closed / Lapsed |