Thermoplastic resin composition

Claim 2

A thermoplastic resin composition which comprises (I) 100 parts by weight of a resin comprising 5-95% by weight of a polyphenylene ether resin, a mixture of a polyphenylene ether resin and a styrene resin or a graft polymer of a polyphenylene ether resin and styrene and 95-5% by weight of polyamide resin, (II) 0-50 parts by weight of a rubber-like material, (III) 2.0-50 parts by weight of an inorganic filler having an average particle size of 5.0 μ or less and (IV) 0.01-10 parts by weight of at least one compatibilizing agent which improves compatibility between the polyphenylene ether resin and the polyamide resin.

Claim 3

A thermoplastic resin composition according to claim 1, wherein the inorganic filler (III) has an average particle size of 5.0 μ or less and an aspect ratio of 5 or higher.

Claim 4

A thermoplastic resin composition according to claim 2, wherein the inorganic filler (III) is talc.

Claim 5

A thermoplastic resin composition according to claim 1, wherein the compatibilizing agent is at least one compound selected from the group consisting of the following (A)-(G): (A) Compounds having in their molecule both (a) carbon-carbon double bond or carbon-carbon triple bond and (b) carboxyl group, acid anhydride group, amino group, acid amide group, imido group, epoxy group, carboxylate group, isocyanate group, methylol group or hydroxyl group; (B) Aliphatic polycarboxylic acids represented by the formula: (R I O) m R(COOR II ) n (CONR III R IV ) s [wherein R is a straight chain or branched chain saturated aliphatic hydrocarbon group of 2-20 carbon atoms: R I is a hydrogen atom, or an alkyl, aryl, acyl or carbonyldioxy group which has 1-10 carbon atoms; each R II is independently a hydrogen atom or an alkyl or aryl group which has 1-20 carbon atoms; R III and R IV are independently a hydrogen atom or an alkyl or aryl group which has 1-10 carbon atoms; m=1, (n+s)≧2, n≧0 and s≧0; and (OR I ) is on α or β position relative to carbonyl group and at least two carbonyl groups are separated by 2-6 carbon atoms] or derivatives thereof or reaction products thereof; (C) Functional polyphenylene ethers comprising reaction products of (a) polyphenylene ether and (b) a compound of the formula: (i)--Z--(ii) [wherein (i) is a group of the formula: [X--C(O)-- (wherein X is F, Cl, Br, I, OH, --OR or --O--C(O)--R where R is H, an alkyl group or an aryl group), (ii) is a carboxylic acid group, an acid anhydride group, an acid amide group, an imido group, a carboxylate group, an amino group or a hydroxyl group, (i) and (ii) are covalently bonded through a bridge Z, and Z is a divalent hydrocarbon group]; (D) Organo silane compounds having in molecular structure both (a) at least one silicon bonded to carbon through an oxygen link and (b) at least one ethylenic carbon-carbon double bond or carbon-carbon triple bond and/or functional group selected from the group consisting of an amino group and a mercapto group, in which the functional group is not bonded directly to the silicon atom; (E) Oxidized polyolefin waxes; (F) Copolymers having unit of vinyl-aromatic compound and unit of α,β-unsaturated dicarboxylic acid or dicarboxylic anhydride or copolymers having unit of vinyl aromatic compound and unit of α,β-unsaturated dicarboxylic imido compound; and (G) At least one compound selected from the group consisting of a reaction product of (a) a 1,2-substituted olefin compound having a carboxyl group or an acid anhydride group, (b) polyphenylene ether and (c) a free-radical initiator and a reaction product of (a) and (b) in the absence of (c).

Claim 6

A thermoplastic resin composition according to claim 1, wherein the polyphenylene ether resin (I) is poly(2,6-dimethyl-1,4-phenylene) ether.

Claim 7

A thermoplastic resin composition according to claim 1, wherein the styrene resin (I) is homopolystyrene or rubber reinforced polystyrene.

Claim 8

A thermoplastic resin composition according to claim 1, wherein the polyamide resin (I) is polyhexamethylene adipamide.

Claim 9

A thermoplastic resin composition according to claim 1, wherein the polyamide resin (I) is polyhexamethylene adipamide.

Claim 10

A thermoplastic resin composition according to claim 1, wherein the polyamide resin (I) is at least one polyamide resin selected from the group consisting of aliphatic polyamides, thermoplastic aromatic copolyamides and aromatic nuclear-hydrogenated copolyamides.

Claim 11

A thermoplastic resin according to claim 1, wherein the rubber-like material (II) is at least one material selected from the group consisting of ethylene-propylene rubber, ethylene-propylene-non-conjugated diene rubber, styrene-butadiene block copolymer, hydrogenated styrene-butadiene block copolymer, styrene-isoprene block copolymer, hydrogenated styrene-isoprene block copolymer, styrene grafted ethylene-propylene rubber, styrene grafted ethylene-propylene-non-conjugated diene rubber, and carboxyl group modified product and glycidyl group modified product thereof.

Claim 12

A thermoplastic resin composition according to claim 4, wherein the compatibilizing agent (IV) is maleic anhydride, maleic acid, fumaric acid, itaconic acid, himic anhydride, glycidyl acrylate or glycidyl methacrylate.

Claim 13

A thermoplastic resin composition according to claim 1, wherein the inorganic filler (III) is talc which has an average particle size of 5.0 μ or less and shows weight loss on heating of 0.2% by weight or less when heated at 300° C. for 2 hours.

Claim 14

A thermoplastic resin composition according to claim 1, wherein the polyamide resin (I) is a polyamide having a relative viscosity of less than 2.5.

Claim 15

A thermoplastic resin composition which comprises (I) 100 parts by weight of a resin comprising 5-95% by weight of a polyphenylene ether resin, a mixture of a polyphenylene ether resin and a styrene resin or a graft polymer of a polyphenylene ether resin and styrene and 95-5% by weight of polyamide resin, (II) 0-50 parts by weight of a rubber-like material, (III) 2.0-50 parts by weight of an inorganic filler having an average particle size of 5.0 μ or less and glass fiber and (IV) 0.01-10 parts by weight of at least on compatibilizing agent which improves compatibility between the polyphenylene ether resin and the polyamide resin.

Claim 16

A thermoplastic resin composition which comprises (I) 100 parts by weight of a resin comprising 5-95% by weight of a polyphenylene ether resin, a mixture of a polyphenylene ether resin and a styrene resin or a graft polymer of a polyphenylene ether resin and styrene and 95-5% by weight of polyamide resin, (II) 0-50 parts by weight of a rubber-like material, (III) 2.0-50 parts by weight of an inorganic filler having an average particle size of 5.0 μ or less and glass fiber and (IV) 0.01-10 parts by weight of at least on compatibilizing agent which improves compatibility between the polyphenylene ether resin and the polyamide resin.

Claim 17

A thermoplastic resin composition according to claim 14, wherein the inorganic filler (III) has an average particle size of 5.0 μ or less and an aspect ratio of 5 or higher.

Claim 18

A thermosplastic resin composition according to claim 14, wherein the inorganic filler (III) is talc.

Claim 19

A thermoplastic resin composition according to claim 14, wherein the compatibilizing agent is at least one compound selected from the group consisting of the following (A)-(G): (A) Compounds having in their molecule both (a) carbon-carbon double bond or carbon-carbon triple bond and (b) carboxyl group, acid anhydride group, amino group, acid amide group, imido group, epoxy group, carboxylate group, isocyanate group, methylol group or hydroxyl group; (B) Aliphatic polycarboxylic acids represented by the formula: (R I O) m R(COOR II ) n (CONR III R IV ) s , wherein R is a straight chain or branched chain saturated aliphatic hydrocarbon group of 2-20 carbon atoms; R I is a hydrogen atom, or an alkyl, aryl, acyl or carbonyldioxy group which has 1-10 carbon atoms; each R II is independently a hydrogen atom or an alkyl or aryl group which has 1-20 carbon atoms; R III and R IV are independently a hydrogen atom or an alkyl or aryl group which has 1-10 carbon atoms; m=1, (n+s)≧2, n≧0 and s≧0; and (OR I ) is on α or β position relative to carbonyl group and at least two carbonyl groups are separated by 2-6 carbon atoms or derivatives thereof or reaction products thereof; (C) Functionalized polyphenylene ethers comprising reaction products of (a) polyphenylene ether and (b) a compound of the formula: (i)--Z--(ii), wherein (i) is a group of the formula: X--C(O)--, wherein X is F, Cl, Br, I, OH, --OR or --O--C(O)--R where R is H, an alkyl group or an aryl group), (ii) is a carboxylic acid group, an acid anhydride group, an acid amide group, an imido group a carboxylate group, an amino group or a hydroxyl group, (i) and (ii) are covalently bonded through a bridge Z, and Z is a divalent hydrocarbon group; (D) Organo silane compounds having in molecular structure both (a) at least one silicon bonded to carbon through an oxygen link and (b) at least one ethylenic carbon-carbon double bond or carbon-carbon triple bond and/or functional group selected from the group consisting of an amino group and a mercapto group, in which the functional group is not bonded directly to the silicon atom; (E) Oxidized polyolefin waxes; (F) Copolymers having unit of vinyl-aromatic compound and unit of α,β-unsaturated dicarboxylic acid or dicarboxylic anhydride or copolymers having unit of vinyl aromatic compound and unit of α,β-unsaturated dicarboxylic imido compound; and (G) At least one compound selected from the group consisting of a reaction product of (a) a 1,2-substituted olefin compound having a carboxyl group or an acid anhydride group, (b) polyphenylene ether and (c) a free-radical initiator and a reaction product of (a) and (b) in the absence of (c).

Claim 20

A thermoplastic resin composition according to claim 14, wherein the polyphenylene ether resin (I) is poly(2,6-dimethyl-1,4-phenylene) ether.

Claim 21

A thermoplastic resin composition according to claim 14, wherein the styrene resin (I) is homopolystyrene or rubber reinforced polystyrene.

Claim 22

A thermoplastic resin composition according to claim 14, wherein the polyamide resin (I) is polycaprolactam.

Claim 23

A thermoplastic resin composition according to claim 14, wherein the polyamide resin (I) is polyhexamethylene adipamide.

Claim 24

A thermoplastic resin composition according to claim 14, wherein the polyamide resin (I) is at least one polyamide resin selected from the group consisting of aliphatic polyamides, thermoplastic aromatic copolyamides and aromatic nuclear-hydrogenated copolyamides.

Claim 25

A thermoplastic resin according to claim 14, wherein the rubber-like material (II) is at least one material selected from the group consisting of ethylene-propylene rubber, ethylene-propylene-non-conjugated diene rubber, styrene-butadiene block copolymer, hydrogenated styrene-butadiene block copolymer, styrene-isoprene block copolymer, hydrogenated styrene-isoprene block copolymer, styrene grafted ethylene-propylene rubber, styrene grafted ethylene-propylene-non-conjugated diene rubber, and carboxyl group modified product and glycidyl group modified product thereof.

Claim 26

A thermoplastic resin composition according to claim 14, wherein the compatibilizing agent (IV) is maleic anhydride, maleic acid, fumaric acid, itaconic acid, himic anhydride, glycidyl acrylate or glycidyl methacrylate.

Claim 27

A thermoplastic resin composition according to claim 14, wherein the ratio of the inorganic filler and the glass fiber (III) is 20-80% by weight of the former and 80-20% by weight of the latter.

Claim 28

A thermoplastic resin composition according to claim 14, wherein the inorganic filler (III) is talc which has an average particle size of 5.0 μ or less and shows weight loss on heating of 0.2% by weight or less when heated at 300° C. or 2 hours.

Claim 29

A thermoplastic resin composition according to claim 14, wherein the polyamide resin (I) is a polyamide having a relative viscosity of less than 2.5.