Polyphenylene ether-polyamide composition

Claim 2

A thermoplastic composition comprising: (A) about 20% by weight to about 80% by weight of polyphenylene ether; (B) about 80% by weight to about 20% by weight of a polyamide; (C) about 0.05% to about 4% by weight, based on the weight of the entire composition, of a compatibilizing compound for components (A) and (B); and (D) about 0.05% to about 2% by weight, based on the weight of the entire composition, of an additive combination which itself comprises (i) at least one metal stearate, and (ii) at least one amide selected from the group consisting of primary amides, secondary amides, and alkylenebisamides.

Claim 3

The composition of claim 1 wherein the polyphenylene ether comprises a plurality of structural units having the formula ##STR2## and in each of said units independently, each Q 1 is independently halogen, primary or secondary lower alkyl, phenyl, haloalkyl, aminoalkyl, hydrocarbonoxy, or halohydrocarbonoxy wherein at least two carbon atoms separate the halogen and oxygen atoms; and each Q 2 is independently hydrogen, halogen, primary or secondary lower alkyl, phenyl, haloalkyl, hydrocarbonoxy or halohydrocarbonoxy as defined for Q 1 .

Claim 4

The composition of claim 2 wherein the polyphenylene ether is poly(2,6-dimethyl-1,4-phenylene ether).

Claim 5

The composition of claim 2 wherein the polyamide is selected from the group consisting of polyamide 6; polyamide 6,6; polyamide 12; and polyamide 6/10.

Claim 6

The composition of claim 2 wherein the weight ratio of polyphenylene ether to polyamide is in the range of about 40:60 to about 60:40.

Claim 7

The composition of claim 1 wherein compatibilizing compound (C) is selected from the group consisting of (a) compounds which contain both (i) an ethylenic carbon-carbon double bond or a carbon-carbon triple bond and (ii) a carboxylic acid, acid anhydride, acid amide, imido, carboxylic ester, amino, or hydroxyl group; (b) liquid diene polymers; (c) epoxy compounds; (d) polycarboxylic acids or derivatives thereof; (e) an oxidized polyolefin wax; (f) a compound containing an acyl functional group; (g) a polyphenylene ether modified with a compound containing an acyl functional group; and (h) a chloroepoxytriazine compound

Claim 8

The composition of claim 6 wherein the compatibilizing agent is selected from the group consisting of maleic anhydride, maleic acid, fumaric acid, maleimide, and maleic hydrazide.

Claim 9

The composition of claim 6 wherein the compatibilizing agent is trimellitic anhydride acid chloride or polyphenylene ether modified with trimellitic anhydride acid chloride.

Claim 10

The composition of claim 6, wherein the polycarboxylic acid or derivative thereof is selected from the group consisting of citric acid, malic acid, and salts and hydrates thereof.

Claim 11

The composition of claim 1, further comprising a styrene resin selected from the group consisting of styrene homopolymers, styrene copolymers, rubber-modified polystyrene, and blends thereof.

Claim 12

The composition of claim 10 wherein the styrene resin is present in the composition at a level of about 1%-30% by weight, based on the weight of the entire composition.

Claim 13

The composition of claim 1, further comprising an elastomeric block copolymer.

Claim 14

The composition of claim 12, wherein the elastomeric block copolymer is a diblock or triblock copolymer of styrene and at least one olefin or conjugated diene, any conjugated diene block being non-hydrogenated or partially or entirely hydrogenated.

Claim 15

The composition of claim 13, wherein the block copolymer is present in the composition at a level of about 5%-20% by weight, based on the weight of the entire composition.

Claim 16

The composition of claim 14 wherein the block copolymer is a styrene-butadiene diblock or styrene-butadiene-styrene triblock copolymer.

Claim 17

The composition of claim 1, further comprising about 1% by weight to about 40% by weight glass fibers, based on the weight of the entire composition.

Claim 18

The composition of claim 1, further comprising effective amounts of a stabilizer which inhibits oxidation or thermal degradation of the composition.

Claim 19

The composition of claim 17 wherein the stabilizer is a hindered polyphenol.

Claim 20

The composition of claim 1 wherein the metal stearate is selected from the group consisting of zinc stearate, calcium stearate, aluminum stearate, cerium stearate, and magnesium stearate.

Claim 21

The composition of claim 1 wherein the amide is selected from the group consisting of stearamide, behenamide, oleamide, erucamide, stearyl erucamide, erucyl erucamide, oleyl palmitamide, stearyl stearamide, erucyl stearamide, N,N'-ethylenebisstearamide, and N,N'-ethylenebisoleamide.

Claim 22

The composition of claim 1 wherein the amide of component D(ii) is stearyl erucamide.

Claim 23

The composition of claim 21 wherein the metal stearate is zinc stearate.

Claim 24

The composition of claim 1 wherein the weight ratio of metal stearate to amide ranges from about 80:20 to about 60:40.

Claim 25

A thermoplastic composition comprising: (a) about 20%-50% polyphenylene ether resin; (b) about 20%-50% polyamide resin; (c) about 5%-20% elastomeric block copolymer; (d) about 0.1%-1.5% aliphatic polycarboxylic acid; (e) about 1%-20% styrene resin; and (f) about 0.05%-2.0% of an additive combination which consists essentially of at least one metal stearate and at least one amide selected from the group consisting of primary amides, secondary amides, and alkylenebisamides, each component in the composition measured in terms of percent-by-weight, based on the weight of the entire composition.

Claim 26

A thermoplastic composition comprising: (a) about 20%-50% polyphenylene ether resin; (b) about 20%-50% polyamide resin; (c) about 5%-20% elastomeric block copolymer; (d) about 0.1%-1.5% aliphatic polycarboxylic acid; (e) about 1%-20% styrene resin; and (f) about 0.05%-2.0% of an additive combination which consists essentially of at least one metal stearate and at least one amide selected from the group consisting of primary amides, secondary amides, and alkylenebisamides, each component in the composition measured in terms of percent-by-weight, based on the weight of the entire composition.

Claim 27

An improved method for extruding polyphenylene ether-polyamide compositions, comprising: (a) admixing, in a molten state, at least one polyphenylene ether resin with at least one compatibilizing compound for polyphenylene ethers and polyamides; and (b) adding to the extruder at least one polyamide resin along with an additive combination which itself comprises (i) at least one metal stearate, and (ii) at least one amide selected from the group consisting of primary amides, secondary amides, and alkylenebisamides; said composition while in the extruder being subjected to a temperature in the range of about 250 degrees Centigrade to about 350 degrees Centigrade for a time period of about 10 seconds to about 30 seconds.

Claim 28

An improved method for extruding polyphenylene ether-polyamide compositions, comprising: (a) admixing, in a molten state, at least one polyphenylene ether resin with at least one compatibilizing compound for polyphenylene ethers and polyamides; and (b) adding to the extruder at least one polyamide resin along with an additive combination which itself comprises (i) at least one metal stearate, and (ii) at least one amide selected from the group consisting of primary amides, secondary amides, and alkylenebisamides; said composition while in the extruder being subjected to a temperature in the range of about 250 degrees Centigrade to about 350 degrees Centigrade for a time period of about 10 seconds to about 30 seconds.