US4874810A
Expired / Lapsed
US
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Impact modified polyphenylene ether-polyamide compositions
Assignee: General Electric Co
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Filing: 1987-03-06
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Granted: 1989-10-17
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Expires: 2007-03-06
Abstract
Abstract Reinforced thermoplastic compositions comprised of compatible combinations of a polyphenylene ether resin, polyamide resin, and glass fibers can be impact modified with a modifying agent comprising a partially hydrogenated diblock copolymer of styrene and ethylene/propylene which result in molding compositions having improved thermal aging characteristics.
Inventors
- 👤 Gim F. Lee, Jr.
- 👤 Jean M. Heuschen
- 👤 Roelof van der Meer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 10:20
CPC Classifications
C; C08; C08L; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L77/00; Y; Y10; Y10S; Y10S525/00; Y10S525/905
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
83 words
A thermoplastic composition comprising: A. 100 parts by weight of a base resin comprising a compatibilized polyphenylene ether resin and polyamide resin, B. 1 to 30 parts by weight per 100 parts of base resin A. of a selectively hydrogenated diblock copolymer of the A-B type wherein block A is an alkenyl aromatic polymer and block B is an ethylene-propylene polymer, and C. 5 to 45 weight percent of glass fibers based upon the weight of components A., B., and C. taken together.
Claim 2
Dependent Claim
83 words
A thermoplastic composition comprising: A. 100 parts by weight of a base resin comprising a compatibilized polyphenylene ether resin and polyamide resin, B. 1 to 30 parts by weight per 100 parts of base resin A. of a selectively hydrogenated diblock copolymer of the A-B type wherein block A is an alkenyl aromatic polymer and block B is an ethylene-propylene polymer, and C. 5 to 45 weight percent of glass fibers based upon the weight of components A., B., and C. taken together.
Claim 3
Dependent Claim
42 words
A composition as in claim 1 wherein said compatible base resin A. is comprised of (a.) 5 to 95 weight percent polyphenylene ether resin and (b.) 95 to 5 weight percent polyamide resin, based upon the weight of a. and b. together.
Claim 4
Dependent Claim
27 words
A composition as in claim 2 wherein said polyamide resin constitutes a continuous phase in an amount greater than, approximately, 35 weight percent of the resinous components.
Claim 5
Dependent Claim
37 words
A composition as in claim 1 further comprising a compatibilizing agent selected from the group consisting of: maleic anhydride, fumaric acid, citric acid, malic acid, and reaction products of a polyphenylene ether and trimellitic anhydride acid chloride.
Claim 6
Dependent Claim
59 words
A composition as in claim 1 wherein said polyphenylene ether resin is a polymer or copolymer comprised primarily of one or more units derived from units selected from the group consisting of 2,6-dimethyl phenol units and 2,3,6-trimethyl phenol units, and wherein said resin has an intrinsic viscosity of 0.25 to 0.6 dl/g as measured in chloroform at 25° C.
Claim 7
Dependent Claim
13 words
A composition as in claim 5 wherein said polyphenylene ether is poly(2,6-dimethyl-1,4-phenylene ether).
Claim 8
Dependent Claim
22 words
A composition as in claim 1 wherein said polyamide resin is selected from the group consisting of polyamide 6, and polyamide 6,6.
Claim 9
Dependent Claim
37 words
A composition as in claim 1 wherein said diblock copolymer is comprised of, approximately, 20 to 40 weight percent styrene and 80 to 60 weight percent ethylene-propylene polymer based upon the weight of both blocks taken together.
Claim 10
Dependent Claim
33 words
A composition as in claim 1 wherein said diblock copolymer is present in an amount of, approximately, 5 to 25 parts by weight based upon the total weight of polyphenylene ether and polyamide.
Claim 11
Dependent Claim
34 words
A composition as in claim 1 wherein the glass fibers are present in an amount of, approximately, 10 to 30 weight percent based upon the weight of components A., B., and C. taken together
Claim 12
Dependent Claim
22 words
A composition as in claim 1 wherein the selectively hydrogenated diblock copolymer is a selectively hydrogenated diblock copolymer of styrene and isoprene.
Claim 13
Dependent Claim
61 words
A thermoplastic composition comprising: (a) a base resin comprising a compatiblized polyphenylene ether resin and polyamide resin, (b) a selectively hydrogenated diblock copolymer of the A-B type wherein block A is an alkenyl aromatic polymer and block B is an ethylene-propylene polymer, and (c) glass fibers, wherein the total weight of components (a), (b) and (c) is 100 parts by weight.
Claim 14
Dependent Claim
61 words
A thermoplastic composition comprising: (a) a base resin comprising a compatiblized polyphenylene ether resin and polyamide resin, (b) a selectively hydrogenated diblock copolymer of the A-B type wherein block A is an alkenyl aromatic polymer and block B is an ethylene-propylene polymer, and (c) glass fibers, wherein the total weight of components (a), (b) and (c) is 100 parts by weight.
Claim 15
Dependent Claim
24 words
A composition according to claim 12 wherein the polyphenylene ether resin is present in an amount of at least about 27 parts by weight.
Claim 16
Dependent Claim
23 words
A composition according to claim 12 wherein the polyamide resin is present in an amount of at least about 37 parts by weight.
Claim 17
Dependent Claim
25 words
A composition according to claim 12 wherein the selectively hydrogenated diblock copolymer is present in an amount of at least about 6 parts by weight.
Claim 18
Dependent Claim
22 words
A composition according to claim 12 wherein the glass fibers are present in an amount of at least about 10% by weight.
Claim 19
Dependent Claim
24 words
A composition according to claim 12 wherein the polyphenylene ether resin is present in an amount of 27 to about 42 parts by weight.
Claim 20
Dependent Claim
25 words
A composition according to claim 12 wherein the polyamide resin is present in an amount of from about 37 to about 42 parts by weight.
Claim 21
Dependent Claim
25 words
A composition according to claim 12 wherein the glass fibers are present in an amount of from about 10 to about 30 parts by weight.
Claim 22
Dependent Claim
62 words
A composition according to claim 12 wherein the polyphenylene ether resin is present in an amount of from about 27 to about 42 parts by weight, the polyamide is present in an amount of from about 37 to about 42 parts by weight, and the glass fibers are present in an amount of from about 10 to about 30 parts by weight.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1992-10-16 | 1993-04-17 | 1993-10-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-10-16 | 1997-04-17 | 1997-10-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-10-16 | 2001-04-17 | 2001-10-17 | $7700.00 | Window Closed / Lapsed |