US5085974A
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Photopolymerizable mixture, and a recording material produced therefrom
Assignee: Agfa Gevaert NV
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Filing: 1988-03-28
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Granted: 1992-02-04
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Expires: 2008-03-28
Abstract
Abstract A photopolymerizable mixture is disclosed which comprises a) a polymeric binder, b) an acrylate or alkacrylate of a polyhydric alcohol containing one or more groups which are photooxidizable on exposure in the presence of the photoreducible dye, and one or more urethane groups, c) a photoreducible dye as photoinitiator. The mixture is suitable for the production of printing plates and photoresists and is distinguished by increased photosensitivity, which can be even further increased by the addition of a photolytically cleavable compound which contains at least one trihalomethyl group. A recording material comprising the photopolymerizable mixture is also disclosed.
Inventors
- 👤 Werner Frass
- 👤 Dieter Mohr
- 👤 Klaus Rode
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 20:50
CPC Classifications
C; C08; C08L; C08L35/00; C08L35/02; G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/031; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/116
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
308 words
A photopolymerizable mixture consisting essentially of: a) a polymeric binder present in an amount sufficient to form a uniform layer, b) an acrylate or alkacrylate of a polyhydric alcohol represented by the formula ##STR12## in which Q denotes ##STR13## R denotes an alkyl, hydroxyalkyl or aryl group, R 1 and R 2 each denote a hydrogen atom, an alkyl group or an alkoxyalkyl group, R 3 denotes a hydrogen atom, a methyl group or an ethyl group, X 1 denotes a saturated hydrocarbon group having 2 to 12 carbon atoms, X 2 denotes a (c+1)-valent saturated hydrocarbon group in which up to 5 methylene groups may be replaced by oxygen atoms, D 1 and D 2 each denote a saturated hydrocarbon group having 1 to 5 carbon atoms, E denotes a saturated hydrocarbon group having 2 to 12 carbon atoms, a cycloaliphatic group which has 5 to 7 ring members and which contains, where appropriate, up to 2 N, O or S atoms as ring members, an arylene group having 6 to 12 carbon atoms, or a heterocyclic aromatic group having 5 or 6 ring members, a denotes 0 or an integer from 1 to 4, b denotes 0 to 1, a+b is at least 1, c denotes an integer from 1 to 3, m denotes 2, 3 or 4, depending on the valency of Q, and n denotes an integer from 1 to m, it being possible for all radicals of the same definition to be identical to or different from one another, and c) a photoreducible dye as photoinitiator, wherein components b) and c) are present in an amount sufficient to render exposed areas insoluble in developer and wherein the acrylate or alkacrylate contains one or more groups which are photooxidizable upon exposure in the presence of the photoreducible dye, and one or more urethane groups.
Claim 2
Dependent Claim
308 words
A photopolymerizable mixture consisting essentially of: a) a polymeric binder present in an amount sufficient to form a uniform layer, b) an acrylate or alkacrylate of a polyhydric alcohol represented by the formula ##STR12## in which Q denotes ##STR13## R denotes an alkyl, hydroxyalkyl or aryl group, R 1 and R 2 each denote a hydrogen atom, an alkyl group or an alkoxyalkyl group, R 3 denotes a hydrogen atom, a methyl group or an ethyl group, X 1 denotes a saturated hydrocarbon group having 2 to 12 carbon atoms, X 2 denotes a (c+1)-valent saturated hydrocarbon group in which up to 5 methylene groups may be replaced by oxygen atoms, D 1 and D 2 each denote a saturated hydrocarbon group having 1 to 5 carbon atoms, E denotes a saturated hydrocarbon group having 2 to 12 carbon atoms, a cycloaliphatic group which has 5 to 7 ring members and which contains, where appropriate, up to 2 N, O or S atoms as ring members, an arylene group having 6 to 12 carbon atoms, or a heterocyclic aromatic group having 5 or 6 ring members, a denotes 0 or an integer from 1 to 4, b denotes 0 to 1, a+b is at least 1, c denotes an integer from 1 to 3, m denotes 2, 3 or 4, depending on the valency of Q, and n denotes an integer from 1 to m, it being possible for all radicals of the same definition to be identical to or different from one another, and c) a photoreducible dye as photoinitiator, wherein components b) and c) are present in an amount sufficient to render exposed areas insoluble in developer and wherein the acrylate or alkacrylate contains one or more groups which are photooxidizable upon exposure in the presence of the photoreducible dye, and one or more urethane groups.
Claim 3
Dependent Claim
9 words
A mixture as claimed in claim 1, wherein n=m.
Claim 4
Dependent Claim
20 words
A mixture as claimed in claim 1, wherein E is a saturated alkylene group having 2 to 4 carbon atoms.
Claim 5
Dependent Claim
13 words
A mixture as claimed in claim 1, wherein R 3 ═CH 3 .
Claim 6
Dependent Claim
11 words
A mixture as claimed in claim 1, wherein a+b=1 or 2.
Claim 7
Dependent Claim
155 words
A mixture as claimed in claim 5, wherein the xanthene dye is a compound of the formula II ##STR14## in which R 4 and R 9 are identical or different and denote hydrogen or halogen atoms, nitro or hydroxyl groups or groups of the formula --HgOH, R 6 and R 7 are identical or different and denote hydrogen or halogen atoms or hydroxyl groups, R 5 denotes O or (+)NHalkyl X(-), R 8 denotes a hydrogen atom, an alkali metal, ammonium or trialkylammonium cation, or an alkyl or acyl group, R 10 denotes a hydrogen atom or a COOR 13 group, R 11 denotes a hydrogen or halogen atom or an amino group, R 12 denotes a hydrogen or halogen atom, R 13 denotes a hydrogen atom, an alkali metal or ammonium cation, an alkyl group or a polymeric radical, X denotes an anion, and d denotes zero or an integer from 1 to 3.
Claim 8
Dependent Claim
20 words
A mixture as claimed in claim 1, wherein the photoreducible dye is a xanthene, thiazine, pyronine, porphyrine or acridine dye.
Claim 9
Dependent Claim
54 words
A mixture as claimed in claim 7, wherein the dye is a compound of one of the formulae III and IV ##STR15## in which R 14 is one of the groups ═NH 2 .sup.(+) X.sup.(-) and ═N(alkyl) 2 .sup.(+) X.sup.(-), R 15 is an amino, alkylamino or dialkylamino group and X is an anion.
Claim 10
Dependent Claim
19 words
A mixture as claimed in claim 1, wherein the binder is insoluble in water and soluble in aqueous-alkaline solutions.
Claim 11
Dependent Claim
44 words
A mixture as claimed in claim 1, which contains 10 to 80% by weight of acrylate or alkacrylate, 20 to 90% by weight of polymeric binder and 0.01 to 10% by weight, relative to the nonvolatile components of the mixture, of the photoreducible dye.
Claim 12
Dependent Claim
24 words
A photopolymerizable recording material comprising a layer support and a photopolymerizable layer, wherein the photopolymerizable layer comprises a mixture as claimed in claim 1.
Claim 13
Dependent Claim
32 words
A photopolymerizable recording material according to claim 1, wherein said acrylate or alkacrylate of polyhydric alcohol is present in an amount ranging from about 10 to 80% by weight of the mixture.
Claim 14
Dependent Claim
33 words
A photopolymerizable recording material according to claim 1, wherein the photoreducible dye is present in an amount ranging from about 0.1 to 10% by weight, relative to the non-volatile components of the mixture.
Claim 15
Dependent Claim
15 words
A mixture as claimed in claim 1, wherein a=0 in not more than one radical.
Claim 16
Dependent Claim
9 words
A mixture as claimed in claim 1, wherein a=1.
Claim 17
Dependent Claim
11 words
A mixture as claimed in claim 1, wherein a=1 to 4.
Claim 18
Dependent Claim
74 words
A photopolymerizable mixture consisting essentially of: (a) a polymeric binder, (b) an acrylate or alkacrylate of a polyhydric alcohol, (c) a photoreducible dye as photoinitiator, and (d) a compound with an exposure forms free radicals which are capable of initiating polymerization of the acrylate or alkacrylate wherein the acrylate or alkacrylate contains one or more groups which are photooxidizable upon exposure in the presence of the photoreducible dye, and one or more urethane groups.
Claim 19
Dependent Claim
74 words
A photopolymerizable mixture consisting essentially of: (a) a polymeric binder, (b) an acrylate or alkacrylate of a polyhydric alcohol, (c) a photoreducible dye as photoinitiator, and (d) a compound with an exposure forms free radicals which are capable of initiating polymerization of the acrylate or alkacrylate wherein the acrylate or alkacrylate contains one or more groups which are photooxidizable upon exposure in the presence of the photoreducible dye, and one or more urethane groups.
Claim 20
Dependent Claim
34 words
A mixture as claimed in claim 17, wherein the free radical-forming compound is an s-triazine which is substituted by at least one trihalomethyl group and one further group or is an aryl trihalomethyl sulfone.
Claim 21
Dependent Claim
33 words
A mixture as claimed in claim 18, wherein the further group contains at least one aromatic ring which is connected to the triazine radical either directly or via a conjugated double bond system.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-02-03 | 1995-08-05 | 1996-02-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-02-03 | 1999-08-05 | 2000-02-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-02-03 | 2003-08-05 | 2004-02-04 | $7700.00 | Window Closed / Lapsed |