Processable radiation curable poly(vinyl chloride) resin compositions

Claim 2

A composition comprising a poly(vinyl chloride) resin and a vinyl chloride resin-compatible compound having (a) two to six terminal or pendant ethylenically-unsaturated groups, (b) two or more groups selected from divalent carbonylamino groups, divalent thiocarbonylamino groups, or both, and (c) polyvalent aliphatic group, Z, where Z represents the polyvalent residue remaining after the removal of hydroxyl or amino groups from an oligomeric nucleophilic compound, Z(XH) n , Z containing carbon and hydrogen atoms, and optionally oxygen atoms, and having a molecular weight of 500 to 5000, where X represents --O-- or ##STR25## in which R 2 is hydrogen or lower alkyl group, and where n represents an integer having a value of 2 to 6, provided that there is at least one divalent carbonylamino or thiocarbonylamino group per ethylenically-unsaturated group, the amount of said vinyl chloride resin-compatible compound being sufficient so that upon exposure of the composition to actinic radiation, a gel is formed, said vinyl chloride resin-compatible compound being characterized such that a film of a poly(vinyl chloride) resin and about 10 percent by weight of said vinyl chloride resin-compatible compound remains transparent when pressed at elevated temperatures near the fusing point of the composition of poly(vinyl chloride) resin and said vinyl chloride resin-compatible compound.

Claim 3

The composition of claim 1 further including up to 50 parts by weight of plasticizer per hundred parts by weight poly(vinyl chloride) resin, provided that there is no more than 100 parts in total of said vinyl chloride resin-compatible compound and said plasticizer per hundred parts by weight poly(vinyl chloride) resin, and there is no more than one part of plasticizer per part of vinyl chloride resin-compatible compound.

Claim 4

The composition of claim 1 further including up to 25% by weight, based on weight of total composition, of a reactive diluent monomer, said monomer being ethylenically-unsaturated.

Claim 5

The composition of claim 1 wherein said vinyl chloride resin-compatible compound is prepared by reacting (a) an ethylenically-unsaturated isocyanate or isothiocyanate with (b) an oligomeric nucleophilic compound which is a polyhydroxy compound or a polyamino compound having up to 120 repeating ester, oxyalkylene, or acrylic units.

Claim 6

The composition of claim 1 wherein there is 5 to 100 parts by weight vinyl chloride resin-compatible compound per 100 parts by weight poly(vinyl chloride) resin.

Claim 7

The composition of claim 1 further including up to 10 parts by weight of a source of free radicals per 100 parts by weight poly(vinyl chloride) resin.

Claim 8

A composition comprising a poly(vinyl chloride) resin and a vinyl chloride resin-compatible compound having (a) two to six terminal or pendant ethylenically-unsaturated groups, (b) two or more groups selected from divalent carbonylamino groups, divalent thiocarbonylamino groups, or both, and (c) polyvalent aliphatic group, which is the residue remaining after the removal of hydroxyl or amino groups from an oligomeric nucleophilic compound, provided that there is at least one divalent carbonylamino or thiocarbonylamino group per ethylenically-unsaturated group, the amount of said vinyl chloride resin-compatible compound being sufficient so that upon exposure of the composition to actinic radiation, a gel is formed, said vinyl chloride resin-compatible compound being characterized such that a film of a poly(vinyl chloride) resin and about 10 percent by weight of said vinyl chloride resin-compatible compound remains transparent when pressed at elevated temperatures near the fusing point of the composition of poly(vinyl chloride) resin and said vinyl chloride resin-compatible compound, said vinyl chloride resin-compatible compound having the following formula: ##STR26## wherein: Z represents the polyvalent residue remaining after the removal of hydroxyl or amino group from an oligomeric nucleophilic compound, Z(XH) n , Z containing carbon and hydrogen atoms, and optionally oxygen atoms, and having a molecular weight of 500 to 5000; X represents --O-- or ##STR27## in which R 2 is hydrogen or lower alkyl group; Y represents O or S; R represents a divalent radical selected from the group consisting of (CH 2 -- a , ##STR28## and ##STR29## in which a is an integer from 1 to 6, b is an integer from 2 to 6, R 3 is an alkylene group, a divalent carbocyclic aliphatic group with 5 or 6 ring members, or arylene group, Y is O or S; R 1 represents hydrogen or methyl; and n is an integer having a value of 2 to 6.

Claim 9

A composition comprising a poly(vinyl chloride) resin and a vinyl chloride resin-compatible compound having (a) two to six terminal or pendant ethylenically-unsaturated groups, (b) two or more groups selected from divalent carbonylamino groups, divalent thiocarbonylamino groups, or both, and (c) polyvalent aliphatic group, which is the residue remaining after the removal of hydroxyl or amino groups from an oligomeric nucleophilic compound, provided that there is at least one divalent carbonylamino or thiocarbonylamino group per ethylenically-unsaturated group, the amount of said vinyl chloride resin-compatible compound being sufficient so that upon exposure of the composition to actinic radiation, a gel is formed, said vinyl chloride resin-compatible compound being characterized such that a film of a poly(vinyl chloride) resin and about 10 percent by weight of said vinyl chloride resin-compatible compound remains transparent when pressed at elevated temperatures near the fusing point of the composition of poly(vinyl chloride) resin and said vinyl chloride resin-compatible compound, said vinyl chloride resin-compatible compound having the following formula: ##STR26## wherein: Z represents the polyvalent residue remaining after the removal of hydroxyl or amino group from an oligomeric nucleophilic compound, Z(XH) n , Z containing carbon and hydrogen atoms, and optionally oxygen atoms, and having a molecular weight of 500 to 5000; X represents --O-- or ##STR27## in which R 2 is hydrogen or lower alkyl group; Y represents O or S; R represents a divalent radical selected from the group consisting of (CH 2 -- a , ##STR28## and ##STR29## in which a is an integer from 1 to 6, b is an integer from 2 to 6, R 3 is an alkylene group, a divalent carbocyclic aliphatic group with 5 or 6 ring members, or arylene group, Y is O or S; R 1 represents hydrogen or methyl; and n is an integer having a value of 2 to 6.

Claim 10

A film prepared from the composition of claim 1.