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US4019972A Expired / Lapsed US ⏱️ 0.0 years remaining

Photopolymerizable copying compositions containing biuret-based polyfunctional monomers

Assignee: Hoechst AG
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Filing: 1974-12-02
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Granted: 1977-04-26
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Expires: 1994-12-02
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Abstract

Abstract This invention relates to a photopolymerizable copying composition comprising at least one binder, at least one photoinitiator, and at least one polymerizable, acid amide group-containing acrylic acid derivative or alkyl acrylic acid derivative which is not volatile at 100° C and contains at least two polymerizable groups in the molecule, the polymerizable compound containing at least one compound of the following general formula A(--X--NH--CO--G).sub.p wherein: A stands for Z(--CO--NH--) 2 wherein Z is ##STR1## --O--CH 2 --C q H 2q --O--, or --O--(CH 2 CH 2 --O--) r Wherein q is a whole number from 1 to 11, and r is a whole number from 1 to 5, or for E--C(--CH.sub.2 --O--CO--NH--).sub.3 wherein E is CH 3 --, C 2 H 5 -- or --NH--CO--O--CH 2 --, G stands for ##STR2## or ##STR3## wherein n is 0, 1, or 2, m is a whole number from 1 to 11, k is 0 or a whole number from 1 to 4, R 1 is alkyl with 1 to 3 carbon atoms, or --R 4 or --CH 2 --R 4 , R 2 and R 3 , which may be the same or different, are --H, --CH 3 , or --CH 2 R 4 , and R 4 is ##STR4## and is present in at least one of the groups R 1 , R 2 , and R 3 , X stands for a saturated or unsaturated bi-valent hydrocarbon group with 2 to 12 carbon atoms, and p is a whole number from 2 to 4.

Inventors

  • 👤 Raimund Josef Faust

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 17:33
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/106; Y10S430/109; Y10S430/11; Y10S430/111; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31721

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 193 words
A photopolymerizable copying composition comprising at least one binder, at least one photoinitiator, and at least one polymerizable acid amide group-containing acrylic acid derivative or alkyl acrylic acid derivative which is not volatile at 100° C and contains at least three polymerizable unsaturated groups in the molecule, the polymerizable compound containing at least one compound of the following general formula A (--X--NH--CO--G).sub.p wherein: A stands for --N(--CO--NH--) 2 G stands for ##STR20## or ##STR21## wherein n is 0, 1, or 2, m is a whole number from 1 to 11, k is 0 or a whole number from 1 to 4, R 1 is alkyl with 1 to 3 carbon atoms, or --R 4 or --CH 2 --R 4 R 4 and R 3 , which may be the same or different, are --H, --CH 3 , or --CH 2 R 4 , and R 4 is ##STR22## and is present at least one of the groups R 1 , R 2 , and R 3 , X stands for a saturated or unsaturated bi-valent hydrocarbon group with 2 to 12 carbon atoms, and p is a whole number from 2 to 4.
Claim 2
Dependent Claim 193 words
A photopolymerizable copying composition comprising at least one binder, at least one photoinitiator, and at least one polymerizable acid amide group-containing acrylic acid derivative or alkyl acrylic acid derivative which is not volatile at 100° C and contains at least three polymerizable unsaturated groups in the molecule, the polymerizable compound containing at least one compound of the following general formula A (--X--NH--CO--G).sub.p wherein: A stands for --N(--CO--NH--) 2 G stands for ##STR20## or ##STR21## wherein n is 0, 1, or 2, m is a whole number from 1 to 11, k is 0 or a whole number from 1 to 4, R 1 is alkyl with 1 to 3 carbon atoms, or --R 4 or --CH 2 --R 4 R 4 and R 3 , which may be the same or different, are --H, --CH 3 , or --CH 2 R 4 , and R 4 is ##STR22## and is present at least one of the groups R 1 , R 2 , and R 3 , X stands for a saturated or unsaturated bi-valent hydrocarbon group with 2 to 12 carbon atoms, and p is a whole number from 2 to 4.
Claim 3
Dependent Claim 19 words
A copying composition according to claim 1 wherein the polymerizable compound has a molecular weight between 300 and 10,000.
Claim 4
Dependent Claim 22 words
A copying composition according to claim 1 wherein the polymerizable compound have a viscosity between 5 and 10,000 poises at 50° C.
Claim 5
Dependent Claim 22 words
A copying composition according to claim 3 wherein the polymerizable compound has a viscosity between 10 and 2,500 poises at 50° C.
Claim 6
Dependent Claim 12 words
A copying composition according to claim 1 wherein A stands for ##STR23##
Claim 7
Dependent Claim 11 words
A copying composition according to claim 1 wherein n is 1.
Claim 8
Dependent Claim 14 words
A copying composition according to claim 1 wherein X is a saturated aliphatic group.
Claim 9
Dependent Claim 17 words
A copying composition according to claim 1 wherein the polymerizable compound contains at least two urethane groups.
Claim 10
Dependent Claim 24 words
A copying composition according to claim 1 wherein at least one of the groups G in the molecule has at least one oxygen atom.
Claim 11
Dependent Claim 15 words
A copying composition according to claim 1 wherein the polymerizable compound has the formula ##STR24##
Claim 12
Dependent Claim 15 words
A copying composition according to claim 1 wherein the polymerizable compound has the formula ##STR25##
Claim 13
Dependent Claim 15 words
A copying composition according to claim 1 wherein the polymerizable compound has the formula ##STR26##

References Cited (Backward Citations)

US3840369A Cited
US3850770A Cited
US3751259A Cited
US3804631A Cited
US3878077A Cited
US3673140A Cited
US3759809A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-04-25 1980-10-25 1981-04-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-04-25 1984-10-25 1985-04-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-04-25 1988-10-25 1989-04-26 $7700.00 Window Closed / Lapsed

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