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US5066616A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for improving photoresist on wafers by applying fluid layer of liquid solvent

Assignee: Avago Technologies International Sales Pte Ltd
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Filing: 1990-09-07
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Granted: 1991-11-19
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Expires: 2010-09-07
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Abstract

Abstract A method for applying photoresist to a top surface of a semiconductor wafer for defining an electronic circuit pattern. The wafer is placed on a horizontal turntable and liquid solvent is dispensed onto the wafer's top surface. Spinning the wafer distributes the solvent to a substantially uniform film thickness over the entire top surface. Liquid photoresist is dispensed onto the top surface over the solvent film, preferably while spinning the wafer, to distribute a photoresist layer over the entire top surface. Photoresist discharge is controlled so that the wafer sirface remains entirely wetted by the solvent film during distribution of the liquid photoresist. The solvent viscosity is lower than the liquid photoresist viscosity and the solvent film thickness is sufficient to enable the photoresist to fully cover any bare silicon, high density or undercut circuit features, generally in a range of 500 to 10,000 Angstroms and preferably 1,000 to 5,000 Angstroms.

Inventors

  • 👤 William G. Gordon

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 16:58
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/16; G03F7/162; Y; Y10; Y10S; Y10S148/00; Y10S148/137; Y10S438/00; Y10S438/942; Y10S438/948

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 101 words
In an integrated circuit fabrication process, a method for uniformly applying photoresist to a top surface of a wafer, the method comprising: spreading a liquid solvent substantially uniformly over the wafer surface to form a liquid solvent film; applying a liquid photoresist to the wafer surface; and spreading the photoresist over the solvent film while a thickness of at least 100 Angstroms of liquid solvent remains on the entire wafer surface to wet the wafer surface with a mobile layer of fluid solvent such that the photoresist is distributed in a substantially uniform layer over the entire surface of the wafer.
Claim 2
Dependent Claim 101 words
In an integrated circuit fabrication process, a method for uniformly applying photoresist to a top surface of a wafer, the method comprising: spreading a liquid solvent substantially uniformly over the wafer surface to form a liquid solvent film; applying a liquid photoresist to the wafer surface; and spreading the photoresist over the solvent film while a thickness of at least 100 Angstroms of liquid solvent remains on the entire wafer surface to wet the wafer surface with a mobile layer of fluid solvent such that the photoresist is distributed in a substantially uniform layer over the entire surface of the wafer.
Claim 3
Dependent Claim 27 words
A method according to claim 1 including spinning the wafer to spread the liquid solvent thereon and continuing to spin the wafer during discharge of the photoresist.
Claim 4
Dependent Claim 29 words
A method according to claim 2 in which the liquid photoresist is applied, while the liquid solvent film has a thickness sufficient to display interference colors under visible light.
Claim 5
Dependent Claim 85 words
A method according to claim 2 in which the liquid solvent is applied while the wafer is static and allowed to stand for a first time interval, the wafer is next spun at a first rate of rotation for a second time interval and then spun at a reduced, second rate of rotation for a third time interval, and the liquid photoresist discharge is commenced at the end of the third time interval while the wafer continues to rotate at said second rate of rotation.
Claim 6
Dependent Claim 40 words
A method according to claim 4 in which discharge of the liquid photoresist is stopped after a fourth time interval following commencement thereof and the wafer is spun at an increased, third rate of rotation for a fifth time interval.
Claim 7
Dependent Claim 47 words
A method according to claim 5 in which the first and second rates of rotation and the second and third time intervals are arranged so that the top surface of the wafer remains entirely wetted by the solvent film during discharge and spreading of the liquid photoresist.
Claim 8
Dependent Claim 14 words
A method according to claim 1 in which the solvent and photoresist are miscible.
Claim 9
Dependent Claim 18 words
A method according to claim 7 in which the liquid solvent and the liquid photoresist both include EGMEA.
Claim 10
Dependent Claim 14 words
A method according to claim 8 in which the liquid solvent further includes HMDS.
Claim 11
Dependent Claim 20 words
A method according to claim 1 in which the solvent has a viscosity less than a viscosity of the photoresist.
Claim 12
Dependent Claim 29 words
A method according to claim 1 in which the solvent film has a thickness in a range of 1,000 to 5,000 Angstroms when application of the photoresist is commenced.
Claim 13
Independent Claim 150 words
A method for applying photoresist to a top surface of a semiconductor wafer for defining an electronic circuit pattern thereto, the method comprising: positioning the wafer on a horizontal turntable with the top surface facing toward; discharging a liquid solvent onto a central area of the top surface; spinning the wafer to distribute a film of the solvent to a substantially uniform thickness over the entire top surface of the wafer; discharging a liquid photoresist onto the central area of the top surface of the wafer over the solvent film; spinning the wafer to distribute the photoresist in a layer over the entire top surface of the wafer; and controlling the discharge of photoresist so that the top surface of the wafer remains entirely wetted by a mobile fluid layer having a thickness of at least 100 Angstroms of the solvent film during discharge and distribution of the liquid photoresist.
Claim 14
Independent Claim 150 words
A method for applying photoresist to a top surface of a semiconductor wafer for defining an electronic circuit pattern thereto, the method comprising: positioning the wafer on a horizontal turntable with the top surface facing toward; discharging a liquid solvent onto a central area of the top surface; spinning the wafer to distribute a film of the solvent to a substantially uniform thickness over the entire top surface of the wafer; discharging a liquid photoresist onto the central area of the top surface of the wafer over the solvent film; spinning the wafer to distribute the photoresist in a layer over the entire top surface of the wafer; and controlling the discharge of photoresist so that the top surface of the wafer remains entirely wetted by a mobile fluid layer having a thickness of at least 100 Angstroms of the solvent film during discharge and distribution of the liquid photoresist.
Claim 15
Dependent Claim 75 words
A method according to claim 12 in which the wafer has an intermediate electronic circuit pattern formed thereon, the intermediate circuit pattern including at least one of bare silicon surfaces, high density circuit features and undercut circuit features; the solvent having a viscosity less than the viscosity of the liquid photoresist and the solvent film having sufficient fluid thickness to cause the photoresist to fully cover said bare silicon, high density and undercut circuit features.
Claim 16
Dependent Claim 29 words
A method according to claim 12 in which the solvent film has a thickness in a range of 500 to 10,000 Angstroms when application of the photoresist is commenced.
Claim 17
Dependent Claim 70 words
A method according to claim 12 in which the wafer is spun at a first rate of rotation for a first time interval to distribute the solvent film and then spun at a reduced, second rate of rotation for a second time interval, and the liquid photoresist discharge is commenced at the end of the second time interval while the wafer continues to rotate at said second rate of rotation.
Claim 18
Dependent Claim 40 words
A method according to claim 15 in which discharge of the liquid photoresist is stopped after a third time interval following commencement thereof and the wafer is spun at an increased, third rate of rotation for a fourth time interval.
Claim 19
Dependent Claim 47 words
A method according to claim 15 in which the first and second rates of rotation and the first and second time intervals are arranged so that the top surface of the wafer remains entirely wetted by the solvent film during discharge and distribution of the liquid photoresist.
Claim 20
Dependent Claim 16 words
A method as in claim 1 in which the liquid solvent comprises a glycol ether solvent.
Claim 21
Dependent Claim 18 words
A method as in claim 1 in which the liquid solvent comprises a glycol monoethyl ether acetate solvent.
Claim 22
Dependent Claim 19 words
A method as in claim 1 in which the liquid solvent comprises an ethylene glycol monoethyl ether acetate solvent.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-11-18 1995-05-20 1995-11-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-11-18 1999-05-20 1999-11-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-11-18 2003-05-20 2003-11-19 $7700.00 Window Closed / Lapsed

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