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US5019887A Expired / Lapsed US ⏱️ 0.0 years remaining

Non-single crystalline photosensor with hydrogen and halogen

Assignee: Canon Inc
•
Filing: 1990-10-11
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Granted: 1991-05-28
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Expires: 2010-10-11
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Abstract

Abstract A photosensor has a photoconductive member. The photoconductive member has a structure comprising a laminated product consisting of functional thin films superposed on one another. The laminated product comprises at least two functional thin films. The functional thin film containing 10 atomic % or less of hydrogen. The band gaps and conduction types and/or conductivity of the functional thin films are controlled to provide high photo sensitivity.

Inventors

  • 👤 Mitsuyuki Niwa
  • 👤 Takayoshi Arai
  • 👤 Isamu Shimizu
  • 👤 Eiji Takeuchi
  • 👤 Tsutomu Murakami
  • 👤 Shunichi Ishihara

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 19:13
CPC Classifications
H; H10; H10F; H10F71/00; H10F71/10; H10F71/103; H10F71/1035; H10F30/00; H10F30/10; H10F30/15; H10F77/00; H10F77/10; H10F77/16; H10F77/169; H10F77/1692; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y02P; Y02P70/00; Y02P70/50

Claims Analysis

Total Claims: 40
Claim 1
Independent Claim 122 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a laminate of a plurality of alternating layers of a first non-single crystalline thin film and a second non-single crystalline thin film, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; at least one of said first and second non-single crystalline thin films includes impurity for controlling conductivity; and said first and second non-single crystalline thin films have band gaps equal to each other and at least one of electroconduction types and electroconductivities different from each other.
Claim 2
Dependent Claim 122 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a laminate of a plurality of alternating layers of a first non-single crystalline thin film and a second non-single crystalline thin film, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; at least one of said first and second non-single crystalline thin films includes impurity for controlling conductivity; and said first and second non-single crystalline thin films have band gaps equal to each other and at least one of electroconduction types and electroconductivities different from each other.
Claim 3
Dependent Claim 13 words
A photosensor according to claim 1, wherein said photoconductive member contains amorphous silicon.
Claim 4
Dependent Claim 13 words
A photosensor according to claim 1, wherein said photoconductive member contains polycrystalline silicon.
Claim 5
Dependent Claim 122 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a laminate of a plurality of alternating layers of a first non-single crystalline thin film and a second non-single crystalline thin film, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; at least one of said first and second non-single crystalline thin films includes impurity for controlling conductivity; and said first and second non-single crystalline thin films have band gaps different from each other and at least one of electroconductive types and electroconductivities different from each other.
Claim 6
Dependent Claim 122 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a laminate of a plurality of alternating layers of a first non-single crystalline thin film and a second non-single crystalline thin film, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; at least one of said first and second non-single crystalline thin films includes impurity for controlling conductivity; and said first and second non-single crystalline thin films have band gaps different from each other and at least one of electroconductive types and electroconductivities different from each other.
Claim 7
Dependent Claim 13 words
A photosensor according to claim 4, wherein said photoconductive member contains amorphous silicon.
Claim 8
Dependent Claim 13 words
A photosensor according to claim 4, wherein said photoconductive member contains polycrystalline silicon.
Claim 9
Dependent Claim 122 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a laminate of a plurality of alternating layers of a first non-single crystalline thin film and a second non-single crystalline thin film, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; at least one of said first and second non-single crystalline thin films includes band gap regulating atoms; and said first and second non-single crystalline thin films have band gaps different from each other and at least one of electroconductive types and electroconductivities different from each other.
Claim 10
Dependent Claim 122 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a laminate of a plurality of alternating layers of a first non-single crystalline thin film and a second non-single crystalline thin film, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; at least one of said first and second non-single crystalline thin films includes band gap regulating atoms; and said first and second non-single crystalline thin films have band gaps different from each other and at least one of electroconductive types and electroconductivities different from each other.
Claim 11
Dependent Claim 13 words
A photosensor according to claim 7, wherein said photoconductive member contains amorphous silicon.
Claim 12
Dependent Claim 13 words
A photosensor according to claim 7, wherein said photoconductive member contains polycrystalline silicon.
Claim 13
Dependent Claim 202 words
A photosensor having a pair of electrodes and first and second photoconductive members sandwiched between the pair of electrodes, wherein said first photoconductive member consists of at least two kinds of non-single crystalline thin films laminated alternatively; each of said two kinds of non-single crystalline thin films has a thickness of 10 Å-10 μm; each of said two kinds of non-single crystalline thin films includes silicon atoms, hydrogen atoms at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; said two kinds of non-single crystalline thin films have at least one of band gaps and electroconductive types and conductivities different form each other; wherein said second photoconductive member consists of at least two kinds of non-single crystalline thin films laminated alternatively; each of said two kinds of non-single crystalline thin films has a thickness of 10 Å-10 μm; each of said two kinds of non-single crystalline thin films includes silicon atoms, hydrogen atoms at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; said two kinds of non-single crystalline thin films have band gaps equal to other, and at least one of electroconductive types and conductivity different from each other; and wherein said first and second photoconductive members are laminated.
Claim 14
Dependent Claim 202 words
A photosensor having a pair of electrodes and first and second photoconductive members sandwiched between the pair of electrodes, wherein said first photoconductive member consists of at least two kinds of non-single crystalline thin films laminated alternatively; each of said two kinds of non-single crystalline thin films has a thickness of 10 Å-10 μm; each of said two kinds of non-single crystalline thin films includes silicon atoms, hydrogen atoms at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; said two kinds of non-single crystalline thin films have at least one of band gaps and electroconductive types and conductivities different form each other; wherein said second photoconductive member consists of at least two kinds of non-single crystalline thin films laminated alternatively; each of said two kinds of non-single crystalline thin films has a thickness of 10 Å-10 μm; each of said two kinds of non-single crystalline thin films includes silicon atoms, hydrogen atoms at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; said two kinds of non-single crystalline thin films have band gaps equal to other, and at least one of electroconductive types and conductivity different from each other; and wherein said first and second photoconductive members are laminated.
Claim 15
Dependent Claim 13 words
A photosensor according to claim 10, wherein said photoconductive members contain amorphous silicon.
Claim 16
Dependent Claim 13 words
A photosensor according to claim 10, wherein said photoconductive members contain polycrystalline silicon.
Claim 17
Dependent Claim 147 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a laminate of a plurality of alternating layers of a first non-single crystalline thin film and a second non-single crystalline thin film, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; at least one of said first and second non-single crystalline thin films includes an impurity for controlling conductivity so that at least one of said first and second non-single crystalline thin films electroconductive types and conductivity are different from each other, wherein all of said first and second non-single crystalline thin films have band gaps different from each other, the band gaps continuously changing in the direction of said film thickness.
Claim 18
Dependent Claim 147 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a laminate of a plurality of alternating layers of a first non-single crystalline thin film and a second non-single crystalline thin film, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; at least one of said first and second non-single crystalline thin films includes an impurity for controlling conductivity so that at least one of said first and second non-single crystalline thin films electroconductive types and conductivity are different from each other, wherein all of said first and second non-single crystalline thin films have band gaps different from each other, the band gaps continuously changing in the direction of said film thickness.
Claim 19
Dependent Claim 13 words
A photosensor according to claim 13, wherein said photoconductive member contains polycrystalline silicon.
Claim 20
Dependent Claim 13 words
A photosensor according to claim 13, wherein said photoconductive member contains polycrystalline silicon.
Claim 21
Dependent Claim 222 words
A photosensor having a pair of electrodes and first and second photoconductive members sandwiched between the pair of electrodes, wherein said first photoconductive member consists of at least two kinds of non-single crystalline thin films laminated alternatively; each of said two kinds of non-single crystalline thin films has a thickness of 10 Å-10 μm; each of said two kinds of non-single crystalline thin films includes silicon atoms, hydrogen atoms at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; said two kinds of non-single crystalline thin films have band gaps different from each other, and at least one of electroconductive type and conductivity different from each other; wherein said second photoconductive member consists of at least two kinds of non-single crystalline thin films laminated alternatively; each of aid two kinds of non-single crystalline thin films has a thickness of 10 Å-10 μm; each of said tow kinds of non-single crystalline thin films includes silicon atoms, hydrogen atoms at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; said two kinds of non-single crystalline thin films have band gaps equal to each other, and at least one of electroconductive type and conductivity different from each other; and wherein said two kinds of non-single crystalline thin films are laminated; and the band gaps of the first and second photoconductive members are different.
Claim 22
Dependent Claim 222 words
A photosensor having a pair of electrodes and first and second photoconductive members sandwiched between the pair of electrodes, wherein said first photoconductive member consists of at least two kinds of non-single crystalline thin films laminated alternatively; each of said two kinds of non-single crystalline thin films has a thickness of 10 Å-10 μm; each of said two kinds of non-single crystalline thin films includes silicon atoms, hydrogen atoms at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; said two kinds of non-single crystalline thin films have band gaps different from each other, and at least one of electroconductive type and conductivity different from each other; wherein said second photoconductive member consists of at least two kinds of non-single crystalline thin films laminated alternatively; each of aid two kinds of non-single crystalline thin films has a thickness of 10 Å-10 μm; each of said tow kinds of non-single crystalline thin films includes silicon atoms, hydrogen atoms at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; said two kinds of non-single crystalline thin films have band gaps equal to each other, and at least one of electroconductive type and conductivity different from each other; and wherein said two kinds of non-single crystalline thin films are laminated; and the band gaps of the first and second photoconductive members are different.
Claim 23
Dependent Claim 13 words
A photosensor according to claim 16, wherein said photoconductive members contain amorphous silicon.
Claim 24
Dependent Claim 12 words
A photosensor according claim 16, wherein said photoconductive members contain polycrystalline silicon.
Claim 25
Dependent Claim 112 words
An image-forming method, which comprises: (a) using a photosensor having a non-single crystalline multi-layer film comprising two layers each with a thickness of 10 Å-10 μm, different electroconductivities and electroconductive types, superposed alternately, and each layer including silicon, hydrogen at 0.1 to 10 atomic percent and halogen at 0.0001 to 10 atomic percent, having electrodes respectively on the upper surface and the lower surface of said multi-layer film, with at least one of said electrodes being capable of transmitting light therethrough, and (b) irradiating light from an image signal on a portion of the multi-layer film constituting said photosensor to generate a current between the electrodes reflecting information from said image signal.
Claim 26
Dependent Claim 112 words
An image-forming method, which comprises: (a) using a photosensor having a non-single crystalline multi-layer film comprising two layers each with a thickness of 10 Å-10 μm, different electroconductivities and electroconductive types, superposed alternately, and each layer including silicon, hydrogen at 0.1 to 10 atomic percent and halogen at 0.0001 to 10 atomic percent, having electrodes respectively on the upper surface and the lower surface of said multi-layer film, with at least one of said electrodes being capable of transmitting light therethrough, and (b) irradiating light from an image signal on a portion of the multi-layer film constituting said photosensor to generate a current between the electrodes reflecting information from said image signal.
Claim 27
Dependent Claim 74 words
A photosensor having a photoconductive member, said photoconductive member having a structure comprising laminated non-single crystalline thin films of silicon and 0.5-10 atomic percent hydrogen, alternating pairs of said thin films having at least one of electroconductive types and electroconductivities different from each other, said photoconductive member having electrodes on the upper surface and the lower surfaces and both sides thereof, with at least one of said electrodes being capable of transmitting light therethrough.
Claim 28
Dependent Claim 74 words
A photosensor having a photoconductive member, said photoconductive member having a structure comprising laminated non-single crystalline thin films of silicon and 0.5-10 atomic percent hydrogen, alternating pairs of said thin films having at least one of electroconductive types and electroconductivities different from each other, said photoconductive member having electrodes on the upper surface and the lower surfaces and both sides thereof, with at least one of said electrodes being capable of transmitting light therethrough.
Claim 29
Dependent Claim 53 words
An image reading method, which comprises using a photosensor as defined in claim 20, applying a voltage between the electrodes on the photoconductive member and at the same time irradiating lightly from the image from the transparent electrode side to thereby generate a current reflecting the image information and reading the image information.
Claim 30
Dependent Claim 18 words
A photosensor according to claim 20, wherein said thin films contain 1 atomic percent or less of fluorine.
Claim 31
Dependent Claim 17 words
A photosensor according to claim 20, wherein the thin films constituting said photoconductive member contain amorphous silicon.
Claim 32
Dependent Claim 17 words
A photosensor according to claim 20, wherein the thin films constituting said photoconductive member contain polycrystalline silicon.
Claim 33
Dependent Claim 142 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a laminate of a plurality of alternating layers of a first non-single crystalline thin film and a second non-single crystalline thin film, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; at least one of said first and second non-single crystalline thin films includes an impurity for controlling conductivity; wherein the degree of crystallinity of at least one of said first and second non-single crystalline thin film is regulated; and said first and second non-single crystalline thin films have band gaps different from other, and at least one of electroconductive types and electroconductivities different from each other.
Claim 34
Dependent Claim 142 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a laminate of a plurality of alternating layers of a first non-single crystalline thin film and a second non-single crystalline thin film, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; at least one of said first and second non-single crystalline thin films includes an impurity for controlling conductivity; wherein the degree of crystallinity of at least one of said first and second non-single crystalline thin film is regulated; and said first and second non-single crystalline thin films have band gaps different from other, and at least one of electroconductive types and electroconductivities different from each other.
Claim 35
Dependent Claim 123 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a laminate of a plurality of alternating layers of a first non-single crystalline thin film and a second non-single crystalline thin film, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; degree of crystallinity of at least one of said first and second non-single crystalline thin films is regulated; and said first and second non-single crystalline thin films have band gaps equal to each other and at least one of electroconductive types and electroconductivities different from each other.
Claim 36
Dependent Claim 123 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a laminate of a plurality of alternating layers of a first non-single crystalline thin film and a second non-single crystalline thin film, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent; degree of crystallinity of at least one of said first and second non-single crystalline thin films is regulated; and said first and second non-single crystalline thin films have band gaps equal to each other and at least one of electroconductive types and electroconductivities different from each other.
Claim 37
Dependent Claim 119 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a plurality of first non-single crystalline thin films and a plurality of second non-single crystalline thin films laminated alternatively, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent, at least one of said first and second non-single crystalline thin films includes band gap regulating atoms, and said first and second non-single crystalline thin films have band gaps different from each other, and at least one of electroconductive types and electroconductivities equal to each other.
Claim 38
Dependent Claim 119 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a plurality of first non-single crystalline thin films and a plurality of second non-single crystalline thin films laminated alternatively, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent, at least one of said first and second non-single crystalline thin films includes band gap regulating atoms, and said first and second non-single crystalline thin films have band gaps different from each other, and at least one of electroconductive types and electroconductivities equal to each other.
Claim 39
Dependent Claim 122 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a plurality of first non-single crystalline thin films and a plurality of second non-single crystalline thin films laminated alternatively, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent, wherein the degree of crystallinity of at least one of said first and second non-single crystalline thin films is regulated, and said first and second non-single crystalline thin films have band gaps different from each other, and at least one of electroconductive types and electroconductivities equal to each other.
Claim 40
Dependent Claim 122 words
A photosensor having a pair of electrodes and a photoconductive member sandwiched between the pair of electrodes, said photoconductive member consisting of a plurality of first non-single crystalline thin films and a plurality of second non-single crystalline thin films laminated alternatively, wherein each of said first and second non-single crystalline thin films has a thickness of 10 Å-10 μm, and includes hydrogen at 0.5-10 atomic percent and halogen atoms at 0.0001-10 atomic percent, wherein the degree of crystallinity of at least one of said first and second non-single crystalline thin films is regulated, and said first and second non-single crystalline thin films have band gaps different from each other, and at least one of electroconductive types and electroconductivities equal to each other.

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Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-05-27 1994-11-26 1995-05-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-05-27 1998-11-26 1999-05-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-05-27 2002-11-26 2003-05-28 $7700.00 Window Closed / Lapsed

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