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Polyimides reaction products and use in electrophoretic deposition

Assignee: International Business Machines Corp
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Filing: 1987-01-02
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Granted: 1989-05-23
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Expires: 2007-01-02
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Abstract

Abstract Reaction product of a polyimide and a secondary/tertiary polyamine and/or primary/tertiary polyamine, and/or protected primary/tertiary polyamine, and use thereof in electrophoretic deposition.

Inventors

  • 👤 Stephen L. Buchwalter

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 06:11
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/1003; C09; C09D; C09D5/00; C09D5/44; C09D5/4419; C09D5/4461; H; H10; H10W; H10W20/00; H10W20/40; H10W20/45; H10W20/48

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 40 words
Reaction product of an organic, soluble polyimide polymer and a polyamine selected from the group consisting of secondary/tertiary polyamines, protected primary/secondary polyamines, and mixtures thereof to form diamide groups wherein said polyamine contains only one available reactive secondary amino group.
Claim 2
Dependent Claim 40 words
Reaction product of an organic, soluble polyimide polymer and a polyamine selected from the group consisting of secondary/tertiary polyamines, protected primary/secondary polyamines, and mixtures thereof to form diamide groups wherein said polyamine contains only one available reactive secondary amino group.
Claim 3
Dependent Claim 13 words
The reaction product of claim 1 wherein said polyamine is a secondary/tertiary polyamine.
Claim 4
Dependent Claim 13 words
The reaction product of claim 1 wherein said polyamine is a secondary/tertiary diamine.
Claim 5
Dependent Claim 11 words
The reaction product of claim 1 wherein said polyamine is 1-methylpiperazine.
Claim 6
Dependent Claim 31 words
The reaction product of claim 1 wherein the said polyamine is employed in an amount sufficient to react with at least about 10% of the imide groups of said polyimide polymer.
Claim 7
Dependent Claim 31 words
The reaction product of claim 1 wherein the said polyamine is employed in an amount sufficient to react with at least about 25% of the imide groups of said polyimide polymer.
Claim 8
Dependent Claim 43 words
Reaction product of an organic, soluble polyimide polymer and a polyamine selected from the group consisting of secondary/tertiary polyamines, protected primary/secondary polyamines and mixtures thereof to form diamide groups wherein said polyamine contains only one available reactive secondary amino group and an acid.
Claim 9
Dependent Claim 43 words
Reaction product of an organic, soluble polyimide polymer and a polyamine selected from the group consisting of secondary/tertiary polyamines, protected primary/secondary polyamines and mixtures thereof to form diamide groups wherein said polyamine contains only one available reactive secondary amino group and an acid.
Claim 10
Dependent Claim 14 words
The reaction product of claim 7 wherein said acid is an organic carboxylic acid.
Claim 11
Dependent Claim 27 words
The reaction product of claim 7 wherein said acid is selected from the group consisting of acetic acid, oxalic acid, lactic acid, chloroacetic acid, and mixtures thereof.
Claim 12
Dependent Claim 12 words
The reaction product of claim 7 wherein said acid includes acetic acid.
Claim 13
Dependent Claim 12 words
The reaction product of claim 7 wherein said acid includes lactic acid.
Claim 14
Dependent Claim 26 words
The reaction product of claim 7 wherein the acid is employed in an amount to provide an acid to amine equivalent of about 0.9 to 1.1.
Claim 15
Dependent Claim 13 words
The reaction product of claim 7 wherein said polyamine is a secondary/tertiary polyamine.
Claim 16
Dependent Claim 13 words
The reaction production of claim 7 wherein said polyamine is a secondary/tertiary diamine.
Claim 17
Dependent Claim 11 words
The reaction product of claim 7 wherein said polyamine is 1-methylpiperazine.
Claim 18
Dependent Claim 31 words
The reaction product of claim 7 wherein the said polyamine is employed in an amount sufficient to react with at least about 10% of the imide groups of said polyimide polymer.
Claim 19
Dependent Claim 31 words
The reaction product of claim 7 wherein the said polyamine is employed in an amount sufficient to react with at least about 25% of the imide groups of said polyimide polymer.
Claim 20
Dependent Claim 10 words
An aqueous emulsion containing the reaction product of claim 7.
Claim 21
Dependent Claim 18 words
The emulsion of claim 18 that contains about 1% to about 10% by weight of said reaction product.
Claim 22
Independent Claim 64 words
A method of coating a substrate comprising electrophoretically depositing a polyimide polymer onto a conductive substrate from composition containing the reaction product of an organic, soluble polyimide polymer and a polyamine selected from a the group consisting of secondary/tertiary polyamines, protected primary/secondary polyamines, and mixtures thereof to form diamide groups wherein said polyamine contains only one available reactive secondary amino group and an acid.
Claim 23
Independent Claim 64 words
A method of coating a substrate comprising electrophoretically depositing a polyimide polymer onto a conductive substrate from composition containing the reaction product of an organic, soluble polyimide polymer and a polyamine selected from a the group consisting of secondary/tertiary polyamines, protected primary/secondary polyamines, and mixtures thereof to form diamide groups wherein said polyamine contains only one available reactive secondary amino group and an acid.
Claim 24
Dependent Claim 12 words
The method of claim 20 wherein said composition is an aqueous emulsion.
Claim 25
Dependent Claim 14 words
The method of claim 21 wherein said polyimide polymer is deposited onto a cathode.
Claim 26
Dependent Claim 25 words
The method of claim 20 which further includes post-baking after the depositing to remove at least about 90% of the polyamine from the polyimide polymer.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-05-22 1992-11-21 1993-05-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-05-22 1996-11-21 1997-05-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-05-22 2000-11-21 2001-05-23 $7700.00 Window Closed / Lapsed

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