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US4433131A Expired / Lapsed US ⏱️ 0.0 years remaining

Coating solution of polyetherimide monomers

Assignee: Von Roll Isola USA Inc
•
Filing: 1981-07-30
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Granted: 1984-02-21
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Expires: 2001-07-30
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Abstract

Abstract Disclosed is a coating solution including an aromatic bis(ether anhydride) component, an organic diamine component, an organic triamine component, and a solvent system, and optionally water which may be coated on a substrate and polymerized to form high quality polyetherimide coatings.

Inventors

  • 👤 Donald A. Bolon
  • 👤 Thomas B. Gorczyca

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 02:04
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/1046; C08G73/1053; C08G73/1003; C08G73/1035; C08G73/1057; C08G73/1064; C08G73/1085; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 262 words
A monomeric coating solution comprising (1) an organic residue selected from the group consisting of acidic derivatives of aromatic bis(ether anhydride) and esterified derivatives of aromatic bis(ether anhydride) obtained from monofunctional alcohols, said bis(ether anhydride) having the formula: ##STR11## (2) an organic diamine having the formula: H.sub.2 N--R'--HN.sub.2 (3) an organic triamine having the formula: R.sup.2 (NH.sub.2).sub.3 (4) water and (5) a suitable organic solvent where R is a member selected from the class consisting of (A) divalent organic radicals having the following formulas: ##STR12## and (B) divalent organic radicals of the general formula: an (B) divalent organic radicals of the general formula: ##STR13## where m is 0 to 1 and X is a member selected from the class consisting of divalent radicals of the formulas, ##STR14## where y is an integer from 1 to 4, R 1 is a divalent organic radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6 to about 20 carbon atoms and haloginated derivatives thereof, (b) alkylene radicals having from 2 to about 20 carbon atoms, and cycloalkylene radicals having from 3 to about 30 carbon atoms, (c) from C 2 to about C 8 alkylene terminated polydiorganosiloxane, and (d) divalent radicals of the general formula: ##STR15## where m is as previously defined and Q is a member selected from the class consisting of: ##STR16## where x is an integer from 1 to 5 inclusive and R 2 is a member selected from the class consisting of (a) the following trivalent aromatic radicals: ##STR17## and (b) trivalent aliphatic radicals, or combinations thereof.
Claim 2
Dependent Claim 262 words
A monomeric coating solution comprising (1) an organic residue selected from the group consisting of acidic derivatives of aromatic bis(ether anhydride) and esterified derivatives of aromatic bis(ether anhydride) obtained from monofunctional alcohols, said bis(ether anhydride) having the formula: ##STR11## (2) an organic diamine having the formula: H.sub.2 N--R'--HN.sub.2 (3) an organic triamine having the formula: R.sup.2 (NH.sub.2).sub.3 (4) water and (5) a suitable organic solvent where R is a member selected from the class consisting of (A) divalent organic radicals having the following formulas: ##STR12## and (B) divalent organic radicals of the general formula: an (B) divalent organic radicals of the general formula: ##STR13## where m is 0 to 1 and X is a member selected from the class consisting of divalent radicals of the formulas, ##STR14## where y is an integer from 1 to 4, R 1 is a divalent organic radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6 to about 20 carbon atoms and haloginated derivatives thereof, (b) alkylene radicals having from 2 to about 20 carbon atoms, and cycloalkylene radicals having from 3 to about 30 carbon atoms, (c) from C 2 to about C 8 alkylene terminated polydiorganosiloxane, and (d) divalent radicals of the general formula: ##STR15## where m is as previously defined and Q is a member selected from the class consisting of: ##STR16## where x is an integer from 1 to 5 inclusive and R 2 is a member selected from the class consisting of (a) the following trivalent aromatic radicals: ##STR17## and (b) trivalent aliphatic radicals, or combinations thereof.
Claim 3
Dependent Claim 25 words
The coating solution of claim 1 wherein the diamine is used in a ratio of between 0.5 and 2.0 moles diamine per mole of dianhydride.
Claim 4
Dependent Claim 25 words
The coating solution of claim 1 wherein the diamine is used in a ratio of between 1.0 and 1.3 moles diamine per mole of dianhydride.
Claim 5
Dependent Claim 25 words
A coating solution of claim 1 where the aromatic bis(ether anhydride) is ##STR18## where R 2 is ##STR19## and Q 1 is selected from ##STR20##
Claim 6
Dependent Claim 20 words
A coating solution of claim 1 where the aromatic bis(ether anhydride) is ##STR21## where R 2 is as previously defined.
Claim 7
Dependent Claim 13 words
A coating solution of claim 1 where the organic diamine is methylene dianiline.
Claim 8
Dependent Claim 12 words
A coating solution of claim 1 where the organic diamine is oxydianiline.
Claim 9
Dependent Claim 21 words
The coating solution of claim 1, where the aromatic bis(ether anhydride) is 2,2-bis[4-(3,4-dicarboxyphenoxy)phenyl] propane dianhydride and the orgainic diamine is 4,4'-methylene-dianiline.
Claim 10
Dependent Claim 12 words
The coating solution of claim 1 where the triamine is 2,4-bis(p aminobenzyl)aniline.
Claim 11
Dependent Claim 11 words
The coating solution of claim 1 where the triamine is melamine.
Claim 12
Dependent Claim 22 words
The coating solution of claim 1 where the triamine is obtained by the hydrolysis of a phenol blocked polymeric 2,4 toluene diisocyanate.
Claim 13
Dependent Claim 27 words
The coating solution of claim 1 wherein the triamine is used in a ratio of between 1 percent to about 60 percent by weight of bis(ether anhydride).
Claim 14
Dependent Claim 11 words
An insulated electrical conductor coated with the solution of claim 1.
Claim 15
Dependent Claim 11 words
An insulated electrical conductor coated with the solution of claim 9.
Claim 16
Dependent Claim 11 words
An insulated electrical conductor coated with the solution of claim 10.
Claim 17
Dependent Claim 11 words
An insulated electrical conductor coated with the solution of claim 11.
Claim 18
Dependent Claim 14 words
A coating solution of claim 1 wherein said organic solvent comprises a monofunctional alcohol.
Claim 19
Dependent Claim 31 words
A coating solution comprising: (1) a monomeric acidic derivative of 2,2 bis[4,(3,4-dicarboxy phenoxy phenyl]propane dianhydride. (2) 2,4 bis (p-aminobenzyl aniline) (3) 4,4 methylene dianiline (4) water and (5) N-methyl pyrrolidone solvent.
Claim 20
Dependent Claim 31 words
A coating solution comprising: (1) a monomeric acidic derivative of 2,2 bis[4,(3,4-dicarboxy phenoxy phenyl]propane dianhydride. (2) 2,4 bis (p-aminobenzyl aniline) (3) 4,4 methylene dianiline (4) water and (5) N-methyl pyrrolidone solvent.
Claim 21
Dependent Claim 56 words
A coating solution comprising: (1) a monomeric residue selected from the group consisting of acidic derivatives and esterified derivatives of 2,2 bis(4,(3,4 dicarboxy phenoxy) phenyl) propane dianhydride obtained from the monomethyl ether of diethylene glycol and water (2) 2,4 bis(p-amino benzyl aniline) (3) 4,4 methylene dianiline (4) water and (5) the monomethyl ether of diethylene glycol.
Claim 22
Dependent Claim 56 words
A coating solution comprising: (1) a monomeric residue selected from the group consisting of acidic derivatives and esterified derivatives of 2,2 bis(4,(3,4 dicarboxy phenoxy) phenyl) propane dianhydride obtained from the monomethyl ether of diethylene glycol and water (2) 2,4 bis(p-amino benzyl aniline) (3) 4,4 methylene dianiline (4) water and (5) the monomethyl ether of diethylene glycol.

References Cited (Backward Citations)

US3498948A Cited
US4157996A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-02-20 1987-08-22 1988-02-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-02-20 1991-08-22 1992-02-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-02-20 1995-08-22 1996-02-21 $7700.00 Window Closed / Lapsed

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