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US4252707A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyamide-imide-acid binder with amine base

Assignee: Individual
•
Filing: 1977-01-04
•
Granted: 1981-02-24
•
Expires: 1997-01-04
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Abstract

Abstract High temperature resistant, water-thinnable, polyimide resin containing coating compositions are disclosed which have excellent properties of flexibility, adhesion and hydrolytic stability. Also disclosed are methods of making and using the novel coating compositions of the invention.

Inventors

  • 👤 John O. Ruid

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 09:03
CPC Classifications
C; C08; C08L; C08L79/00; C08L79/04; C08L79/08; C09; C09D; C09D179/00; C09D179/04; C09D179/08

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 76 words
An infinitely water-thinnable coating composition, which comprises; a binder which is a film forming salt of a polyamide-imide acid and a stoichiometric excess of an amine base selected from the group consisting of diethylamine, triethylamine, dipropylamine, ethylaminoethanol, N,N-dimethylethanolamine, N,N-diethylaminoethanol, diethylaminoethoxyethanol and diisopropylaminoethanol; a filler; and a water-miscible, inert, organic solvent for said salt; said salt having been formed in the presence of a proportion of a water-miscible, inert, organic solvent sufficient to solubilize said polyamide-imide acid.
Claim 2
Dependent Claim 76 words
An infinitely water-thinnable coating composition, which comprises; a binder which is a film forming salt of a polyamide-imide acid and a stoichiometric excess of an amine base selected from the group consisting of diethylamine, triethylamine, dipropylamine, ethylaminoethanol, N,N-dimethylethanolamine, N,N-diethylaminoethanol, diethylaminoethoxyethanol and diisopropylaminoethanol; a filler; and a water-miscible, inert, organic solvent for said salt; said salt having been formed in the presence of a proportion of a water-miscible, inert, organic solvent sufficient to solubilize said polyamide-imide acid.
Claim 3
Dependent Claim 53 words
A composition of claim 1 wherein said polyamide-imide acid contains imide linkages and recurring moieties of the structural formula: ##STR8## in the backbone thereof, wherein A is selected from hydrogen and a carboxy group; B is selected from oxygen and a group of the formula NH; and R represents a divalent organic radical.
Claim 4
Dependent Claim 30 words
A composition of claim 1 wherein said salt is formed by the reaction of said polyamide-imide acid and said base at a temperature of from about 150° to 200° F.
Claim 5
Dependent Claim 17 words
A composition according to claim 1 wherein said filler is an inorganic pigment having high temperature resistance.
Claim 6
Dependent Claim 12 words
A composition according to claim 1 wherein said amine base is N,N-dimethylethanolamine.
Claim 7
Dependent Claim 15 words
A composition according to claim 1 wherein said polyamide-imide acid is a polytrimellitamide resin acid.
Claim 8
Dependent Claim 21 words
A composition according to claim 1 wherein said polyamide-imide acid is the reaction product of p,p-diaminodiphenylmethane and trimellitic anhydride acid chloride.
Claim 9
Dependent Claim 19 words
A composition according to claim 1 wherein the filler/pigment-volume concentration is from about 1 percent to about 90 percent.
Claim 10
Dependent Claim 19 words
A composition according to claim 1 wherein the filler/pigment-volume concentration is from about 5 percent to about 75 percent.
Claim 11
Dependent Claim 10 words
A composition of claim 1 wherein said solvent is N-methylpyrrolidone.

References Cited (Backward Citations)

US3242136A Cited
US3528937A Cited
US3245932A Cited
US3546152A Cited
US3582458A Cited
US3652500A Cited
US3766117A Cited
US3833533A Cited
US3804793A Cited
US3787338A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-02-24 1984-08-25 1985-02-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-02-24 1988-08-25 1989-02-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-02-24 1992-08-25 1993-02-24 $7700.00 Window Closed / Lapsed

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