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US4778549A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalysts for accelerating burnout or organic materials

Assignee: Corning Glass Works
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Filing: 1987-04-13
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Granted: 1988-10-18
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Expires: 2007-04-13
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Abstract

Abstract This invention relates to a method for accelerating the burnout of organic material from a glass, glass-ceramic, or ceramic body where the burnout is conducted in a gaseous, essentially non-oxidizing atmosphere. The invention comprises incorporating very minute amounts of a metal-containing material into the glass, glass-ceramic, or ceramic body to act as a catalyst in the burnout process. Metals operable as catalysts include Ru, Rh, Pd, Os, Ir, and Pt.

Inventors

  • 👤 James H. Cowan, Jr.
  • 👤 Frederick E. Noll
  • 👤 Lloyd G. Young

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 05:46
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/01; C04B35/03; C04B35/04; C03; C03C; C03C10/00; C03C1/00; C03C8/00; C03C8/14; C04B35/622; C04B35/626; C04B35/63; C04B35/638; C04B37/00; C04B37/04; H; H10; H10D; H10D86/00; H10D86/80; H10D86/85; H05; H05K; H05K1/00; H05K1/02; H05K1/03; H05K1/0306

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 81 words
A method for accelerating the burnout in a wet, gaseous, inert atmosphere containing a very low level of oxygen of organic material from a body prior to sintering said body, said body comprising said organic material and an inorganic material selected from the group consisting of glasses, glass-ceramics, and ceramics, by incorporating in said body an effective amount of at least one metal-containing material wherein said metal is selected from the group consisting of Ru, Rh, Pd, Os, Ir, and Pt.
Claim 2
Independent Claim 81 words
A method for accelerating the burnout in a wet, gaseous, inert atmosphere containing a very low level of oxygen of organic material from a body prior to sintering said body, said body comprising said organic material and an inorganic material selected from the group consisting of glasses, glass-ceramics, and ceramics, by incorporating in said body an effective amount of at least one metal-containing material wherein said metal is selected from the group consisting of Ru, Rh, Pd, Os, Ir, and Pt.
Claim 3
Dependent Claim 31 words
A method according to claim 1 wherein at least one metal-containing material is incorporated in an amount calculated to be equivalent to at least about 2 ppm total of said metals.
Claim 4
Dependent Claim 27 words
A metal according to claim 2 wherein said metal-containing material is incorporated in an amount calculated to be equivalent to at least about 2-100 ppm of metal.
Claim 5
Dependent Claim 25 words
A method according to claim 1 wherein said metal-containing material is incorporated in a batch which is then melted and formed into a glass body.
Claim 6
Dependent Claim 18 words
A method according to claim 4 wherein said glass body is crystallized in situ to a glass-ceramic body.
Claim 7
Dependent Claim 24 words
A method according to claim 1 wherein said metal-containing material is incorporated in a glass body as an impurity from the glass melting unit.
Claim 8
Dependent Claim 19 words
A method according to claim 6 wherein said glass body is crystallized in situ to a glass ceramic body.
Claim 9
Dependent Claim 18 words
A method according to claim 1 wherein said metal-containing material is incorporated in said body in particulate form.
Claim 10
Dependent Claim 21 words
A method according to claim 1 wherein said metal-containing material is incorporated in said body in solution with said organic material.
Claim 11
Independent Claim 215 words
A method for fabricating microelectronic circuits consisting of interconnected, multilayer glass-ceramic substrates with conducting patterns and interconnecting vias produced from copper-containing thick-film inks comprising the steps of: (a) preparing a glass-forming batch of a desired composition; (b) melting said batch; (c) cooling said batch to a glass (d) comminuting said glass to very fine particles; (e) preparing a slurry of said glass particles in an organic vehicle system; (f) forming said slurry into thin green sheets; (g) cutting said sheets to desired dimensions and forming vias therein; (h) applying copper-containing, thick-film ink to said sheets and in said vias; (i) laminating said sheets together to form an integral monolithic substrate; (j) heating said substrate in a wet, gaseous, inert atmosphere containing avery low level of oxygen to a temperature and for a time sufficient to burn out said organic vehicle system; and (k) heating said substrate to a higher temperature for a time sufficient to sinter said glass particles together and simultaneously crystallize the glass in situ to a glass-ceramic; the improvement comprising accelerating the rate of burnout of said organic vehicle system by incorporating an effective amount of at least one metal-containing material into said thin green sheets, said metal being selected from the group consisting of Ru, Rh, Pd, Os, Ir, and Pt.
Claim 12
Independent Claim 215 words
A method for fabricating microelectronic circuits consisting of interconnected, multilayer glass-ceramic substrates with conducting patterns and interconnecting vias produced from copper-containing thick-film inks comprising the steps of: (a) preparing a glass-forming batch of a desired composition; (b) melting said batch; (c) cooling said batch to a glass (d) comminuting said glass to very fine particles; (e) preparing a slurry of said glass particles in an organic vehicle system; (f) forming said slurry into thin green sheets; (g) cutting said sheets to desired dimensions and forming vias therein; (h) applying copper-containing, thick-film ink to said sheets and in said vias; (i) laminating said sheets together to form an integral monolithic substrate; (j) heating said substrate in a wet, gaseous, inert atmosphere containing avery low level of oxygen to a temperature and for a time sufficient to burn out said organic vehicle system; and (k) heating said substrate to a higher temperature for a time sufficient to sinter said glass particles together and simultaneously crystallize the glass in situ to a glass-ceramic; the improvement comprising accelerating the rate of burnout of said organic vehicle system by incorporating an effective amount of at least one metal-containing material into said thin green sheets, said metal being selected from the group consisting of Ru, Rh, Pd, Os, Ir, and Pt.
Claim 13
Dependent Claim 31 words
A method according to claim 10 wherein at least one metal-containing material is incorporated in an amount calculated to be equivalent to at least about 2 ppm total of said metals.
Claim 14
Dependent Claim 31 words
A method according to claim 11 wherein at least one metal-containing material is incorporated in an amount calculated to be equivalent to at least about 2-100 ppm total of said metals.
Claim 15
Dependent Claim 16 words
A method according to claim 10 wherein said metal-containing material is incorporated in said glass-forming batch.
Claim 16
Dependent Claim 23 words
A method according to claim 10 wherein said metal-containing material is incorporated in said glass as an impurity from the glass melting unit.
Claim 17
Dependent Claim 18 words
A method according to claim 10 wherein said metal-containing material is incorporated in particulate form in said slurry.
Claim 18
Dependent Claim 19 words
A method according to claim 10 wherein said metal-containing material is incorporated in solution with said organic vehicle system.
Claim 19
Dependent Claim 30 words
A method according to claim 10 wherein the crystal phase present in said glass-ceramic is selected from the group consisting of cordierite, Ba-osumilite, anorthite, willemite, beta-spodumene, and BPO 4 .
Claim 20
Dependent Claim 26 words
A method according to claim 10 wherein said organic vehicle system contains a binder selected from the group consisting of polyvinylbutyral, ethyl cellulose, and epoxy resin.

References Cited (Backward Citations)

US4267074A Cited
US4234367A Cited
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US4547625A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-10-18 1992-04-18 1992-10-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-10-18 1996-04-18 1996-10-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-10-18 2000-04-18 2000-10-18 $7700.00 Window Closed / Lapsed

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