Abstract Templating compounds of the formula: (HO--C.sub.2 H.sub.4).sub.3 N.sup.⊕ --(CH.sub.2).sub.n -N.sup.⊕ (C 2 H 4 --OH) 3 2 Br.sup.⊖ wherein n equals 3, 4 or 5 are produced by reacting triethanolamine with α, ωdibromoalkanes, for example in the presence of a solvent. One can also react dibromoalkane with the triethanolamine in dropwise manner at reaction temperature. The product is subsequently recovered by known methods. The templating compositions can be used for the preparation of the zeolites of the pentasil types. These zeolites have the composition represented by the summary formula: (0.4-0.7)Na.sub.2 O/(0.3-0.6)Q.sub.2 O/Al.sub.2 O.sub.3 /(30-80)SiO.sub.2 /(4-10)H 2 O and have the following X-ray diffraction pattern: ______________________________________ d Å I/Io
______________________________________
11.0 ± 0.2
30-70
10.0 ± 0.2
30-80
4.4 ± 0.1
10-20
4.3 ± 0.1
10-20
3.85 ± 0.05
100
3.74 ± 0.05
40-65
3.66 ± 0.05
20-40
3.43 ± 0.03
15-25
2.01 ± 0.02
5-15
1.99 ± 0.02
5-15
______________________________________ They are prepared by utilizing an aqueous suspension of precipitated silica and mixing with an aqueous sodium aluminate composition and an aqueous solution of the template compound. This mixture is then converted under autogeneous pressure, the product is dried and then calcined. The pentasil type zeolites can be used in the conversion of methanol into hydrocarbons.
A method for the preparation of a zeolite of the pentasil type which is represented by the formula: (0.4-0.2)Na.sub.2 O/(0.3-0.6)Q.sub.2 O/Al.sub.2 O.sub.3 /(30-80)SiO.sub.2 /(4-10)H.sub.2 O wherein Q is an organic cation and by the x-ray diffraction pattern: ______________________________________
d (Å)
I/Io
______________________________________
11.0 ± 0.2
30-70
10.0 ± 0.2
30-80
4.4 ± 0.1
10-20
4.3 ± 0.1
10-20
3.85 ± 0.05
100
3.74 ± 0.05
40-65
3.66 ± 0.05
20-40
3.43 ± 0.03
15-25
2.01 ± 0.02
5-15
1.99 ± 0.02
5-15.
______________________________________ comprising suspending precipitated silica in water and adding thereto an aqueous solution of sodium aluminate and sodium hydroxide in water, providing a solution of a templating compound represented by the formula: (HO--C.sub.2 H.sub.4).sub.3 N.sup.⊕ --(CH.sub.2).sub.n --N.sup.⊕ (C.sub.2 H.sub.4 --OH).sub.3 2Br.sup.⊖ wherein n equals 3, 4, or 5 in water, and combining said solutions for the preparation of a reaction mixture with a composition (1.0-4.0) templating compound: (5-10)Na 2 O:Al 2 O 3 :(30-90)SiO 2 :(900-3000)H 2 O, subjecting the reaction mixture to autogeneous pressure at a temperature range of 100° to 180° C. within a time period of 1 to 20 days, isolating the product so obtained, drying and then calcining at a temperature ranging from 300° to 600° C.
Claim 2
Independent Claim
203 words
A method for the preparation of a zeolite of the pentasil type which is represented by the formula: (0.4-0.2)Na.sub.2 O/(0.3-0.6)Q.sub.2 O/Al.sub.2 O.sub.3 /(30-80)SiO.sub.2 /(4-10)H.sub.2 O wherein Q is an organic cation and by the x-ray diffraction pattern: ______________________________________
d (Å)
I/Io
______________________________________
11.0 ± 0.2
30-70
10.0 ± 0.2
30-80
4.4 ± 0.1
10-20
4.3 ± 0.1
10-20
3.85 ± 0.05
100
3.74 ± 0.05
40-65
3.66 ± 0.05
20-40
3.43 ± 0.03
15-25
2.01 ± 0.02
5-15
1.99 ± 0.02
5-15.
______________________________________ comprising suspending precipitated silica in water and adding thereto an aqueous solution of sodium aluminate and sodium hydroxide in water, providing a solution of a templating compound represented by the formula: (HO--C.sub.2 H.sub.4).sub.3 N.sup.⊕ --(CH.sub.2).sub.n --N.sup.⊕ (C.sub.2 H.sub.4 --OH).sub.3 2Br.sup.⊖ wherein n equals 3, 4, or 5 in water, and combining said solutions for the preparation of a reaction mixture with a composition (1.0-4.0) templating compound: (5-10)Na 2 O:Al 2 O 3 :(30-90)SiO 2 :(900-3000)H 2 O, subjecting the reaction mixture to autogeneous pressure at a temperature range of 100° to 180° C. within a time period of 1 to 20 days, isolating the product so obtained, drying and then calcining at a temperature ranging from 300° to 600° C.