EP0065401A2
Expired / Lapsed
EP
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Zeolites
Assignee: Imperial Chemical Industries Ltd
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Filing: 1982-05-10
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Granted: —
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Expires: 2002-05-10
Abstract
Abstract A synthetic zeolite material, designated zeolite Nu-4, having a molar composition expressed by the formula: 0.1 to 7.5 M 2 O:0.2 to 2.5 Y 2 0 3 :100 X0 2 :0 to 50 H 2 0 wherein M' is a monovalent cation or 1/n of a cation of valency n, X is silicon or germanium, Y is aluminium, iron, chromium, vanadium, molybdenum, arsenic, antimony, manganese, gallium, or boron, and H 2 0 is water of hydration additional to water notionally present when M 1 is H and having a defined X-raypattem is prepared from defined aqueous mixtures containing the oxide XO 2 , the oxide Y 2 O 3 and a polyalkylene polyamine. The zeolite is a useful catalyst for xylenes isomerisation and the like.
Inventors
- 👤 Thomas Vincent Whittam
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-10-28 11:14
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/046; B01J29/06; B01J29/40; B01J29/48; B01J29/86; C; C01; C01B; C01B39/00; C01B39/02; C01B39/06; C01B39/10; C01B39/12; C01B39/36; C01B39/38; C01B39/40; C10; C10G; C10G11/00; C10G11/02; C10G11/04; C10G11/05; C10G49/00; C10G49/02; C10G49/08; C10G2300/00; C10G2300/70
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
98 words
A synthetic zeolite material having a molar composition expressed by the formula: 0.1 to 7.5 M20 : 0.2 to 2.5 Y 2 O 3 : 100 XO 2 : 0 to 50 H 2 O wherein M 1 is a monovalent cation or 1/n of a cation of valency n, X is silicon or germanium, Y is aluminium, iron, chromium, vanadium, molybdenum, arsenic, antimony, manganese, gallium, or boron, and H 2 0 is water of hydration additional to water notionally present when M 1 is H, and having an X-ray pattern substantially as set out in Table 1.
Claim 2
Dependent Claim
98 words
A synthetic zeolite material having a molar composition expressed by the formula: 0.1 to 7.5 M20 : 0.2 to 2.5 Y 2 O 3 : 100 XO 2 : 0 to 50 H 2 O wherein M 1 is a monovalent cation or 1/n of a cation of valency n, X is silicon or germanium, Y is aluminium, iron, chromium, vanadium, molybdenum, arsenic, antimony, manganese, gallium, or boron, and H 2 0 is water of hydration additional to water notionally present when M 1 is H, and having an X-ray pattern substantially as set out in Table 1.
Claim 3
Dependent Claim
45 words
A synthetic zeolite material according to claim 1 having a molar compostion expressed by the formula: 0 . 1 to 7 . 5 M20 : 0 . 5 to 2 Y 2 O 3 : 100 XO 2 : 0 to 50 H 2 O
Claim 4
Dependent Claim
18 words
A synthetic zeolite material according to claim 1 or claim 2 wherein M 1 is or includes hydrogen.
Claim 5
Dependent Claim
125 words
A method of making a synthetic zeolite material as defined in claim 1 which comprises reacting an aqueous mixture containing at least one oxide XO 2 , at least one oxide Y 2 O 3 and at least one polyalkylene polyamine having the formula wherein each of R 1 and R 2 , independently, represents hydrogen or a C 1 - C 6 alkyl group, x is an integer from 2 to 6 and y is an integer from 0 to 10, provided that when y is O and R 1 and R 2 are both alkyl groups, x is 2 to 5 and that when y is O and R 1 and R 2 are not both alkyl groups, x is 4 or 5.
Claim 6
Dependent Claim
58 words
A method according to claim 4 wherein the aqueous mixture has the molar composition: wherein X and Y have the meanings given in claim 1 , M 1 is an alkali metal optionally with ammonium and/or hyrogen, M 2 is an alkali metal, ammonium or hydrogen, Q is the polyalkylene polyamine and Z is a strong acid radical.
Claim 7
Dependent Claim
14 words
A method according to claim 5 wherein the aqueous mixture has the molar composition:
Claim 8
Dependent Claim
14 words
A method according to claim 5 wherein the aqueous mixture has the molar composition:
Claim 9
Dependent Claim
14 words
A method according to claim 5 wherein the aqueous mixture has the molar composition:
Claim 10
Dependent Claim
14 words
A method according to claim 5 wherein the aqueous mixture has the molar composition:
Claim 11
Dependent Claim
14 words
A method according to claim 5 wherein the aqueous mixture has the molar compostion:
Claim 12
Dependent Claim
14 words
A method according to claim 5 wherein the aqueous mixture has the molar composition:
Claim 13
Independent Claim
23 words
A method according to any-one of claims 4 to 11 wherein the polyamine is triethylene tetramine, tetraethylene pentamine or N, N-diethyl ethylene diamine.
Claim 14
Dependent Claim
17 words
A catalyst composing a synthetic zeolite material as claimed in any one of claims 1 to 3.
Claim 15
Dependent Claim
10 words
A catalytic process employing the catalyst claimed in claim 13.
References Cited (Backward Citations)
No citation records indexed.
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