US4626421A
Expired / Lapsed
US
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Preparation of magadiite
Assignee: Chevron USA Inc
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Filing: 1985-06-28
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Granted: 1986-12-02
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Expires: 2005-06-28
Abstract
Abstract A method for preparing magadiite is described wherein the reaction mixture for crystallization thereof contains as a promoter, a hydrocarbon substituted urea or amide. The magadiite prepared according to this method may act as a source of silica in preparing crystalline zeolites or molecular sieves.
Inventors
- 👤 Stacey I. Zones
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 06:28
CPC Classifications
C; C01; C01B; C01B33/00; C01B33/20; C01B33/36; C01B33/38; C01B39/00; C01B39/02; C01B39/36; C01B39/38; C01B39/40
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
284 words
In the method for preparing magadiite or an alkali metal form of magadiite from an aqueous reaction mixture containing an alkali metal hydroxide and a source of silica oxide, the improvement which comprises adding to said aqueous reaction mixture a promoter selected from the group consisting of a hydrocarbon substituted urea and hydrocarbon substituted amide or mixtures thereof wherein the hydrocarbon substituted urea has the formula: ##STR3## wherein R 2 and R 3 are the same or different and each is H, lower alkyl of 1 to 5 carbon atoms or R 2 and R 3 together with the nitrogen to which they are attached form an alkylene group containing 4 to 7 carbon atoms which may be interrupted by an O, S or N atom; R 4 and R 5 are the same or different and each is H, lower alkyl of 1 to 5 carbon atoms or R 4 and R 5 together with the nitrogen to which they are attached form an alkylene group containing 4 to 7 carbon atoms which may be interrupted by an O, S or N atom, with the proviso that R 2 , R 3 R 4 and R 5 cannot all be hydrogen at the same time, the hydrocarbon substituted amide has the formula: ##STR4## wherein R 6 and R 7 are H or lower alkyl containing 1 to 5 carbon atoms or R 6 or R 7 together with the nitrogen to which they are attached form an alkylene group containing 4 to 7 carbon atoms which may be interrupted by an O, S or N atom, with the proviso that both R 6 and R 7 cannot be hydrogen at the same time.
Claim 2
Dependent Claim
284 words
In the method for preparing magadiite or an alkali metal form of magadiite from an aqueous reaction mixture containing an alkali metal hydroxide and a source of silica oxide, the improvement which comprises adding to said aqueous reaction mixture a promoter selected from the group consisting of a hydrocarbon substituted urea and hydrocarbon substituted amide or mixtures thereof wherein the hydrocarbon substituted urea has the formula: ##STR3## wherein R 2 and R 3 are the same or different and each is H, lower alkyl of 1 to 5 carbon atoms or R 2 and R 3 together with the nitrogen to which they are attached form an alkylene group containing 4 to 7 carbon atoms which may be interrupted by an O, S or N atom; R 4 and R 5 are the same or different and each is H, lower alkyl of 1 to 5 carbon atoms or R 4 and R 5 together with the nitrogen to which they are attached form an alkylene group containing 4 to 7 carbon atoms which may be interrupted by an O, S or N atom, with the proviso that R 2 , R 3 R 4 and R 5 cannot all be hydrogen at the same time, the hydrocarbon substituted amide has the formula: ##STR4## wherein R 6 and R 7 are H or lower alkyl containing 1 to 5 carbon atoms or R 6 or R 7 together with the nitrogen to which they are attached form an alkylene group containing 4 to 7 carbon atoms which may be interrupted by an O, S or N atom, with the proviso that both R 6 and R 7 cannot be hydrogen at the same time.
Claim 3
Dependent Claim
28 words
The method of claim 1 which contains an additional step of treating the product formed therein under acidic conditions in order to form the hydrogen form of magadiite.
Claim 4
Dependent Claim
12 words
The method of claim 1 wherein the hydrocarbon substituted urea is N,N,N',N'-tetramethylurea.
Claim 5
Dependent Claim
53 words
A method according to claim 1 wherein in the hydrocarbon substituted urea, R 2 , R 3 , R 4 and R 5 are the same or different and each is hydrogen or lower alkyl of 1 to 5 carbon atoms with the proviso that each cannot be hydrogen at the same time.
Claim 6
Dependent Claim
39 words
The method of claim 1 wherein in the hydrocarbon substituted amide, R 6 and R 7 are hydrogen or lower alkyl of 1 to 5 carbon atoms with the proviso that both cannot be hydrogen at the same time.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-12-01 | 1990-06-02 | 1990-12-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-12-01 | 1994-06-02 | 1994-12-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-12-01 | 1998-06-02 | 1998-12-02 | $7700.00 | Window Closed / Lapsed |