Zeolite SSZ-13 and its method of preparation

Claim 2

A zeolite having a mole ratio of an oxide as synthesized selected from the group consisting of silicon oxide, germanium oxide and mixtures thereof to an oxide selected from the group consisting of aluminum oxide, gallium oxide, and mixtures thereof greater than 5:1, and having the X-ray diffraction pattern of Table 1.

Claim 3

A zeolite having a composition, as synthesized and in the anhydrous state, in terms of mole ratios of oxides as follows: (0.5 to 1.0)R 2 O:(0 to 0.50)M 2 O--W 2 O 3 : (greater than 5) YO 2 wherein M is an alkali metal cation, W is selected from the group consisting of aluminum, gallium and mixtures thereof, Y is selected from the group consisting of silicon, germanium and mixtures thereof, R is a quaternary lower alkylammonium cation compound selected from the group consisting of N-alkyl-3-quinuclidinol, N,N,N-tri-alkyl-1-adamantammonium, and N,N,N-trialkyl-exoaminonorbornane, or mixtures thereof, and having the X-ray diffraction pattern of Table 1.

Claim 4

A zeolite having a composition, as synthesized and in the anhydrous state, in terms of mole ratios of oxides as follows: (0.5 to 1.0)R 2 O:(0 to 0.50)M 2 O--W 2 O 3 : (greater than 5) YO 2 wherein M is an alkali metal cation, W is selected from the group consisting of aluminum, gallium and mixtures thereof, Y is selected from the group consisting of silicon, germanium and mixtures thereof, R is a quaternary lower alkylammonium cation compound selected from the group consisting of N-alkyl-3-quinuclidinol, N,N,N-tri-alkyl-1-adamantammonium, and N,N,N-trialkyl-exoaminonorbornane, or mixtures thereof, and having the X-ray diffraction pattern of Table 1.

Claim 5

A zeolite according to claim 2 wherein W is aluminum and Y is silicon.

Claim 6

A zeolite prepared by calcining the zeolite of claim 3, at a temperature from about 200° C. to 820° C. and having the X-ray diffraction lines of Table 2.

Claim 7

A zeolite according to claim 1, 2, 3 or 4 which has undergone ion exchange with hydrogen, ammonium, rare earth metal, Group IIA metal, or Group VIII metal ions.

Claim 8

A zeolite according to claim 1, 2, 3 or 4 wherein rare earth metals, Group IIA metals, or Group VIII metals are occluded in the zeolite.

Claim 9

A zeolite of matter, comprising the zeolite of claim 1, 2, 3 or 4 and an inorganic matrix.

Claim 10

A method for preparing the zeolite of claim 2, comprising: (a) preparing an aqueous mixture containing sources of an organonitrogen compound, an oxide selected from the group consisting of aluminum oxide, gallium oxide, and mixtures thereof, and an oxide selected from silicon oxide, germanium oxide, and mixtures thereof the aqueous mixture having the following composition in terms of mole ratio of oxides: YO 2 /W 2 O 3 =5-350 M 2 O/W 2 O 3 =0.5 to 20 R 2 O/W 2 O 3 =0.5-40 wherein R is a quaternary lower alkylammonium cation compound selected from the group consisting of N-alkyl-3-quinuclidinol, N,N,N-trialkyl-1-adamantammonium, and N,N,N-trialkyl-2-exoaminonorbornane or mixtures thereof, Y is silicon, germanium, or mixtures thereof, W is aluminum, gallium, or mixtures thereof; (b) maintaining the mixture at a temperature of at least 100° C. until the crystals of said zeolite form; and (c) recovering said crystals.

Claim 11

The method of according to claim 6 wherein Y is silicon, and said source of silicon oxide is an aqueous colloidal suspension of silica.

Claim 12

The method according to claim 6 wherein Y is silicon, said source of silicon oxide is a solution of a silicon salt, and said aqueous mixture has a mole ratio of OH:SiO 2 of greater than 0.95:1.