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US4526852A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid developer for developing electrostatic charge images and process for its preparation

Assignee: Hoechst AG
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Filing: 1983-12-16
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Granted: 1985-07-02
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Expires: 2003-12-16
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Abstract

Abstract The invention relates to a liquid developer with negatively charged toner particles for developing electrostatic charge images. It is composed of a carrier liquid of high electric resistivity and low dielectric constant, pigments or dyes, a binder, a dispersing agent and a charge control agent, such as an N-vinylpyrrolidone-containing polymer, a waxy substance and conventional additives. The liquid developer additionally contains at least one wax which is readily soluble in the carrier liquid at increasing temperatures, but difficultly soluble at room temperature, which reduces the specific electric conductivity of the liquid developer and which has a softening point within a range of from about 50° to 120° C. and an acid number of from about 0 to 200.

Inventors

  • 👤 Heinz Herrmann
  • 👤 Hans-Joachim Schlosser

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 23:00
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/12; G03G9/135; G03G9/13; G03G9/131

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 141 words
A liquid developer containing negatively charged toner particles for developing electrostatic charge images, which comprises: a carrier liquid of high electric resistivity and low dielectric constant; pigments or dyes; a N-vinylpyrrolidone-containing polymer; and at least one wax which is readily soluble in said carrier liquid at increasing temperatures, but difficultly soluble a room temperature in aliphatic hydrocarbon carrier liquids, which reduces the specific electric conductivity of the liquid developer and which has a softening point within a range of from about 50° to 120° C. and an acid number of from about 0 to about 200, said wax (i) being an acid or ester wax derived from montan wax, hydrated castor oil or polyoctadecene, and (ii) being present in said carrier liquid as fine particles or microcrystalline structures having a size of between about 0.1 and a few tens of microns.
Claim 2
Dependent Claim 141 words
A liquid developer containing negatively charged toner particles for developing electrostatic charge images, which comprises: a carrier liquid of high electric resistivity and low dielectric constant; pigments or dyes; a N-vinylpyrrolidone-containing polymer; and at least one wax which is readily soluble in said carrier liquid at increasing temperatures, but difficultly soluble a room temperature in aliphatic hydrocarbon carrier liquids, which reduces the specific electric conductivity of the liquid developer and which has a softening point within a range of from about 50° to 120° C. and an acid number of from about 0 to about 200, said wax (i) being an acid or ester wax derived from montan wax, hydrated castor oil or polyoctadecene, and (ii) being present in said carrier liquid as fine particles or microcrystalline structures having a size of between about 0.1 and a few tens of microns.
Claim 3
Dependent Claim 46 words
A liquid developer as claimed in claim 1, wherein the wax reduces the specific electric conductivity of said liquid developer by at least about 15%, when 1% by weight of wax is added to the toner concentrate having a solids content of about 7% by weight.
Claim 4
Dependent Claim 25 words
A liquid developer as claimed in claim 1, wherein the wax has a softening point within a range of from about 60° to 90° C.
Claim 5
Dependent Claim 21 words
A liquid developer as claimed in claim 1, wherein the wax has an acid number of from about 0 to 160.
Claim 6
Dependent Claim 21 words
A liquid developer as claimed in claim 1, wherein the wax has an acid number of from about 10 to 160.
Claim 7
Dependent Claim 30 words
A liquid developer as claimed in claim 1, wherein between about 0.1 and 1.5 parts by weight of wax are contained per 1 part by weight of pigment or dye.
Claim 8
Dependent Claim 54 words
A liquid developer as claimed in claim 1, wherein the wax comprises an ester wax which is derived from montan wax and has a softening point within a range of from about 82° to 88° C., an acid number of from 78 to 88, and a saponification number of from about 120 to 135.
Claim 9
Dependent Claim 55 words
A liquid developer as claimed in claim 1, wherein the wax comprises an ester wax which is derived from montan wax and has a softening point within a range of from about 76° to 82° C., an acid number of from about 15 to 20, and a saponification number of from about 125 to 155.
Claim 10
Dependent Claim 55 words
A liquid developer as claimed in claim 1, wherein the wax comprises an ester wax which is derived from montan wax and has a softening point within a range of from about 78° to 86° C., an acid number of from about 15 to 30 and a saponification number of from about 130 to 150.
Claim 11
Dependent Claim 46 words
A liquid developer as claimed in claim 1, wherein the wax comprises an acid wax which is derived from montan wax and has a softening point within a range of from about 78° to 84° C. and an acid number of from about 135 to 155.
Claim 12
Dependent Claim 35 words
A liquid developer as claimed in claim 1, wherein the wax comprises a hydrated castor oil which has a softening point of from about 86° to 88° C. and an acid number of about 2.
Claim 13
Dependent Claim 29 words
A liquid developer as claimed in claim 1, wherein the wax comprises a polyoctadecene which has a softening point of about 70° C. and an acid number of 0.
Claim 14
Dependent Claim 27 words
A liquid developer as claimed in claim 1, wherein said wax is readily soluble in said carrier liquid at a temperature between about 50° and 80° C.

References Cited (Backward Citations)

US3542682A Cited
US4081391A Cited
JPS5140465A Cited
US3992342A Cited
US4243736A Cited
US4357406A Cited
US4250241A Cited
JPS5590959A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-07-01 1988-12-31 1989-07-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-07-01 1992-12-31 1993-07-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-07-01 1996-12-31 1997-07-02 $7700.00 Window Closed / Lapsed

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