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US4506435A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for forming recessed isolated regions

Assignee: International Business Machines Corp
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Filing: 1981-07-27
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Granted: 1985-03-26
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Expires: 2001-07-27
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Abstract

Abstract A method is described for forming the recessed dielectric isolation in a silicon substrate involves first forming trenches which may be less than about 1 micron in depth in areas of one principal surface of the silicon substrate where isolation is desired. Where, for example, an NPN bipolar transistor structure is planned to be formed it is usually necessary to have a P+ region underneath the recessed dielectric isolation to allow full isolation between the various bipolar transistor devices. A PNP transistor uses an N+ region underneath the isolation. Where a field effect transistor is planned a channel stop can be substituted for the P+ region. Under the circumstance of bipolar devices, the P+ region is formed in the substrate prior to the deposition of an epitaxial layer thereover. The trench formation is caused to be formed through the epitaxial layer and into the P+ regions therein. The surface of the trenches are then oxidized in an oxidizing ambient to form a silicon dioxide layer thereon. A glass is deposited over this principal surface. The glass used has a thermal coefficient of expansion that approximates that of silicon and has a softening temperature of less than about 1200 DEG C. The structure is then heated to a temperature that allows the flow of the deposited glass on the surface so as to fill the trenches. The glass on the principal surface above the trench can be removed by a reactive ion etching method. Alternatively and preferably, the glass is removed from areas other than the immediate area of the trench by lithography and etching techniques followed by a second heating of the structure to cause the glass flow to result in surface planarization.

Inventors

  • 👤 William A. Pliskin
  • 👤 Jacob Riseman
  • 👤 Joseph F. Shepard

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 21:54
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/69; H10P14/692; H10P14/6921; H10P14/6928; H10P14/6929; H10P14/63; H10P14/6326; H10P14/6328; H10P14/6329; H10P14/6334; H10P14/6342; H10P14/65; H10P14/6502; H10P14/6506; H10P95/00; H10W; H10W10/00; H10W10/01; H10W10/011; H10W10/014; H10W10/0145; H10W10/0148; H10W10/10; H10W10/17

Claims Analysis

Total Claims: 31
Claim 1
Independent Claim 123 words
A method for forming recessed dielectric isolation in a silicon substrate comprising: forming by reactive ion etching a pattern of trenches in the order of microns in depth and with substantially vertical walls in the areas of one surface of said substrate wherein said isolation is desired; oxidizing the surfaces of said trenches to form a silicon dioxide layer thereon; depositing a glass having a thermal coefficient of expansion that approximates that of silicon and is between about 20 to 50×10 -7 per degree centigrade and has a softening temperature of less than about 1200° C. onto the said surface of said substrate; and thermally heating the structure to cause the flow of said glass on said surface and filling of said trenches.
Claim 2
Independent Claim 123 words
A method for forming recessed dielectric isolation in a silicon substrate comprising: forming by reactive ion etching a pattern of trenches in the order of microns in depth and with substantially vertical walls in the areas of one surface of said substrate wherein said isolation is desired; oxidizing the surfaces of said trenches to form a silicon dioxide layer thereon; depositing a glass having a thermal coefficient of expansion that approximates that of silicon and is between about 20 to 50×10 -7 per degree centigrade and has a softening temperature of less than about 1200° C. onto the said surface of said substrate; and thermally heating the structure to cause the flow of said glass on said surface and filling of said trenches.
Claim 3
Dependent Claim 21 words
The method of claim 1 wherein a layer of silicon nitride is formed over said silicon dioxide layer in said trenches.
Claim 4
Dependent Claim 14 words
The method of claim 1 wherein said glass is formed by a sedimentation process.
Claim 5
Dependent Claim 21 words
The method of claim 3 wherein said sedimentation process involves spray coating of glass particles upon said surfaces of said substrate.
Claim 6
Dependent Claim 22 words
The method of claim 3 wherein said sedimentation process involves centrifuging a coating of glass particles upon said surfaces of said substrate.
Claim 7
Dependent Claim 24 words
The method of claim 3 wherein said sedimentation process involves a spin-on of a coating of glass particles upon said surfaces of said substrate.
Claim 8
Dependent Claim 14 words
The method of claim 1 wherein said glass is formed by a sputtering process.
Claim 9
Dependent Claim 14 words
The method of claim 1 wherein said glass is formed by an evaporation process.
Claim 10
Dependent Claim 26 words
The method of claim 1 wherein the said heating step raises the temperature of said structure to less than about 1000° C. to cause said flow.
Claim 11
Dependent Claim 13 words
The method of claim 1 wherein said glass is a lead borosilicate glass.
Claim 12
Dependent Claim 14 words
The method of claim 1 wherein said glass is a calcium alumino borosilicate glass.
Claim 13
Dependent Claim 12 words
The method of claim 1 wherein said glass is a β-spodumene glass-ceramic.
Claim 14
Dependent Claim 12 words
The method of claim 1 wherein said glass is a cordierite glass-ceramic.
Claim 15
Dependent Claim 15 words
The method of claim 2 wherein there is a significant sodium content in said glass.
Claim 16
Dependent Claim 13 words
The method of claim 1 wherein the said glass is substantially sodium free.
Claim 17
Dependent Claim 36 words
The method of claim 12 and further comprising removing glass from said surface by etching in areas other than the immediate areas of said trenches and heating the structure to cause glass flow and surface planarization.
Claim 18
Dependent Claim 19 words
The method of claim 16 wherein each of said heating is at temperatures of less than about 1000° C.
Claim 19
Dependent Claim 20 words
The method of claim 1 wherein bipolar transistor devices are formed in said silicon substrate within said recessed dielectric isolation.
Claim 20
Dependent Claim 21 words
The method of claim 1 wherein field effect transistor devices are formed in said silicon substrate within said recessed dielectric isolation.
Claim 21
Independent Claim 255 words
The method for forming a bipolar integrated circuit having recessed dielectric isolation in a silicon body comprising: providing a monocrystalline silicon substrate; forming doped regions of a first conductivity in said substrate in areas designated to be part of subcollector region; forming doped regions of a second conductivity in areas designated to form part of a junction isolation which cooperates with said recessed dielectric isolation to isolate regions of said silicon body; growing an epitaxial layer upon said substrate wherein during the growth said doped regions of a first conductivity outdiffuse into said epitaxial layer to fully form the said subcollector regions and, said doped regions of a second conductivity outdiffuse into said epitaxial layer to fully form the said junction isolation regions; forming by reactive ion etching a pattern of trenches in the order of microns in depth into the areas of said epitaxial layer wherein said isolation is desired and deep enough to penetrate said junction isolation regions thereunder; oxidizing the surfaces on said trenches to form a silicon dioxide layer thereon; depositing a glass having a thermal coefficient of expansion between about 20 to 50×10 -7 per degree Centigrade and has a softening temperature of less than about 1200° C. onto the said surface of said epitaxial layer; thermally heating the structure at a temperature of less than about 1200° C. to cause the flow of said glass on said surface and filling of said trenches; and forming said bipolar transistor devices within the silicon body isolated by said recessed dielectric isolation.
Claim 22
Independent Claim 255 words
The method for forming a bipolar integrated circuit having recessed dielectric isolation in a silicon body comprising: providing a monocrystalline silicon substrate; forming doped regions of a first conductivity in said substrate in areas designated to be part of subcollector region; forming doped regions of a second conductivity in areas designated to form part of a junction isolation which cooperates with said recessed dielectric isolation to isolate regions of said silicon body; growing an epitaxial layer upon said substrate wherein during the growth said doped regions of a first conductivity outdiffuse into said epitaxial layer to fully form the said subcollector regions and, said doped regions of a second conductivity outdiffuse into said epitaxial layer to fully form the said junction isolation regions; forming by reactive ion etching a pattern of trenches in the order of microns in depth into the areas of said epitaxial layer wherein said isolation is desired and deep enough to penetrate said junction isolation regions thereunder; oxidizing the surfaces on said trenches to form a silicon dioxide layer thereon; depositing a glass having a thermal coefficient of expansion between about 20 to 50×10 -7 per degree Centigrade and has a softening temperature of less than about 1200° C. onto the said surface of said epitaxial layer; thermally heating the structure at a temperature of less than about 1200° C. to cause the flow of said glass on said surface and filling of said trenches; and forming said bipolar transistor devices within the silicon body isolated by said recessed dielectric isolation.
Claim 23
Dependent Claim 15 words
The method of claim 20 wherein the etching of said trenches produces substantially vertical sidewalls.
Claim 24
Dependent Claim 38 words
The method of claim 20 and further comprising removing said glass from said epitaxial layer by etching in areas other than the immediate areas of the trenches and heating the structure to cause glass flow and surface planarization.
Claim 25
Dependent Claim 30 words
The method of claim 20 wherein a silicon nitride layer formed over said silicon dioxide layer on said surfaces of the trenches and said glass has a significant sodium content.
Claim 26
Dependent Claim 19 words
The method of claim 20 wherein said first conductivity is N type and said second conductivity is P type.
Claim 27
Independent Claim 149 words
A method for forming field effect transistor devices having recessed dielectric isolation in a silicon body comprising: forming by reactive ion etching a pattern of trenches in the order of microns in depth in the areas of one surface of said body wherein said isolation is desired; forming a channel stop at the bottom of said trenches by ion implantation; oxidizing the surfaces of said trenches to form a silicon dioxide layer thereon; depositing a glass having a thermal coefficient of expansion between about 20 to 50×10 -7 per degree Centigrade and has a softening temperature of less than about 1200° C. onto the said surface of said substrate; thermally heating the structure at a temperature less than about 1200° C. to cause the flow of said glass on said surface and filling of said trenches; and forming said field effect transistor devices within and upon said silicon body.
Claim 28
Independent Claim 149 words
A method for forming field effect transistor devices having recessed dielectric isolation in a silicon body comprising: forming by reactive ion etching a pattern of trenches in the order of microns in depth in the areas of one surface of said body wherein said isolation is desired; forming a channel stop at the bottom of said trenches by ion implantation; oxidizing the surfaces of said trenches to form a silicon dioxide layer thereon; depositing a glass having a thermal coefficient of expansion between about 20 to 50×10 -7 per degree Centigrade and has a softening temperature of less than about 1200° C. onto the said surface of said substrate; thermally heating the structure at a temperature less than about 1200° C. to cause the flow of said glass on said surface and filling of said trenches; and forming said field effect transistor devices within and upon said silicon body.
Claim 29
Dependent Claim 37 words
The method of claim 25 and further comprising removing said glass from said surface by etching in areas other than the immediate areas of the trenches and heating the structure to cause glass flow and surface planarization.
Claim 30
Dependent Claim 30 words
The method of claim 25 wherein a silicon nitride layer formed over said silicon dioxide layer on said surfaces of the trenches and said glass has a significant sodium content.
Claim 31
Dependent Claim 20 words
The method of claim 25 wherein said channel stop is P type and said field effect transistors are N type.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-03-25 1988-09-24 1989-03-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-03-25 1992-09-24 1993-03-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-03-25 1996-09-24 1997-03-26 $7700.00 Window Closed / Lapsed

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