US4424252A
Expired / Lapsed
US
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Conformal coating systems
Assignee: Henkel Loctite Corp
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Filing: 1982-11-12
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Granted: 1984-01-03
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Expires: 2002-11-12
Abstract
Abstract Ultraviolet curable polymerizable coating system having one or more built-in secondary curing mechanisms is disclosed. The polymerizable coating system is a two component system comprising (1) a first component comprising at least one urethane-acrylate or methacrylate, and a mono or polyfunctional acrylate or methacrylate diluent and a polymerization initiator of the photo-initiator type, and (2) a second component comprising a polyisocyanate. The coating system is uv curable, and also possess at least one additional cure mechanism.
Inventors
- 👤 Larry A. Nativi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 20:27
CPC Classifications
B; B05; B05D; B05D3/00; B05D3/06; C; C08; C08F; C08F299/00; C08F299/02; C08F299/06; C08F299/065; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10; C08G18/28; C08G18/67; C08G18/671; C08G18/672; C09; C09D; C09D4/00; H; H05; H05K; H05K3/00; H05K3/22; H05K3/28; H05K3/285; H05K3/287; H05K2201/00; H05K2201/09; H05K2201/09818; H05K2201/09872; Y; Y10; Y10S; Y10S428/00; Y10S428/901; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24917
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
87 words
A two-part coating composition, especially useful for conformal coating, comprising: (1) a first part comprising at least one urethane-acrylate or urethane-methacrylate compound, a mono or polyfunctional acrylate or methacrylate reactive diluent and a polymerization initiator of the photoinitiator type; and (2) a second part comprising a polyisocyanate containing adduct, at least one component of said first part containing unreacted hydroxyl groups, said composition having an equivalent weight excess of isocyanate groups in said second part to the hydroxyl groups in said first part of at least 2:1.
Claim 2
Dependent Claim
87 words
A two-part coating composition, especially useful for conformal coating, comprising: (1) a first part comprising at least one urethane-acrylate or urethane-methacrylate compound, a mono or polyfunctional acrylate or methacrylate reactive diluent and a polymerization initiator of the photoinitiator type; and (2) a second part comprising a polyisocyanate containing adduct, at least one component of said first part containing unreacted hydroxyl groups, said composition having an equivalent weight excess of isocyanate groups in said second part to the hydroxyl groups in said first part of at least 2:1.
Claim 3
Dependent Claim
21 words
The coating composition of claim 1, wherein said urethane-acrylate or urethane methacrylate compound comprises a polyester-urethane-acrylate or a polyester urethane methacrylate.
Claim 4
Dependent Claim
17 words
The coating composition of claim 2, wherein the polyester portion of said polyester-urethane-methacrylate comprises a polyester diol.
Claim 5
Dependent Claim
22 words
The coating composition of claim 3, wherein said polyester diol comprises the reaction product of neopentyl glycol and 1,6-hexanediol with adipic acid.
Claim 6
Dependent Claim
12 words
The coating composition of claim 1, and further comprising a non-ionic surfactant.
Claim 7
Dependent Claim
15 words
The coating composition of claim 5, wherein said non-ionic surfactant contains pendant free hydroxyl groups.
Claim 8
Dependent Claim
14 words
The coating composition of claim 6, wherein said non-ionic surfactant comprises a polyoxyalkene silicone.
Claim 9
Dependent Claim
20 words
The coating composition of claim 1, wherein said acrylate or methacrylate reactive diluent contains at least one reactive allylic bond.
Claim 10
Dependent Claim
23 words
The coating composition of claim 1, wherein said reactive diluent comprises from about 30% to about 70% by weight of said first part.
Claim 11
Dependent Claim
24 words
The coating composition of claim 1 wherein said polyisocyanate is present in equivalent weight excess in the range of about 2:1 to about 10:1.
Claim 12
Dependent Claim
25 words
The coating composition of claim 1 wherein said polyisocyanate is present in equivalent weight range excess in the range of about 5:1 to about 7:1.
Claim 13
Dependent Claim
18 words
The coating composition of claim 10 wherein said polyisocyanate is present in equivalent weight excess of about 6:1.
Claim 14
Independent Claim
185 words
A method of forming a UV curing polymerizable conformal coating on a substrate wherein said substrate has one or more shadow areas, comprising the steps in sequence of: (1) providing a two-part coating composition, the first part of which comprises at least one urethane-acrylate or urethane-methacrylate compound, a mono or polyfunctional acrylate or methacrylate reactive diluent and a polymerization initiator of the photo-initiator part, and a second part which comprises a polyisocyanate containing adduct at least one component of said first part containing unreacted hydroxyl groups, said composition having an equivalent weight excess of isocyanate groups in said second part to the hydroxyl groups in said first part of at least 2:1; (2) blending said first and second parts to form a coating composition; (3) applying said coating composition to said substrate; (4) exposing the coated substrate to UV light wave length and intensity to effect UV cure of exposed areas of said coating; and (5) storing said coated substrate under conditions of temperature and humidity such as to promote curing of unexposed (shadow) areas of said coating through a built-in secondary moisture cure mechanism.
Claim 15
Independent Claim
185 words
A method of forming a UV curing polymerizable conformal coating on a substrate wherein said substrate has one or more shadow areas, comprising the steps in sequence of: (1) providing a two-part coating composition, the first part of which comprises at least one urethane-acrylate or urethane-methacrylate compound, a mono or polyfunctional acrylate or methacrylate reactive diluent and a polymerization initiator of the photo-initiator part, and a second part which comprises a polyisocyanate containing adduct at least one component of said first part containing unreacted hydroxyl groups, said composition having an equivalent weight excess of isocyanate groups in said second part to the hydroxyl groups in said first part of at least 2:1; (2) blending said first and second parts to form a coating composition; (3) applying said coating composition to said substrate; (4) exposing the coated substrate to UV light wave length and intensity to effect UV cure of exposed areas of said coating; and (5) storing said coated substrate under conditions of temperature and humidity such as to promote curing of unexposed (shadow) areas of said coating through a built-in secondary moisture cure mechanism.
Claim 16
Dependent Claim
31 words
A method according to claim 13, wherein said substrate comprises a circuit board, and wherein said circuit board has one or more components mounted thereon overshadowing areas of said circuit board.
Claim 17
Dependent Claim
25 words
A printed circuit board having one or more components mounted thereon, and covered at least in part with the cured coating composition of claim 1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-01-02 | 1987-07-04 | 1988-01-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-01-02 | 1991-07-04 | 1992-01-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-01-02 | 1995-07-04 | 1996-01-03 | $7700.00 | Window Closed / Lapsed |