US4128600A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Interpenetrating dual cure resin compositions
Assignee: General Mills Chemicals Inc
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Filing: 1977-01-14
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Granted: 1978-12-05
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Expires: 1997-01-14
Abstract
Abstract Curable resin compositions are prepared containing a radiation-sensitive reactive diluent and a saturated polyol. Curing is accomplished by mixing the reactive diluent and the polyol with a polyisocyanate, followed by exposure of the resultant composition to radiation to polymerize the reactive diluent and then, by thermal curing, to form the hydroxyisocyanate (urethane) linkage. The fully cured resin composition is described as interpenetrated or one in which there is no cross-linking between the reactive diluent and urethane linked co-polymer. The interpenetrated resin compositions form tough and hard coatings on various substrates.
Inventors
- 👤 Earl Skinner
- 👤 Marvin Emeott
- 👤 Allan Jevne
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 12:08
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/63; C08G18/638; C08G18/62; C08G18/6216; C08G18/622; C08G18/6225; C08G18/6229; C08G18/637; C09; C09D; C09D175/00; C09D175/04; C08G2270/00
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
84 words
An interpenetrating radiation-sensitive resin composition comprising: (a) from about 40% to about 90% by weight of a saturated polyol which is a hydroxy functional acrylic copolymer of: (1) methyl methacrylate; (2) butyl acrylate, and (3) hydroxyethyl acrylate and, (b) from about 10% to about 60% by weight of a reactive diluent having a radiation sensitive pi bond and having a boiling point greater than that of benzene, and mixtures thereof said reactive diluent being a fully substituted polyacrylate or polymethacrylate of a polyfunctional alcohol.
Claim 2
Dependent Claim
84 words
An interpenetrating radiation-sensitive resin composition comprising: (a) from about 40% to about 90% by weight of a saturated polyol which is a hydroxy functional acrylic copolymer of: (1) methyl methacrylate; (2) butyl acrylate, and (3) hydroxyethyl acrylate and, (b) from about 10% to about 60% by weight of a reactive diluent having a radiation sensitive pi bond and having a boiling point greater than that of benzene, and mixtures thereof said reactive diluent being a fully substituted polyacrylate or polymethacrylate of a polyfunctional alcohol.
Claim 3
Dependent Claim
26 words
The composition of claim 1 wherein the reactive diluent is selected from the group consisting of diol diacrylates, triol triacrylates, and tetrol tetraacrylates and mixtures thereof.
Claim 4
Dependent Claim
43 words
The composition of claim 2 wherein the reactive diluent is selected from the group consisting of: (a) 1,6-hexane diol diacrylate; (b) ethylene glycol diacrylate; (c) trimethylol propane triacrylate; (d) triethylene glycol diacrylate; (e) neopentyl diol diacrylate; and (f) pentaerythritol tetraacrylate, and mixtures thereof.
Claim 5
Dependent Claim
59 words
The composition of claim 3 wherein the reactive diluent is 1,6-hexane diol diacrylate at from about 20% to about 50% by weight and from about 50% to about 80% by weight of a hydroxyfunctional copolymer of: (a) methyl methacrylate, (b) butyl acrylate, and (c) hydroxyethyl acrylate in a molar ratio of a:b:c of from about 4:1:1 to about 1:4:3.
Claim 6
Dependent Claim
96 words
An interpenetrating urethane-linking, radiation-sensitive resin composition comprising: (a) from about 40% to about 90% by weight of a saturated polyol which is a hydroxy functional acrylic copolymer of: (1) methyl methacrylate; (2) butyl acrylate, and (3) hydroxyethyl acrylate and, (b) from about 10% to about 60% by weight of a reactive diluent selected from the group consisting of the fully substituted polyacrylates and polymethacrylates of poly-functional alcohols, 2-ethylhexylacrylate, isodecylacrylate, diallyl maleate, styrene, divinylbenzene, vinyl acetate, and N-vinyl-2-pyrrolidone, and mixtures thereof; and, (c) from about 80% to about 120% on a hydroxylisocyanate equivalent basis of a polyisocyanate.
Claim 7
Dependent Claim
96 words
An interpenetrating urethane-linking, radiation-sensitive resin composition comprising: (a) from about 40% to about 90% by weight of a saturated polyol which is a hydroxy functional acrylic copolymer of: (1) methyl methacrylate; (2) butyl acrylate, and (3) hydroxyethyl acrylate and, (b) from about 10% to about 60% by weight of a reactive diluent selected from the group consisting of the fully substituted polyacrylates and polymethacrylates of poly-functional alcohols, 2-ethylhexylacrylate, isodecylacrylate, diallyl maleate, styrene, divinylbenzene, vinyl acetate, and N-vinyl-2-pyrrolidone, and mixtures thereof; and, (c) from about 80% to about 120% on a hydroxylisocyanate equivalent basis of a polyisocyanate.
Claim 8
Dependent Claim
19 words
The composition of claim 5 wherein the sum of the polyisocyanate functionality and hydroxy functionality is greater than four.
Claim 9
Dependent Claim
13 words
The composition of claim 5 wherein the reactive diluent is 1,6-hexane diol diacrylate.
Claim 10
Dependent Claim
31 words
The composition of claim 7 wherein the reactive diluent is a mixture of 1,6-hexane diol diacrylate and N-vinyl 2-pyrrolidone in a respective weight ratio of from about 4:1 to about 1:4.
Claim 11
Dependent Claim
21 words
The composition of claim 8 wherein the polyisocyanate is present at from about 95% to 105% on a hydroxyl-isocyanate equivalent basis.
Claim 12
Dependent Claim
21 words
The composition of claim 9 wherein the polyisocyanate is selected from the group consisting of diisocyanates and triisocyanates and mixtures thereof.
Claim 13
Dependent Claim
57 words
The composition of claim 10 wherein the polyisocyanate is selected from the group consisting of: (a) toluene diisocyanate; (b) xylene diisocyanate; (c) isophorone diisocyanate; (d) hexamethylene diisocyanate; (e) the triisocyanate adduct of hexamethylene diisocyanate and water, (f) trimethyl hexamethylene diisocyanate, (g) aliphatic diisocyanates having from 12 to 40 carbon atoms in the aliphatic moiety; and mixtures thereof.
Claim 14
Dependent Claim
22 words
The composition of claim 5 wherein the weight ratio of (a) plus (c) to (b) is from about 80:20 to about 20:80.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-12-04 | 1982-06-05 | 1982-12-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-12-04 | 1986-06-05 | 1986-12-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-12-04 | 1990-06-05 | 1990-12-05 | $7700.00 | Window Closed / Lapsed |