Process for producing pressure-sensitive copy sheets using novel radiation curable coatings

Claim 2

A process for producing a pressure-sensitive carbonless record sheet comprising the steps of: (a) preparing a liquid chromogenic coating composition by mixing a color developing material with a liquid radiation curable substance, said color developing material being an acidic electron acceptor, said liquid radiation curable substance including one or a mixture of ethylenically unsaturated organic compounds having at least one terminal ethylenic group per molecule, said liquid radiation curable substance being compatible with the color forming characteristics of said color developing material; (b) coating said liquid chromogenic coating composition on a substrate, said coating being applied at a coat weight of from about 0.2 pounds to about 8.0 pounds per 3300 square feet of said substrate; and (c) exposing said coated substrate to radiation for a period of time sufficient to cure said liquid coating composition to a tack-free film, said tack free film being compatible with the color forming characteristics of said color developing material.

Claim 3

The process of claim 1 in which said acidic electron-acceptor is selected from the group consisting of the novolaks of p-phenylphenol, p-octylphenol and p-tert-butylphenol, the zinc modified novolaks of p-phenylphenol, p-octylphenol and p-tert-butylphenol and mixtures thereof.

Claim 4

The process of claim 1 in which said liquid chromogenic coating composition additionally contains a photoinitiator and said coated substrate is exposed to ultraviolet radiation having a wavelength of from about 2000 A to about 4000 A.

Claim 5

The process of claim 3 in which said liquid chromogenic coating composition additionally contains a photoinitiation synergist.

Claim 6

A process for producing a pressure-sensitive carbonless transfer sheet comprising the steps of: (a) preparing a liquid chromogenic coating composition by mixing a chromogenic material with a liquid radiation curable substance, said chromogenic material being a color precursor of the electron donating type, said liquid radiation curable substance including one or a mixture of ethylenically unsaturated organic compounds having at least one terminal ethylenic group per molecule, said liquid radiation curable substance being compatible with the color forming characteristics of said color precursor; (b) coating said liquid chromogenic coating composition on a substrate, said coating being applied at a coat weight of from about 1.0 pounds to about 8.0 pounds per 3300 square feet of said substrate; and (c) exposing said coated substrate to radiation for a period of time sufficient to cure said liquid coating composition to a tack-free film, said tack-free film being compatible with the color forming characteristics of said color precursor.

Claim 7

A process for producing a pressure-sensitive carbonless transfer sheet comprising the steps of: (a) preparing a liquid chromogenic coating composition by mixing a chromogenic material with a liquid radiation curable substance, said chromogenic material being a color precursor of the electron donating type, said liquid radiation curable substance including one or a mixture of ethylenically unsaturated organic compounds having at least one terminal ethylenic group per molecule, said liquid radiation curable substance being compatible with the color forming characteristics of said color precursor; (b) coating said liquid chromogenic coating composition on a substrate, said coating being applied at a coat weight of from about 1.0 pounds to about 8.0 pounds per 3300 square feet of said substrate; and (c) exposing said coated substrate to radiation for a period of time sufficient to cure said liquid coating composition to a tack-free film, said tack-free film being compatible with the color forming characteristics of said color precursor.

Claim 8

The process of claim 5 in which said color precursor is dissolved in an oil to form a solution of color precursor in an oil and said oil containing said color precursor is microencapsulated prior to mixing with a liquid radiation curable substance.

Claim 9

The process of claim 5 in which said color precursor is selected from the group consisting of lactone phthalides, lactone fluorans, lactone xanthenes, leucoauramines, 2-(omega substituted vinylene)3,3-disubstituted-3-H-indoles,1,3,3-trialkylinodolinspirans and mixtures thereof.

Claim 10

A process for producing a pressure-sensitive carbonless copy sheet comprising the steps of: (a) preparing a liquid chromogenic coating composition by mixing a chromogenic material with a liquid radiation curable substance, said chromogenic material being selected from the group consisting of acidic electron accepting color developers and electron donating color precursors, said liquid radiation curable substance including at least one ethylenically unsaturated organic compound having at least one terminal ethylenic group per molecule, said radiation curable substance being compatible with the color forming characteristics of said chromogenic material; (b) coating said liquid coating composition on a paper substrate, said coating composition being applied at a coat weight of from about 0.2 pounds to about 8 pounds per 3300 square feet of said substrate; and (c) exposing said coated paper to radiation for a period of time sufficient to cure said liquid coating composition to a tack-free film, said tack-free film being compatible with the color forming characteristics of said chromogenic material.

Claim 11

A process for producing a pressure-sensitive carbonless copy sheet comprising the steps of: (a) preparing a liquid chromogenic coating composition by mixing a chromogenic material with a liquid radiation curable substance, said chromogenic material being selected from the group consisting of acidic electron accepting color developers and electron donating color precursors, said liquid radiation curable substance including at least one ethylenically unsaturated organic compound having at least one terminal ethylenic group per molecule, said radiation curable substance being compatible with the color forming characteristics of said chromogenic material; (b) coating said liquid coating composition on a paper substrate, said coating composition being applied at a coat weight of from about 0.2 pounds to about 8 pounds per 3300 square feet of said substrate; and (c) exposing said coated paper to radiation for a period of time sufficient to cure said liquid coating composition to a tack-free film, said tack-free film being compatible with the color forming characteristics of said chromogenic material.

Claim 12

The process of claim 8 in which said liquid radiation curable substance is a mixture of ethylenically unsaturated organic compounds, said mixture comprising from about 33 to about 67% by weight of said compounds having one terminal ethylenic group per molecule and from about 33 to about 67% by weight of said compounds having more than one ethylenic group per molecule.

Claim 13

A process for producing a pressure-sensitive carbonless record sheet comprising the steps of: (a) preparing a liquid chromogenic coating composition by mixing together from about 25 to about 75% by weight of a chromogenic material and from about 25 to about 75% of a liquid radiation curable substance, said radiation curable substance being a mixture of ethylenically unsaturated organic compounds, said mixture comprising from about 33 to about 67% by weight of said compounds having one terminal ethylenic group per molecule and from about 33 to about 67% by weight of said compounds having more than one terminal ethylenic group per molecule and up to about 15% by weight of a filler material, said radiation curable substance being compatible with the color forming characteristics of said chromogenic material; (b) coating said liquid coating composition on a paper substrate, said coating composition being applied at a coat weight of from about 0.2 pounds to about 8.0 pounds per 3300 square feet of said substrate; and (c) exposing said coated paper to radiation for a period of time sufficient to cure said liquid coating composition to a tack-free film, said tack-free film substance being compatible with the color forming characteristics of said chromogenic material.

Claim 14

A process for producing a pressure-sensitive carbonless record sheet comprising the steps of: (a) preparing a liquid chromogenic coating composition by mixing together from about 25 to about 75% by weight of a chromogenic material and from about 25 to about 75% of a liquid radiation curable substance, said radiation curable substance being a mixture of ethylenically unsaturated organic compounds, said mixture comprising from about 33 to about 67% by weight of said compounds having one terminal ethylenic group per molecule and from about 33 to about 67% by weight of said compounds having more than one terminal ethylenic group per molecule and up to about 15% by weight of a filler material, said radiation curable substance being compatible with the color forming characteristics of said chromogenic material; (b) coating said liquid coating composition on a paper substrate, said coating composition being applied at a coat weight of from about 0.2 pounds to about 8.0 pounds per 3300 square feet of said substrate; and (c) exposing said coated paper to radiation for a period of time sufficient to cure said liquid coating composition to a tack-free film, said tack-free film substance being compatible with the color forming characteristics of said chromogenic material.

Claim 15

A process for producing a pressure-sensitive carbonless transfer sheet comprising the steps of: (a) preparing a solution of a chromogenic material in an oil, said chromogenic material being a color precursor of the electron donating type, said chromogenic material comprising from about 0.5 to about 20.0% of the weight of said oil; (b) microencapsulating said solution of said chromogenic material in said carrier oil; (c) preparing a liquid chromogenic coating composition by mixing together said microencapsulated solution of said chromogenic material in said oil with a liquid radiation curable substance, said radiation curable substance being a mixture of ethylenically unsaturated organic compounds, said mixture comprising from about 33 to about 67% by weight of said compounds having one terminal ethylenic group per molecule and from about 33 to about 67% by weight of said compounds having more than one terminal ethylenic group per molecule and up to about 15% by weight of a filler material, said radiation curable substance being compatible with the color forming characteristics of said chromogenic material; (d) coating said liquid coating composition on a paper substrate said coating being applied at a coat weight of from about 1 pound to about 8 pounds per 3300 square feet of said substrate; and (e) exposing said coated paper to radiation for a period of time sufficient to cure said liquid coating composition to a tack-free film, said tack-free film being compatible with the color forming characteristics of said chromogenic material.

Claim 16

A process for producing a pressure-sensitive carbonless transfer sheet comprising the steps of: (a) preparing a solution of a chromogenic material in an oil, said chromogenic material being a color precursor of the electron donating type, said chromogenic material comprising from about 0.5 to about 20.0% of the weight of said oil; (b) microencapsulating said solution of said chromogenic material in said carrier oil; (c) preparing a liquid chromogenic coating composition by mixing together said microencapsulated solution of said chromogenic material in said oil with a liquid radiation curable substance, said radiation curable substance being a mixture of ethylenically unsaturated organic compounds, said mixture comprising from about 33 to about 67% by weight of said compounds having one terminal ethylenic group per molecule and from about 33 to about 67% by weight of said compounds having more than one terminal ethylenic group per molecule and up to about 15% by weight of a filler material, said radiation curable substance being compatible with the color forming characteristics of said chromogenic material; (d) coating said liquid coating composition on a paper substrate said coating being applied at a coat weight of from about 1 pound to about 8 pounds per 3300 square feet of said substrate; and (e) exposing said coated paper to radiation for a period of time sufficient to cure said liquid coating composition to a tack-free film, said tack-free film being compatible with the color forming characteristics of said chromogenic material.

Claim 17

The process of claim 11 in which from about 0.2 to about 10% by weight of a photoinitiator and from about 0.2 to about 10% by weight of a photoinitiation synergist are mixed into said liquid chromogenic coating composition prior to coating said composition on said paper substrate and said coated paper substrate is exposed to ultraviolet radiation having a wavelength from about 2000 A to about 4000 A.

Claim 18

A process for the production of a manifold carbonless form having one or more surfaces coated with chromogenic material comprising: (a) providing a continuous paper substrate; (b) marking at least one surface of said paper substrate with a pattern; (c) preparing a non-aqueous, solvent-free, liquid chromogenic coating composition by mixing a chromogenic material with a liquid radiation curable substance, said chromogenic material being selected from the group consisting of acidic electron accepting color developers and electron donating color precursors, said liquid radiation curable substance including at least one ethylenically unsaturated organic compound having at least one terminal ethylenic group per molecule; (d) coating said liquid chromogenic coating composition onto said paper substrate, said coating composition being applied at a coat weight of from about 0.2 pounds to about 8.0 pounds per 3300 square feet of said paper substrate; (e) exposing said coated paper substrate to radiation for a period of time sufficient to cure said non-aqueous, solvent-free liquid coating composition to a tack-free film; (f) combining said marked, coated paper substrate with at least one additional paper substrate to form a plurality of paper substrates, each of said additional paper substrates being characterized by having at least a portion of at least one surface coated with at least one non-aqueous, solvent-free coating of said chromogenic material, said coating being cured; (g) collating said plurality of marked, coated paper substrated; and (h) placing said collated paper substrates in contiguous relationship to one another to create a manifold carbonless form.

Claim 19

A process for the production of a manifold carbonless form having one or more surfaces coated with chromogenic material comprising: (a) providing a continuous paper substrate; (b) marking at least one surface of said paper substrate with a pattern; (c) preparing a non-aqueous, solvent-free, liquid chromogenic coating composition by mixing a chromogenic material with a liquid radiation curable substance, said chromogenic material being selected from the group consisting of acidic electron accepting color developers and electron donating color precursors, said liquid radiation curable substance including at least one ethylenically unsaturated organic compound having at least one terminal ethylenic group per molecule; (d) coating said liquid chromogenic coating composition onto said paper substrate, said coating composition being applied at a coat weight of from about 0.2 pounds to about 8.0 pounds per 3300 square feet of said paper substrate; (e) exposing said coated paper substrate to radiation for a period of time sufficient to cure said non-aqueous, solvent-free liquid coating composition to a tack-free film; (f) combining said marked, coated paper substrate with at least one additional paper substrate to form a plurality of paper substrates, each of said additional paper substrates being characterized by having at least a portion of at least one surface coated with at least one non-aqueous, solvent-free coating of said chromogenic material, said coating being cured; (g) collating said plurality of marked, coated paper substrated; and (h) placing said collated paper substrates in contiguous relationship to one another to create a manifold carbonless form.

Claim 20

A process for the continuous production of a manifold carbonless form having one or more surfaces coated with capsular chromogenic material comprising: (a) providing a plurality of continuous paper substrates; (b) advancing each substrate of said plurality of continuous substrates at substantially the same speed, said plurality of continuous substrates being spaced apart and being advanced in a cooperating relationship with one another; (c) marking at least one substrate of said plurality of continuous substrates with a pattern; (d) preparing a non-aqueous, solvent-free liquid chromogenic coating composition by mixing a chromogenic material with a liquid radiation curable substance, said chromogenic material being selected from the group consisting of acidic electron accepting color developers and electron donating color precursors, said liquid radiation curable substance including at least one ethylenically unsaturated organic compound having at least one terminal ethylenic group per molecule; (e) coating said liquid coating composition on at least one paper substrate of said plurality of paper substrates, said coating composition being applied at a coat weight of from about 0.2 pounds to about 8.0 pounds per 3300 square feet of said substrate; (f) exposing said coated substrate to radiation for a period of time sufficient to cure said liquid coating composition to a tack-free film; (g) collating said plurality of continuous webs; and (h) placing said collated continuous webs in contiguous relationship to one another to create a manifold form.

Claim 21

A process for the continuous production of a manifold carbonless form having one or more surfaces coated with capsular chromogenic material comprising: (a) providing a plurality of continuous paper substrates; (b) advancing each substrate of said plurality of continuous substrates at substantially the same speed, said plurality of continuous substrates being spaced apart and being advanced in a cooperating relationship with one another; (c) marking at least one substrate of said plurality of continuous substrates with a pattern; (d) preparing a non-aqueous, solvent-free liquid chromogenic coating composition by mixing a chromogenic material with a liquid radiation curable substance, said chromogenic material being selected from the group consisting of acidic electron accepting color developers and electron donating color precursors, said liquid radiation curable substance including at least one ethylenically unsaturated organic compound having at least one terminal ethylenic group per molecule; (e) coating said liquid coating composition on at least one paper substrate of said plurality of paper substrates, said coating composition being applied at a coat weight of from about 0.2 pounds to about 8.0 pounds per 3300 square feet of said substrate; (f) exposing said coated substrate to radiation for a period of time sufficient to cure said liquid coating composition to a tack-free film; (g) collating said plurality of continuous webs; and (h) placing said collated continuous webs in contiguous relationship to one another to create a manifold form.